scholarly journals Chemical Recycling of PET Wastes with Different Catalysts

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Mohammad Khoonkari ◽  
Amir Hossein Haghighi ◽  
Yahya Sefidbakht ◽  
Khadijeh Shekoohi ◽  
Abolfazl Ghaderian
Keyword(s):  
Ionic Liquids ◽  
Ethylene Glycol ◽  
Polyethylene Terephthalate ◽  
Chemical Processes ◽  
Metal Salts ◽  
Chemical Recycling ◽  
Sample Material ◽  
Pet Waste ◽  
The Subject ◽  
The One

Chemical recycling of polyethylene terephthalate, known as PET, has been the subject of increased interest as a valuable feedstock for different chemical processes. In this work, glycolysis of PET waste granules was carried out using excess ethylene glycol in the presence of different simple chemicals acting as catalysts, which are, namely, categorized in ionic liquids, metal salts, hydrotalcites, and enzymes. From every category, some materials as a sample were used, and the one which is going to bring the best result is noted. The effect of some parameters such as temperature, pressure, amount of sample, material ratio, and stirring rate was investigated. As a result we compared the best of each category with the others and final result is shown.

scholarly journals Metal-Containing Ionic Liquids: Highly Effective Catalysts for Degradation of Poly(Ethylene Terephthalate)

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Qun Feng Yue ◽  
Hua Guang Yang ◽  
Mi Lin Zhang ◽  
Xue Feng Bai
Keyword(s):  
Ionic Liquids ◽  
Ethylene Glycol ◽  
Qualitative Analysis ◽  
Reaction Temperature ◽  
Ethylene Terephthalate ◽  
Main Product ◽  
Local Market ◽  
Pet Waste ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene

Poly(ethylene terephthalate) (PET) waste from local market was depolymerized by ethylene glycol (EG) in the presence of metal-containing ionic liquids, and the qualitative analysis showed that the bis(hydroxyethyl) terephthalate (BHET) was the main product in this process. Compared with other metal-containing ionic liquids, [Bmim]ZnCl3was considered the best catalyst in the glycolysis of PET. When the reaction temperature was 180°C, the conversion of PET reached 97.9% and the BHET was yielded to 83.3% within 5 h. At the same time, [Bmim]ZnCl3could be reused for six times without obvious decrease in the yield of BHET. Additional, the effects of waste PET’s source and size were investigated.

scholarly journals Environment and plastics : A review on greener routes for plastic bottle (PET) waste management through recycling processes

2020 ◽  
Vol 15 (2) ◽  
pp. 105-110
Author(s):  
Swati Singh
Keyword(s):  
Polyethylene Terephthalate ◽  
Value Added ◽  
Waste Recycling ◽  
Operating Conditions ◽  
Chemical Recycling ◽  
Short Term ◽  
Research Papers ◽  
Pet Waste ◽  
Viable Solution ◽  
Value Added Products

Many research papers have been contributed by several authors for making polyethylene terephthalate (PET) waste recycling economically and ecologically more viable as it creates environmental hazards when disposed off after its short term use. Recycling of PET waste was started in last two decades. Most of the authors are devoting their time in getting economically viable solution for development of methods based on either mechanical or chemical recycling. Some success has been obtained in development of chemical recycling methods which provides value added products from PET waste. In this study the operating conditions and mechanism of various recycling processes available for the recycling of polyethylene terephthalate (PET) waste are reported and described.

scholarly journals Chemical Recycling: Comparative Study about the Depolymerization of PET Waste-Bottles to Obtain Terephthalic Acid

Proceedings ◽  
2019 ◽  
Vol 41 (1) ◽  
pp. 78
Author(s):  
Samir Cavalcante ◽  
Daniel Vieira ◽  
Isis Melo
Keyword(s):  
Terephthalic Acid ◽  
Potassium Hydroxide ◽  
Main Product ◽  
Ultra Performance Liquid Chromatography ◽  
Chemical Recycling ◽  
Pet Waste ◽  
Fourier Transformed Infrared Spectroscopy ◽  
Water As Solvent ◽  
The Subject ◽  
Packaging Industry

