scholarly journals Modification Mechanism of Asphalt Modified with Rock Asphalt and Styrene-Butadiene Rubber (SBR)

2021 ◽  
Vol 2021 ◽  
pp. 1-9
Author(s):  
Xiangming Deng ◽  
Hui Huang ◽  
Bin Wang ◽  
Jie Chen

High-performance asphalt binder plays an important role in the durable asphalt pavement. Asphalt modified by rock asphalt (RA) is one of the high-performance modified asphalt materials. It was used in road engineering as a relatively environmentally friendly material, because rock asphalt takes some advantages of large reserves, easy treatment, and efficient modification. Moreover, the main component of rock asphalt is bitumen, which enables it to substitute part of the binder used in asphalt mixtures. On the other hand, the negative low-temperature performance of RA modified asphalt impeded its application in cold regions. The object of this paper is to improve the low-temperature performance of RA modified asphalt by compound modified with styrene-butadiene rubber (SBR). The 70-penetration grade binder and the RA modified asphalt with 15% RA by weight were applied as the base binder. Five types of RA-SBR modified asphalt were prepared, and the content of SBR was 2%, 4%, 5%, 6% and 8% by weight of BRA modified binder. The Fourier transform infrared spectroscopy (FTIR) tests were utilized to illustrate the reasons for the poor low-temperature performance of BRA modified asphalt and reveal the compound modification mechanism of BRA-SBR modified asphalt. The Brookfield viscosity test, dynamic shear rheometer test, and bending beam rheometer test were adopted to reveal the variation patterns of rheological behavior and low-temperature performance with mass contents of SBR. The test results indicated that the worse of low-temperature performance was caused by the increase of asphaltene content and the stress concentration due to ash in RA modified asphalt. And the compound modification is a physical process. The addition of SBR has improved the low-temperature performance of RA modified asphalt dramatically. And based on the rheological behaviors and low-temperature performance of RA-SBR compound modified asphalt, the optimum content of SBR was determined, which is about 4%∼5%.

Materials ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 2358 ◽  
Author(s):  
Xiyan Fan ◽  
Weiwei Lu ◽  
Songtao Lv ◽  
Fangwei He

To improve the low-temperature performance of the Buton rock asphalt (BRA)-modified asphalt, styrene-butadiene rubber (SBR) was added to it. The BRA-modified asphalt and SBR-BRA composite modified asphalt were prepared by high-speed shearing method. The penetration, softening point, ductility, and Brookfield viscosity of the two kinds of asphalt were measured. The dynamic shear rheometer (DSR) and the beam bending rheometer (BBR) were employed to research the performance of BRA-modified asphalt by adding SBR. The results showed that the pure asphalt in BRA was the main reason to reduce the low-temperature performance of neat asphalt when the content of BRA was 19%. However, the ash in BRA was the main factor to reduce the low-temperature performance when its content was more than 39.8%. When the BRA content was 59.8%, the SBR-BRA composite modified asphalt with SBR contents of 2%, 4%, 6%, and 8%, and it shows that the penetration and ductility of the BRA-modified asphalt are increased by the addition of SBR. The equivalent brittle point was reduced, the stiffness modulus was decreased, and the creep rate was increased. At the same time, the Brookfield viscosity was reduced and the rutting factor was increased. The stiffness modulus of the SBR-BRA composite modified asphalt mixture was increased. That is to say, when SBR was mixed into the BRA-modified asphalt, the low-temperature performance could be remarkably improved based on ensuring high-temperature performance. The low-temperature index of composite modified asphalt was analyzed. It was recommended to apply the equivalent brittle point to evaluate the low-temperature performance of SBR-BRA composite modified asphalt.


2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Haitao Zhang ◽  
Ying Wang ◽  
Zuoqiang Liu ◽  
Quansheng Sun

Although the aging asphalt and its regeneration were researched by many researchers, the poor low-temperature performance of regenerating asphalt has still not been solved yet. In this project, the composite technology of regeneration and modification will be used to solve the problem mentioned above. Through the investigation and analysis on the composite mechanism of regeneration and modification for aging asphalt, the objective of the project attempts to explore a method for the synchronized recovery of high- and low-temperature performance of aging asphalt. The research results show that the single regenerating technology cannot fully recover the low-temperature performance of aging asphalt, and the composite technology of regeneration and modification can make the performance of aging asphalt recovery well. The indexes of aging asphalt after composite regeneration and modification have been recovered, which are better than the indexes of 90# asphalt (25°C penetration is 80–100/0.1 mm) and close with the indexes of styrene-butadiene-styrene (SBS) modified asphalt. The project has demonstrated that the composite technology of regeneration and modification can make the high- and low-temperature performance of aging asphalt recovery well. The research results can obtain better economic and social benefits.


2013 ◽  
Vol 753-755 ◽  
pp. 715-718
Author(s):  
Xiu Hua Yang

SBS is a styrene - butadiene - styrene block copolymer, the addition of SBS of high and low temperature performance and road can be very good to improve the performance of asphalt. This paper studied the performance of the modified asphalt on the content of modifier.


Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 771
Author(s):  
Yu Sun ◽  
Dongpo He

The mixture of styreneic methyl copolymers (SMCs) normal temperature-modified asphalt and styrene-butadiene styrene block copolymer (SBS)-modified asphalt (SMCSBS) compound-modified asphalt was investigated in this study. The viscosity and temperature properties of compound modified asphalt (SMCSBS) were studied by Brookfield rotary viscosity test. Dynamic shear rheometer (DSR) and bending beam rheometer (BBR) were used to test SMCSBS compound modified asphalt with different SMC additions. Finally, the microstructure and physicochemical properties of SMCSBS were evaluated by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR), and the modification mechanism of the SMCSBS was studied. The results show that the viscosity of the compound-modified asphalt added with SMC is improved, which is conducive to improving its workability. With the increase of SMC content, the high-temperature performance of the compound modified asphalt firstly increases and then decreases with the increase of SMC content. When the content of SMC is 12%, its high-temperature performance is the best. Compared with SBS-modified asphalt, the SMCSBS has better low-temperature performance, and the creep stiffness S and creep rate m of the SMC with different content are better than that of SBS. Finally, the microcosmic characteristics show that the SMC can give full play to its characteristics and can be uniformly dispersed in SBS modified asphalt. SMC is essentially a surfactant, which can reduce the viscosity and construction temperature by changing the surface tension and surface free energy of asphalt molecules. The curing agent of epoxy resin is slowly cross-linked and cured after contacting with air to form a certain strength, thus improving the road performance of the asphalt mixture.


2019 ◽  
Vol 9 (3) ◽  
pp. 467 ◽  
Author(s):  
Chen Zhang ◽  
Hainian Wang ◽  
Zhanping You ◽  
Junfeng Gao ◽  
Muhammad Irfan

To uniform the evaluation indicators of Styrene-Butadiene-Styrene (SBS) modified asphalt, the SK70# and SK90# matrix asphalt were modified by different SBS modifier dosage in this study. The test methods in China and Superpave were used to test the performance of each SBS-modified asphalt respectively, from which the appropriate evaluation index of SBS-modified asphalt was determined. The results showed that the addition of SBS modifier improved the high temperature performance and lowered the temperature sensitivity of asphalt binder, while it increased the viscosity of asphalt binder in high temperatures. Due to the variability that appeared in the results of the penetration test by the swelling of SBS-modified asphalt, the penetration test was not recommended to evaluate the performances of SBS-modified asphalt. The softening point of SBS-modified asphalt with the modifier dosages of 4.5%, 5%, 5.5% and 6% increased 5.7%, 12.8%, 22.5% and 26.4% respectively compared to the matrix asphalt for SK70# matrix asphalt, and increased 21.2%, 26.3%, 33.6% and 46.6% respectively compared to the matrix asphalt for SK90# matrix asphalt. The effect of SBS-modifier on the softening point of SK90# matrix asphalt is significantly better than that of SK70# matrix asphalt. The improvement effect of SBS modifier on low temperature performance of matrix asphalt decreased with a decrease in test temperature. When studying the influence of the SBS modifier on the low temperature performance of asphalt binder, it was recommended to use the bending beam rheometer (BBR) test to evaluate the low temperature performance of SBS-modified asphalt.


Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5836
Author(s):  
Peifeng Cheng ◽  
Yiming Li ◽  
Zhanming Zhang

To improve the thermal-aging stability and rheological performance of styrene–butadiene rubber (SBR)-modified asphalt, phenolic resin (PF) was introduced in the process of preparing SBR-modified asphalt by melt blending. The effect of PF and SBR on the high and low-temperature rheological performance of the asphalt binder before and after aging was evaluated by a temperature and frequency sweep using a dynamic shear rheometer (DSR). Fourier transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC), and fluorescence microscopy (FM) were used to further investigate the effect of PF and SBR on the thermal stability and morphological characteristics of the asphalt binder. The results showed that the addition of PF can enhance the high-temperature deformation resistance and short-term aging resistance of SBR-modified asphalt. Moreover, PF and SBR form an embedded network structure within the asphalt binder and alleviate the deterioration of the polymer during the aging process. Compared with SBR-modified asphalt, the chemical system of composite-modified asphalt is more stable, and it can remain stable with an aging time of less than 5 h.


2013 ◽  
Vol 477-478 ◽  
pp. 1175-1178
Author(s):  
Ling Zou ◽  
Jing Wei Ne ◽  
Weng Gang Zhang

70# and 90# matrix asphalt mixture with MaR were studied through dynamic modulus test, rutting test, freeze-thaw splitting test, bending test to study the applicability of the Modifying agent of rubber plastic compound (MaR) in matrix asphalt mixture.Test results were Compared with SBSI-C modified asphalt mixture.The results indicate that: high-temperature stability of MaR+70# asphalt mixture is as well as SBSI-C modified asphalt mixture,and is bettere than MaR+90# asphalt mixture; water stability of MaR+90# asphalt mixture is bettere than SBSI-C modified asphalt mixture and MaR+70# asphalt mixture; low temperature performance of MaR+90# asphalt mixture is bettere than MaR+70# asphalt mixture, but is worse than modified asphalt mixture SBSI-C ; MaR+70# asphalt mixture can be first used in area of resisting high temperature and rutting, MaR+90# asphalt mixture can be used if the water stability performance and low temperature performance are considered.


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