scholarly journals Mechanical Properties and Durability of High-Performance Concretes Blended with Circulating Fluidized Bed Combustion Ash and Slag as Replacement for Ordinary Portland Cement

2020 ◽  
Vol 2020 ◽  
pp. 1-12
Author(s):  
Zhi Cheng ◽  
Lei He ◽  
Lan Liu ◽  
Zhijun Cheng ◽  
Xiaobo Pei ◽  
...  

This study investigates the mechanical properties and durability of three families of high-performance concrete (HPC), in which the first was blended with fly ash, the second with circulating fluidized bed combustion (CFBC) ash, and the third with CFBC slag. In addition to each of the three mineral additives, silica fume and a superplasticizer were also incorporated into the HPC. Hence, three families of HPC, containing 10%, 20%, and 30% mineral admixtures and 9% silica fume of the binder mass, respectively, were produced. The microstructure and hydration products of the HPC families were examined by scanning electron microscopy (SEM) and X-ray diffraction (XRD) to explore the influence of fly ash, CFBC ash, and CFBC slag on the compressive strength and frost resistance of HPC. The experimental results show that the compressive strength of HPC could reach 60 MPa at 28 d age. When the fly ash content was 30%, the compressive strength of HPC was 70.2 MPa at 28 d age; after the freeze-thaw cycle, the mass loss and strength loss of HPC were 0.63% and 8.9%, respectively. When the CFBC ash content was 20%, the compressive strength of HPC was 75 MPa at 28 d age. After the freeze-thaw cycle, the mass loss and strength loss of HPC were 0.17% and 0.81%, respectively.

Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 3
Author(s):  
Peeter Paaver ◽  
Päärn Paiste ◽  
Martin Liira ◽  
Kalle Kirsimäe

Mechanical activation of the calcium-rich fly ash formed in circulating fluidized bed combustion (CFBC) boilers was investigated to enhance the compressive strength performance of the pastes. We studied the effect of the activation on the physical, chemical, and mineral characteristics of fly ash and its pastes. Our study shows that already a short mechanical activation yields a 10-fold improvement in the compressive strength of the pastes, reaching 60 MPa after 90 days of curing without any chemical activation or blending. Mechanical activation caused fragmentation of large porous aggregates in the raw ash enhancing the physical properties and reactivity of fly ash particles. Similarly to calcium sulfoaluminate cements, the mechanical strength was provided by the formation of abundant ettringite and possibly C-(A)-S-H gel-like phase that created a highly compact microstructure. Our findings suggest that mechanically activated Ca-rich CFBC fly ash can be successfully used as an alternative binder.


2020 ◽  
Vol 22 (2) ◽  
pp. 94-100
Author(s):  
Antoni Antoni ◽  
Stacia Dwi Shenjaya ◽  
Maria Lupita ◽  
Samuel Santosa ◽  
David Wiyono ◽  
...  

Circulating fluidized bed combustion (CFBC) is a newer type of burner that employ a circulating process to burn fuel effectively. CFBC burning process is gaining more popularity due to its compact size, high efficiency and lower burning temperature compared to the pulverized coal combustion (PCC) burner. The CFBC burner produces fly ash with different physical properties compared to the PCC burner, i.e. the fly ash is not rounded, and required higher water content for comparable workability. The CFBC fly ash also has a high sulfur content that is detrimental for hardened concrete. Due to its drawbacks, the CFBC hardly used as cementitious material and geopolymer precursor. This study focuses on comparing variations in the concentration of NaOH solution and variations in the ratio of alkaline activators to the setting time and compressive strength of geopolymer mortars on a new class of CFBC fly ash, which have low sulfur content. The concentrations of NaOH solution were 6M, 8M, 10M, and 12M, while the alkaline activator ratios used were 3.0, 2.5, 2.0, 1.0, and 0.5. It was concluded that the low sulfur CFBC fly ash has a potential to be utilized as geopolymer precursor, however, with a shortcoming in its high water demand. The CFBC fly ash used in this study resulted in a geopolymer matrix with good compressive strength and stability. The water demand varies with the fly ash sampling time shows the challenges in the utilization of the fly ash. The highest mortar’s compressive strength, 33.4 MPa at 90 days was achieved at NaOH concentration of 8M and ratio of sodium silicate solution to sodium hydroxide solution of 2.5 with excellent stability.