Currently, the plastic packaging industry in Brazil is the second largest producer in the packaging sector, with approximately 35% of the total packaging produced per year. Out of this total, 572 thousand tons are composed of polyethylene terephthalate plastic bottles (PET). In the ranking of the main materials discarded in the country, plastic occupies the third position and, in most cases, inadequately. Objectifying minimizes the amount of PET packaging improperly discarded and to instigate the industrial interest in the subject, our work pursued a viable path, as clean as possible in the principles of Green Chemistry, to depolymerize it. Obtaining the terephthalic acid as the main product, which is commercially obtained by oil sources and using salts and oxide of zinc as catalyzers in water as solvent, besides using inorganic bases as catalyzers in alcohols as solvent, including glycerol, which is a sub product of Biodiesel Industries. The reactions were made by refluxing (traditional way) and by microwave, where was used the reactor Biotage Initiator Plus. The products were characterized by Fourier Transformed Infrared Spectroscopy (FTIR of Bruker) and Ultra Performance Liquid Chromatography with Mass Spectrometer with Electrospray Ionization (UPLC-ESI/MS), where the results were better while using zinc sulfate as catalyzer in water and potassium hydroxide as catalyzer in pentan-1-ol.

“Channeling” the powers of God’s Word

2010 ◽  
Vol 4 (2) ◽  
pp. 135-156 ◽  
Author(s):  
Dorothea E. Schulz
Keyword(s):  
The Other ◽  
Border Zone ◽  
Focus Attention ◽  
Spiritual Power ◽  
New Materials ◽  
God's Word ◽  
Audio Recordings ◽  
Heated Debate ◽  
The Subject ◽  
The One

Starting with the controversial esoteric employment of audio recordings by followers of the charismatic Muslim preacher Sharif Haidara in Mali, the article explores the dynamics emerging at the interface of different technologies and techniques employed by those engaging the realm of the Divine. I focus attention on the “border zone” between, on the one hand, techniques for appropriating scriptures based on long-standing religious conventions, and, on the other, audio recording technologies, whose adoption not yet established authoritative and standardized forms of practice, thereby generating insecurities and becoming the subject of heated debate. I argue that “recyclage” aptly describes the dynamics of this “border zone” because it captures the ways conventional techniques of accessing the Divine are reassessed and reemployed, by integrating new materials and rituals. Historically, appropriations of the Qur’an for esoteric purposes have been widespread in Muslim West Africa. These esoteric appropriations are at the basis of the considerable continuities, overlaps and crossovers, between scripture-related esoteric practices on one side, and the treatment by Sharif Haidara’s followers of audio taped sermons as vessels of his spiritual power, on the other.

PHILOSOPHICAL PROPAEDEUTICS IN THE SYSTEM OF PRESCHOOL EDUCATION

2020 ◽  
Vol 22 (11) ◽  
pp. 11-15
Author(s):  
Gan N.Yu. ◽  
Ponomareva L.I. ◽  
Obukhova K.A.
Keyword(s):  
Modern Science ◽  
Preschool Education ◽  
Modern Society ◽  
Social Relevance ◽  
The Social ◽  
Moral Problems ◽  
The Subject ◽  
The One ◽  
The Individual ◽  
And Training

Today, worldview, spiritual and moral problems that have always been reflected in education and upbringing come to the fore in society. In this situation, there is a demand for philosophical categories. One of the priority goals of education in modern conditions is the formation of a reasonable, reflexive person who is able to analyze their actions and the actions of other people. Modern science is characterized by an understanding of the absolute value and significance of childhood in the development of the individual, which implies the need for its multilateral study. In the conditions of democratization of all spheres of life, the child ceases to be a passive object of education and training, and becomes an active carrier of their own meanings of being and the subject of world creation. One of the realities of childhood is philosophizing, so it is extremely timely to address the identification of its place and role in the world of childhood. Children's philosophizing is extremely poorly studied, although the need for its analysis is becoming more obvious. Children's philosophizing is one of the forms of philosophical reflection, which has its own qualitative specificity, on the one hand, and commonality with all other forms of philosophizing, on the other. The social relevance of the proposed research lies in the fact that children's philosophizing can be considered as an intellectual indicator of a child's socialization, since the process of reflection involves the adoption and development of culture. Modern society, in contrast to the traditional one, is ready to "accept" a philosophizing child, which means that it is necessary to determine the main characteristics and conditions of children's philosophizing.

