scholarly journals Effect of Manganese Contain on the Optical Properties of CuO Thin Films

Author(s):  
Wasmaa Abdulsattar Jabbar

Copper oxide prepared with various contains of Manganese by chemical spray pyrolysis. Some optical properties are studied from recording the absorption spectra via UV-Visible spectrophotometer in the range of 460-900 nm. The absorbance increased with increasing Mn-contain in the CuO thin films, and the absorption coefficient. Extinction coefficient and refractive index are decreased with increasing Mn-contain in the CuO thin films, also the energy gap shifted from 2 eV to 1.91 eV after 4%Mn additive.

2021 ◽  
Vol 19 (49) ◽  
pp. 22-31
Author(s):  
Wasan A. Al-Taa'y ◽  
Bushra A. Hasan

The properties of structural and optical of pure and doped nano titanium dioxide (TiO2) films, prepared using chemical spray pyrolysis (CPS) technique, with different nanosize nickel oxide (NiO) concentrations in the range (3-9)wt% have been studied. X-Ray diffraction (XRD) technique where using to analysis the structure properties of the prepared thin films. The results revealed that the structure properties of TiO2 have polycrystalline structure with anatase phase. The parameters, energy gap, extinction coefficient, refractive index, real and imaginary parts were studied using absorbance and transmittance measurements from a computerized ultraviolet visible spectrophotometer (Shimadzu UV-1601 PC) in the wavelengths range (300-800)nm. Optical properties of TiO2 affected by the adding of NiO impurity where the transmittance increased as NiO concentration increased but with more adding the transmittance returned to decrease again. It was found the extinction coefficient, refractive index, real and imaginary parts values decreased with increasing doping percentage up to 7% and then increases occur one more again at 9%. Energy gap values increased after doping with NiO where the values lies in the range was 3.31 to 3.51 eV .


2018 ◽  
Vol 15 (2) ◽  
pp. 221-226
Author(s):  
Baghdad Science Journal

In this paper the effect of nonthermal atmospheric argon plasma on the optical properties of the cadmium oxide CdO thin films prepared by chemical spray pyrolysis was studied. The prepared films were exposed to different time intervals (0, 5, 10, 15, 20) min. For every sample, the transmittance, Absorbance, absorption coefficient, energy gap, extinction coefficient and dielectric constant were studied. It is found that the transmittance and the energy gap increased with exposure time, and absorption. Absorption coefficient, extinction coefficient, dielectric constant decreased with time of exposure to the argon plasma


Author(s):  
Nidhal Nissan Jandow

This work presents the effect of Cu-doping on some optical properties of Cu:NiO thin film prepared by spray pyrolysis technique. UV-Visible spectrophotometer in the range 380-900 nm used to determine the absorbance spectra for various Cu-doping of Cu:NiO thin film. The transmittance and energy gap are decreased with increasing Cu-doping in the prepared films, while absorption coefficient, extinction coefficient, and skin depth are increased with increasing Cu-doping.


Author(s):  
Sami Salmann Chiad

By chemical spray pyrolysis method. The CdO thin film prepared at constant film thickness (350 nm). The prepared films are annealed at a temperature of 450 and 500 °C. The optical properties are calculated from the measurement of UV-Visible spectrophotometer spectrum in the range of (300-900) nm at room temperature. The transmittance, absorption coefficient, extinction coefficient, refractive index, and skin depth are calculated as annealing temperature. The energy gap decreased from 2.52 eV to 2.47 eV when the annealing temperature increased from room temperature to 500 °C.


Author(s):  
Mahdi M. Mutter ◽  
Habiba Kadhum Atty ◽  
Areej Adnan Hateef

The purpose of this research is studying the effect of gamma radiation on the structural and optical properties of iron oxide Fe2O3thin films. The technique used for prepared the thin films was thermal chemical spray. The effect of Co60irradiation on the structural and optical properties of the thin films was investigated. The crystal structure were studied by XRD pattern. The surface tested from crack and defect was looke by used microscope image. The absorption and transmission spectra by used UV/VIS for the as deposited and irradiated thin films. The energy gap and absorption coefficient were studied. It's found that the energy gap for the un-irradiated sample was 2.3 eV and than after exposed to gamma radiation at (25,50,75,100 and 125) Gy the energy gap decreased and above 5o Gy was increasing. The absorption coefficient increased until (12x104) cm-1at 50 Gy and than was decreasing to (2x104) cm-1at 125 Gy. The effect of radiation on the structural and optical properties was positive at the levels of irradiation used.


2019 ◽  
Vol 30 (1) ◽  
pp. 193
Author(s):  
Karrar Mahdi Saleh

In the present work, undoped CdS and doped with iron CdS:Fe+3 thin films have been prepared by chemical spray pyrolysis method on glass substrate with different temperature from cadmium nitrate solution with constant thickness(450 ± 5 nm), and study the effect of the percentage of doping with iron on optical properties of prepared films. The optical properties have been studied from transmittance and absorbance spectral within wavelengths range (380-900 nm). The results showed that all the prepared films has direct electronic transitions and optical energy gap between (2.31-2.44 eV). They also showed that the transmittance and optical energy gap of films prepared from nitrate solution increase with increasing of substrate temperature, then transmittance start downward with the continued increase in temperature (400, 450 oC), and a decrease in the optical energy gap with increasing doping percentage with iron.