2013 ◽  
Vol 838-841 ◽  
pp. 152-155 ◽  
Author(s):  
Guo Dong Zhang ◽  
Xiu Zhi Zhang ◽  
Zong Hui Zhou ◽  
Xin Cheng

High performance concrete was prepared by using iron tailings mixed with manufactured sand. Effects of the content of iron tailings on the performance of concrete were studied. The results show that the slump of concrete containing iron tailings is equal to concrete with river sand when the content of iron tailings is 60%. With the increase of the content of iron tailings, compressive strength of concrete shows a trend of decrease at same age; meanwhile drying shrinkage decreases and is less than the concrete prepared river sand. After 200 times of freeze-thaw cycle, mass loss of concrete with mixed sand is less than 5% and compressive strength loss is less than 25% which are close to concrete with river sand.


2018 ◽  
Vol 206 ◽  
pp. 02008
Author(s):  
Harry Hermawan ◽  
Ta-Peng Chang ◽  
Herry Suryadi Djayaprabha ◽  
Hoang-Anh Nguyen

This paper aims to examine the engineering properties of ternary blended no-cement mortar which subjected to the various elevated temperatures exposure. The mortars were produced by mixing ground granulated blast furnace slag (S), Type-F fly ash (F) and circulating fluidized bed combustion (CFBC) fly ash (C). The water-to-binder ratio was fixed at 0.40 and the CFBC fly ash content was fixed at 15 wt.% of the mixture that acts as the main activator. The specimens were exposed to the elevated temperatures ranging from 200°C to 800°C. The mass loss, compressive strength, and ultrasonic pulse velocity were determined before and after exposure to the elevated temperatures. The obtained results showed after exposed to high temperature, the mortar weight reduction was discovered in the range of 6.0–8.7% when temperature rose from 200°C to 600°C, and decreased significantly up to 12.4% as temperature reached 800°C. The major strength loss occurred after 600°C with the residual compressive strength approximately at 44.2%. At 200°C, increased strength was found on SFC mixture and when temperature rose to 400°C, the specimens still can resist the load reliably with the strength loss less than 8.0%. Consequently, SFC mortar generates good durability and heat resistance below 400°C.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3106
Author(s):  
Tomasz Kalak ◽  
Kinga Marciszewicz ◽  
Joanna Piepiórka-Stepuk

Recently, more and more attention has been paid to the removal of nickel ions due to their negative effects on the environment and human health. In this research, fly ash obtained as a result of incineration of municipal sewage sludge with the use of circulating fluidized bed combustion (CFBC) technology was used to analyze the possibility of removing Ni(II) ions in adsorption processes. The properties of the material were determined using analytical methods, such as SEM-EDS, XRD, BET, BJH, thermogravimetry, zeta potential, SEM, and FT-IR. Several factors were analyzed, such as adsorbent dose, initial pH, initial concentration, and contact time. As a result of the conducted research, the maximum sorption efficiency was obtained at the level of 99.9%. The kinetics analysis and isotherms showed that the pseudo-second order equation model and the Freundlich isotherm model best suited this process. In conclusion, sewage sludge fly ash may be a suitable material for the effective removal of nickel from wastewater and the improvement of water quality. This research is in line with current trends in the concepts of circular economy and sustainable development.


2014 ◽  
Vol 629-630 ◽  
pp. 306-313 ◽  
Author(s):  
Mao Chieh Chi ◽  
Ran Huang ◽  
Te Hsien Wu ◽  
Toun Chun Fou

Circulating fluidized bed combustion (CFBC) fly ash is a promising admixture for construction and building materials due to its pozzolanic activity and self-cementitious property. In this study, CFBC fly ash and coal-fired fly ash were used in Portland cement to investigate the pozzolanic and cementitious characteristics of CFBC fly ash and the properties of cement-based composites. Tests show that CFBC fly ash has the potential instead of cementing materials and as an alternative of pozzolan. In fresh specimens, the initial setting time of mortars increases with the increasing amount of cement replacement by CFBC fly ash and coal-fire fly ash. In harden specimens, adding CFBC fly ash to replace OPC reduces the compressive strength. Meanwhile, CFBC fly ash would results in a higher length change when adding over 30%. Based on the results, the amount of CFBC fly ash replacement cement was recommended to be limited below 20%.


2016 ◽  
Vol 722 ◽  
pp. 132-139 ◽  
Author(s):  
Tomáš Váchal ◽  
Rostislav Šulc ◽  
Tereza Janků ◽  
Pavel Svoboda

This paper describes chemical properties of fly ash from Circulating fluidized Bed Combustion (CFBC). There are shown thermal properties of fly ash using calorimetric measurement and the total content of calcium oxide CaO was determined. This paper describes the methods of measurement for determining these properties including granulometric measurement and chemical analysis. Also there were described and evaluated properties of fly ash and the reactivity of the fly ash was compared.


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