scholarly journals Laser Induced Modification of the Optical Properties of Nano-ZnO Doped PVC Films

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Tagreed K. Hamad ◽  
Rahimi M. Yusop ◽  
Wasan A. Al-Taa’y ◽  
Bashar Abdullah ◽  
Emad Yousif

The effect of continuous CO2laser radiation on the optical properties of pure polyvinyl chloride and doped of ZnO nanoparticles with two different concentrations (10, 15%) has been investigated. All samples were prepared using casting method at room temperature. Optical properties (absorption, transmission, absorption coefficient, extinction coefficient, refractive index, and optical conductivity) of all films after CO2laser irradiated have been studied as a function of the wavelength in the range (200–800) nm for three energies (300, 400 and 500 mJ). It has been found that the transmission, energy gap, and refractive index increase with increasing laser energy. The values of absorption, Urbach energy, absorption coefficient, extinction coefficient, and optical conductivity were decreased.

Author(s):  
Wasmaa Abdulsattar Jabbar

Copper oxide prepared with various contains of Manganese by chemical spray pyrolysis. Some optical properties are studied from recording the absorption spectra via UV-Visible spectrophotometer in the range of 460-900 nm. The absorbance increased with increasing Mn-contain in the CuO thin films, and the absorption coefficient. Extinction coefficient and refractive index are decreased with increasing Mn-contain in the CuO thin films, also the energy gap shifted from 2 eV to 1.91 eV after 4%Mn additive.


Author(s):  
Nidhal Nissan Jandow

This work presents the effect of Cu-doping on some optical properties of Cu:NiO thin film prepared by spray pyrolysis technique. UV-Visible spectrophotometer in the range 380-900 nm used to determine the absorbance spectra for various Cu-doping of Cu:NiO thin film. The transmittance and energy gap are decreased with increasing Cu-doping in the prepared films, while absorption coefficient, extinction coefficient, and skin depth are increased with increasing Cu-doping.


Author(s):  
Maan A. Saleh ◽  
Abdulazeez O.Mousa ◽  
Mohammed Hadi Shinen

The study includes the recording the absorption and permeability spectra of a combination of polyaniline compound solution with poly(3,4-ethylenedioxythiophene) PEDOT and calculating the absorption factor and other optical constants. These samples were attended to different concentrations (0.01%,0.02%,0.03%) of PEDOT added to polyaniline. The values of absorbance, the refractive index values of pure polymer and its additives are increasing with the increase of the concentrations of these polymer,noting that the increment of absorption coefficient values under the influence of addition caused by increasing density of the solutions as a result of the increased concentrations, that led to the increase of light absorbed because the interaction of the electromagnetic wave and the large molecules of the polymer increases with concentration,the results show that decreasing in the values of transmittance with all concentrations, the values of reflectance are increases with increasing concentration before and after the doping, the results showed decrease energy gap with increasing ratio of doping.


2011 ◽  
Vol 337 ◽  
pp. 120-124
Author(s):  
Yin Feng Chen ◽  
Jun Qi Xu ◽  
Jun Hong Su ◽  
Ling Xia Han

Diamond-like carbon (DLC) films have being widely applied in various domains owing to their excellent optical and mechanical properties, chemical inertness and bio-compatibility[1,2]. But it generally exhibits low a laser induced damage threshold (LIDT).As to infrared protective films, DLC films were asked to be a high laser damage threshold. So far, the real reason of laser damage is unclear. In order to understand the real reason of the laser damage, it is necessary to deeply research the relationship between optical properties and laser radiation. In this paper, optical properties post irraditing by various laser energy were inverstigated. Hydrogen-free amorphous carbon films were deposited by unbalanced magnetron sputtering with a graphite target on Si substrate in this paper. The DLC films were radiated with raster scans methods by a 1064nm and 8–10 ns laser in this work. The transmittance, refractive index, extinction coefficient and surface morphology of DLC before and after radiation were examined by fourier transform infrared spectrometer, ellipsometer and talysurf respectively. The influences were considered as function of laser energy density.The optical properties before and after laser radiation were compared. It is found that as laser fluences rise from 0 to 0.5 J/cm2, the transmittance peak reduce from 67.06% to 58.27%, the refractive index decrease from 1.88 to 1.67(λ=1200), the extinction coefficient increase from 0.07 to 0.32(λ=1200), and the surface roughness become 149.28nm in this procedλure. Especially, the reasons of change were expounded in this paper.


2017 ◽  
Vol 28 (1) ◽  
pp. 158
Author(s):  
Asrar A. Saeed

Effects of methyl green (MG) dye on the optical properties of polystyrene (PS) have been studied. Pure polystyrene and MG doped PS films were prepared by using casting method. These films were characterized using UV/VIS spectrophotometer technique in order to estimate the type of electric transition which was found to be indirect transition. The value of the optical energy gap was decreased with increasing doping ratios of methyl green dye. Absorption coefficient, extinction coefficient, refractive index and energy gap have been also investigated; it was found that all the above parameters affects by doping dye.