Author(s):  
Khalid Haneen Abass

Fe2O3 thin films that doped by NiO were obtained on glass substrates by the chemical spray pyrolysis technique, and annealed at 450 °C and 500 °C. The effect of annealing on optical properties was studied by recording the absorbance spectra using UV-Visible spectrophotometer. The refractive index decreases with increasing annealing temperature, such as an optical band gap that decreases from 2.68 eV before annealing to 2.58 eV after annealing of 500 °C. Absorption coefficient and extinction coefficient increase with increasing annealing temperature.


2020 ◽  
pp. 2050054
Author(s):  
RADOUANE GRAINE ◽  
KHOULOUD BEDOUD ◽  
NADJETTE SEHAB ◽  
DJAMEL ZELMATI

In this study, Anatase thin films of titanium dioxide (TiO[Formula: see text] are deposited by the Direct Current (DC) magnetron sputtering technique on glass substrate for future application in gas sensors. In our work, we focused and discussed the effect of various substrate temperatures [Formula: see text]C, [Formula: see text]C and [Formula: see text]C, and film thicknesses 142, 220 and 410[Formula: see text]nm, respectively, in order to study the structural and optical properties of the TiO2 thin films. The crystalline structure and optical properties of TiO2 nanoparticles were investigated using X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), Atomic Force Microscopy (AFM), Raman spectroscopy and UV–visible spectroscopy. The formation of the Anatase TiO2 with Tetragonal crystal structure has been confirmed with XRD. UV–visible spectrophotometry characterization of the developed thin films showed that all the films had an optical transmission greater than 92% in the visible region. In addition, the obtained direct and indirect optical band gaps using the Tauc plot are 3.66, 3.34[Formula: see text]eV at [Formula: see text]C 3.74, 3.37[Formula: see text]eV at [Formula: see text]C and 3.71, 3.37[Formula: see text]eV at [Formula: see text]C, respectively. Forouhi–Bloomer (FB) physical model has been used to obtain the refractive index and extinction coefficient by fitting theoretical transmittance curves to experimental ones. The optical refractive index is found to vary from 2.350 for [Formula: see text]C, 2.1499 for [Formula: see text]C and 2.1420 for [Formula: see text]C. Moreover, we have obtained an extinction coefficient [Formula: see text] ([Formula: see text] of around [Formula: see text] for both substrate temperatures [Formula: see text]C and [Formula: see text]C, and around [Formula: see text] for the [Formula: see text]C.


2010 ◽  
Vol 7 (1) ◽  
pp. 168-173
Author(s):  
Baghdad Science Journal

Sb2S3 thin films have been prepared by chemical bath deposition on a glas sub Absorbance and transmittance spectra were recorded in the wavelength range (30-900) nm. The effects of thickness on absorption coefficient, reflectance, refractive index, extinction coefficient, real and imaginary parts of dielectric constant were estimated. It was found that the reflectivity, absorption coefficient , extinction coefficient, real part of dielectric constant and refractive index, all these parameters decrease as the thickness increased, while the imaginary part of the dielectric constant increase as the thickness increased.


2017 ◽  
Vol 35 (2) ◽  
pp. 335-345 ◽  
Author(s):  
A.M. Abd-Elnaiem ◽  
M. Mohamed ◽  
R.M. Hassan ◽  
A.A. Abu-Sehly ◽  
M.A. Abdel-Rahim ◽  
...  

Abstract Chalcogenide glasses have attracted much attention largely due to their interesting physical and chemical properties. Though few published articles exist on the As-Te system, little is known about the optical properties of eutectic or near eutectic composition of As-Te system upon heat treatment. Therefore, this paper reports the effects of annealing temperature on the structural and optical parameters of As30Te70 thin films. The bulk and thin films of 150 nm thick As30Te70 chalcogenide glasses were prepared by melt-quenching and thermal evaporation techniques, respectively. The glass transition and crystallization reactions of the bulk samples were investigated using differential scanning calorimetry (DSC). The influence of annealing temperature on the transformation of the crystal structure was studied by X-ray diffraction (XRD), while the surface morphology of the annealed samples was examined using scanning electron microscope (SEM). The optical band gap, refractive index and extinction coefficient were also calculated. The DSC scans showed that the melting temperature remains constant at 636.56 K. In addition, other characteristic temperatures such as the glass transition temperature, the onset crystallization temperature, and the crystallization peak temperature increase with increasing the heating rate. The crystalline phases for the as-prepared and annealed films consist of orthorhombic As, hexagonal Te, and monoclinic As2Te3 phases. Furthermore, the average crystallite size, strain, and dislocation density depend on the annealing temperature. The optical absorption results revealed that the investigated films have a direct transition, and their optical energy gap decreases from 1.82 eV to 1.49 eV as the annealing temperature increases up to 433 K. However, the refractive index, extinction coefficient, dielectric constant and the ratio of free carrier concentration to its effective mass, increase with increasing the annealing temperature.


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