The problem of woman’s emansipation in the feuilleton “Amazonia: a very inept story” by Mykola Chirsky

2020 ◽  
pp. 71-76
Author(s):  
Iryna Rusnak
Keyword(s):  
Scientific Understanding ◽  
The Other ◽  
Literary Studies ◽  
Ethical Guidelines ◽  
Compositional Structure ◽  
Urgent Task ◽  
The Subject ◽  
The One ◽  
Artistic Heritage

The author of the article analyses the problem of the female emancipation in the little-known feuilleton “Amazonia: A Very Inept Story” (1924) by Mykola Chirsky. The author determines the genre affiliation of the work and examines its compositional structure. Three parts are distinguished in the architectonics of associative feuilleton: associative conception; deployment of a “small” topic; conclusion. The author of the article clarifies the role of intertextual elements and the method of constantly switching the tone from serious to comic to reveal the thematic direction of the work. Mykola Chirsky’s interest in the problem of female emancipation is corresponded to the general mood of the era. The subject of ridicule in provocative feuilleton is the woman’s radical metamorphoses, since repulsive manifestations of emancipation becomes commonplace. At the same time, the writer shows respect for the woman, appreciates her femininity, internal and external beauty, personality. He associates the positive in women with the functions of a faithful wife, a caring mother, and a skilled housewife. In feuilleton, the writer does not bypass the problem of the modern man role in a family, but analyses the value and moral and ethical guidelines of his character. The husband’s bad habits receive a caricatured interpretation in the strange behaviour of relatives. On the one hand, the writer does not perceive the extremes brought by female emancipation, and on the other, he mercilessly criticises the male “virtues” of contemporaries far from the standard. The artistic heritage of Mykola Chirsky remains little studied. The urgent task of modern literary studies is the introduction of Mykola Chirsky’s unknown works into the scientific circulation and their thorough scientific understanding.

TARP DVIEJŲ KOLONŲ: XVIII A. PABAIGOS – XIX A. PRADŽIOS VILNIAUS MASONŲ KASDIENYBĖ SIMBOLIKOJE

2018 ◽  
pp. 144-163
Author(s):  
Daiva Milinkevičiūtė
Keyword(s):  
Daily Life ◽  
The Other ◽  
Daily Routine ◽  
The Past ◽  
Secular World ◽  
National Characteristics ◽  
Conservative Christian ◽  
The Subject ◽  
The One ◽  
Craft Guilds

The Age of Enlightenment is defined as the period when the universal ideas of progress, deism, humanism, naturalism and others were materialized and became a golden age for freemasons. It is wrong to assume that old and conservative Christian ideas were rejected. Conversely, freemasons put them into new general shapes and expressed them with the help of symbols in their daily routine. Symbols of freemasons had close ties with the past and gave them, on the one hand, a visible instrument, such as rituals and ideas to sense the transcendental, and on the other, intense gnostic aspirations. Freemasons put in a great amount of effort to improve themselves and to create their identity with the help of myths and symbols. It traces its origins to the biblical builders of King Solomon’s Temple, the posterity of the Templar Knights, and associations of the medieval craft guilds, which were also symbolical and became their link not only to each other but also to the secular world. In this work we analysed codified masonic symbols used in their rituals. The subject of our research is the universal Masonic idea and its aspects through the symbols in the daily life of the freemasons in Vilnius. Thanks to freemasons’ signets, we could find continuity, reception, and transformation of universal masonic ideas in the Lithuanian freemasonry and national characteristics of lodges. Taking everything into account, our article shows how the universal idea of freemasonry spread among Lithuanian freemasonry, and which forms and meanings it incorporated in its symbols. The objective of this research is to find a universal Masonic idea throughout their visual and oral symbols and see its impact on the daily life of the masons in Vilnius. Keywords: Freemasonry, Bible, lodge, symbols, rituals, freemasons’ signets.