2019 ◽  
Vol 15 (32) ◽  
pp. 99-113
Author(s):  
Mahdi Hasan Suhail

Polymer films of PEG and PVA and their blend with differentconcentrations of MnCl2 (0, 2, 4, 6 and 10 %.wt) were study usingcasting technique. The X-ray spectra of pure PEG, PVA andPVA:PEG films and with addition of 2% concentrations from(MnCl2) show amorphous structures. The results for FTIR show theinteraction between the filler and polymer blend results indecreasing crystallinity with rich amorphous phase. Thisamorphous nature confirms the complexation between the filler andthe polymer blend. The optical properties of (PVA:PEG/MnCl2)contain the recording of absorbance (A) and explain that theabsorption coefficient (α), refractive index (n), extinction coefficient(ko) and the dielectric constants (real and imaginary part) increasewith increasing the concentration of Composite (PVA:PEG/MnCl2).The optical energy gap for electrons transitions both are direct andindirect allowed.


2022 ◽  
Author(s):  
Syed Awais Rouf ◽  
Muhammad Iqbal Hussain ◽  
Umair Mumtaz ◽  
Hafiz Tariq Masood ◽  
Hind Albalawi ◽  
...  

Abstract The ab-initio computations were performed to study the electronic and optoelectronic properties of RhXO3 (X = Ga, Ag) using WIEN2k code. The RhGaO3 has band gap of 2.29 eV, and the behavior of RhAgO3 metallic. The sub-TDOS of the studied materials revealed that rhodium and oxygen atoms have significant contributions in the valence band and conduction band formation of both materials. The silver cation is responsible for the reasonable peaks appearing at the Fermi level of RhAgO3, which demonstrated the conducting nature of RhAgO3. The dielectric functions, optical conductivity, energy loss function, absorption coefficient, refractive index, extinction coefficient, and reflectivity are computed for these materials to understand the optical behavior of the studied materials. The analysis of optical properties ensure the RhGaO3 is a promising material for optoelectronics while RhAgO3 has metallic nature.


Author(s):  
Sabah A. Salman ◽  
Nabeel A. Bakr ◽  
Marwa R. Jwameer

Films of polymer (polyvinyl alcohol (PVA)) doped with CuCl salt at different concentrations (2 and 10) wt% were prepared using casting technique. The optical properties of the films were studied after annealing. The transmission and absorption spectra have been recorded in the wavelength range of (300-1100) nm. The effect of annealing on the optical properties for (PVA-CuCl) films with different concentrations (2 and 10) wt% of copper chloride salt shows that the transmittance decreased after annealing for all the films. The optical constants (absorption coefficient, refractive index, extinction coefficient, real and imaginary parts of dielectric constant) for all the films are affected by annealing. The energy gap (Eg) of all the films decreased after annealing.


2021 ◽  
Vol 19 (49) ◽  
pp. 22-31
Author(s):  
Wasan A. Al-Taa'y ◽  
Bushra A. Hasan

The properties of structural and optical of pure and doped nano titanium dioxide (TiO2) films, prepared using chemical spray pyrolysis (CPS) technique, with different nanosize nickel oxide (NiO) concentrations in the range (3-9)wt% have been studied. X-Ray diffraction (XRD) technique where using to analysis the structure properties of the prepared thin films. The results revealed that the structure properties of TiO2 have polycrystalline structure with anatase phase. The parameters, energy gap, extinction coefficient, refractive index, real and imaginary parts were studied using absorbance and transmittance measurements from a computerized ultraviolet visible spectrophotometer (Shimadzu UV-1601 PC) in the wavelengths range (300-800)nm. Optical properties of TiO2 affected by the adding of NiO impurity where the transmittance increased as NiO concentration increased but with more adding the transmittance returned to decrease again. It was found the extinction coefficient, refractive index, real and imaginary parts values decreased with increasing doping percentage up to 7% and then increases occur one more again at 9%. Energy gap values increased after doping with NiO where the values lies in the range was 3.31 to 3.51 eV .


2010 ◽  
Vol 7 (1) ◽  
pp. 168-173
Author(s):  
Baghdad Science Journal

Sb2S3 thin films have been prepared by chemical bath deposition on a glas sub Absorbance and transmittance spectra were recorded in the wavelength range (30-900) nm. The effects of thickness on absorption coefficient, reflectance, refractive index, extinction coefficient, real and imaginary parts of dielectric constant were estimated. It was found that the reflectivity, absorption coefficient , extinction coefficient, real part of dielectric constant and refractive index, all these parameters decrease as the thickness increased, while the imaginary part of the dielectric constant increase as the thickness increased.


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