Quantum Tunneling

2017 ◽  
Author(s):  
Frank S. Levin
Keyword(s):  
Quantum Tunneling ◽  
Alpha Particles ◽  
Attractive Potential ◽  
Scanning Tunneling ◽  
Finite Width ◽  
Potential Well ◽  
Surface Molecules ◽  
Repulsive Coulomb ◽  
The Subject ◽  
The One

Quantum tunneling, wherein a quanject has a non-zero probability of tunneling into and then exiting a barrier of finite width and height, is the subject of Chapter 13. The description for the one-dimensional case is extended to the barrier being inverted, which forms an attractive potential well. The first application of this analysis is to the emission of alpha particles from the decay of radioactive nuclei, where the alpha-nucleus attraction is modeled by a potential well and the barrier is the repulsive Coulomb potential. Excellent results are obtained. Ditto for the similar analysis of proton burning in stars and yet a different analysis that explains tunneling through a Josephson junction, the connector between two superconductors. The final application is to the scanning tunneling microscope, a device that allows the microscopic surfaces of solids to be mapped via electrons from the surface molecules tunneling into the tip of the STM probe.

Democracy and Political Culture

2019 ◽  
Author(s):  
Ross McKibbin
Keyword(s):  
Political Culture ◽  
Case Studies ◽  
Social System ◽  
Political System ◽  
Democratic Politics ◽  
Social Structures ◽  
The Political ◽  
The Subject ◽  
The One ◽  
Definition Of

This book is an examination of Britain as a democratic society; what it means to describe it as such; and how we can attempt such an examination. The book does this via a number of ‘case-studies’ which approach the subject in different ways: J.M. Keynes and his analysis of British social structures; the political career of Harold Nicolson and his understanding of democratic politics; the novels of A.J. Cronin, especially The Citadel, and what they tell us about the definition of democracy in the interwar years. The book also investigates the evolution of the British party political system until the present day and attempts to suggest why it has become so apparently unstable. There are also two chapters on sport as representative of the British social system as a whole as well as the ways in which the British influenced the sporting systems of other countries. The book has a marked comparative theme, including one chapter which compares British and Australian political cultures and which shows British democracy in a somewhat different light from the one usually shone on it. The concluding chapter brings together the overall argument.

Reactions

2011 ◽  
Author(s):  
Peter Atkins
Keyword(s):  
Chemical Reactions ◽  
Molecular Level ◽  
Chemical Processes ◽  
Chemical Formula ◽  
Complex Processes ◽  
Full Color ◽  
Chemistry Textbooks ◽  
Simple Chemical ◽  
The Subject ◽  
Solid Form

Illustrated with remarkable new full-color images--indeed, one or more on every page--and written by one of the world's leading authorities on the subject, Reactions offers a compact, pain-free tour of the inner workings of chemistry. Reactions begins with the chemical formula almost everyone knows--the formula for water, H2O--a molecule with an "almost laughably simple chemical composition." But Atkins shows that water is also rather miraculous--it is the only substance whose solid form is less dense than its liquid (hence ice floats in water)--and incredibly central to many chemical reactions, as it is an excellent solvent, being able to dissolve gases and many solids. Moreover, Atkins tells us that water is actually chemically aggressive, and can react with and destroy the compounds dissolved in it, and he shows us what happens at the molecular level when water turns to ice--and when it melts. Moving beyond water, Atkins slowly builds up a toolkit of basic chemical processes, including precipitation (perhaps the simplest of all chemical reactions), combustion, reduction, corrosion, electrolysis, and catalysis. He then shows how these fundamental tools can be brought together in more complex processes such as photosynthesis, radical polymerization, vision, enzyme control, and synthesis. Peter Atkins is the world-renowned author of numerous best-selling chemistry textbooks for students. In this crystal-clear, attractively illustrated, and insightful volume, he provides a fantastic introductory tour--in just a few hundred colorful and lively pages - for anyone with a passing or serious interest in chemistry.

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