Synthesis and Characterization of Ultrafine Poly(vinylalcohol phosphate) Coated Magnetite Nanoparticles

2006 ◽  
Vol 6 (3) ◽  
pp. 823-829 ◽  
Author(s):  
Sasmita Mohapatra ◽  
Nabakumar Pramanik ◽  
Sudip K. Ghosh ◽  
Panchanan Pramanik
Keyword(s):  
Particle Size ◽  
Magnetite Nanoparticles ◽  
Room Temperature ◽  
Colloidal Stability ◽  
Spinel Phase ◽  
Aqueous Suspension ◽  
Polymer Concentration ◽  
Aqueous Dispersion ◽  
Oxide Surface ◽  
The Impact

Nanosized magnetite (Fe3O4) particles showing superparamagnetism at room temperature have been prepared by controlled coprecipitation of Fe2+ and Fe3+ in presence of highly hydrophilic poly(vinylalcohol phosphate)(PVAP). The impact of polymer concentration on particle size, size distribution, colloidal stability, and magnetic property has been extensively studied. The aqueous suspension of magnetite, prepared using 1% PVAP solution is stable for four weeks at pH 5–8. X-ray diffractograms show the formation of nanocrystalline inverse spinel phase magnetite. Transmission Electron Microscopy confirmed well dispersed cubic magnetite particles of size of about 5.8 nm. Dynamic Light Scattering measurement shows narrow distribution of hydrodynamic size of particle aggregates. Infrared spectra of samples show strong Fe—O—P bond on the oxide surface. UV-visible studies show aqueous dispersion of magnetite formed by using 1% PVAP solution is stable at least for four weeks without any detoriation of particle size. Magnetization measurements at room temperature show superparamagnetic nature of polymer coated magnetite nanoparticles.

One-Pot Synthesis of Water Soluble, Extremely Small-Sized Superparamagnetic Magnetite Nanoparticles

2012 ◽  
Vol 531 ◽  
pp. 219-222
Author(s):  
Li Hua Shen ◽  
Ting Shang ◽  
Jun Zhou ◽  
Dong Wang ◽  
Yu Han ◽  
...  
Keyword(s):  
Magnetite Nanoparticles ◽  
Room Temperature ◽  
Colloidal Stability ◽  
Aqueous Media ◽  
Mri Contrast Agents ◽  
Water Soluble ◽  
Potential Candidate ◽  
One Pot ◽  
Mri Contrast

Extremely small-sized superparamagnetic magnetite nanoparticles of 3Cit). The resulting Cit-coated magnetite nanoparticles exhibited long-term colloidal stability in aqueous media without any surface modification. Regarding the magnetic properties, the nanoparticles were superparamagnetic at room temperature, and might be the potential candidate for MRI contrast agents.

scholarly journals Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal Stability

Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1557
Author(s):  
Kim Waulthers ◽  
Ryan van Zandvoort ◽  
Sam Castermans ◽  
Jeroen Welzen ◽  
Evelien Baeten ◽  
...  
Keyword(s):  
Particle Size ◽  
Chain Length ◽  
Colloidal Stability ◽  
Polymer Particles ◽  
Polystyrene Nanoparticles ◽  
Sodium Chloride Solutions ◽  
Surface Functionality ◽  
Reactive Surfactants ◽  
Emulsion Polymerisation ◽  
The Impact

Reactive surfactants (surfmers), which are covalently attached to the surface of sub-micron sized polymer particles during emulsion polymerisation, are applied to tailor the surface functionality of polymer particles for an application of choice. We present a systematic study on the use of oligoglycidol-functionalised styrene macromolecules as surfmers in the emulsion polymerization of styrene. Firstly, we report the impact of the surfmer concentration on the particle size for polymerisations performed above and below the critical micelle concentration. Secondly, we report the influence of the oligoglycidol chain length on the particle size. Thirdly, we conducted experiments to analyse the influence of the surfmer concentration and its chain length on the colloidal stability of the aqueous polystyrene nanoparticles in sodium chloride solutions. We demonstrated that the size of polystyrene particles could be influenced by changing both the surfmer concentration and its chain length. Furthermore, we showed that the colloidal stability of the oligoglycidol-functionalized polystyrene particles is dependent on the particle size, and not directly related to the oligoglycidol chain length.

Effect of pH on the Structural and Magnetic Properties of Magnetite Nanoparticles Synthesised by Co-Precipitation

2011 ◽  
Vol 324 ◽  
pp. 129-132 ◽  
Author(s):  
Wegdan Ramadan ◽  
Marwa Kareem ◽  
Béatrice Hannoyer ◽  
Shanta Saha
Keyword(s):  
Particle Size ◽  
Raman Spectroscopy ◽  
Magnetic Properties ◽  
Magnetite Nanoparticles ◽  
Room Temperature ◽  
Ph Value ◽  
Magnetite Fe3o4 ◽  
Aqueous Method ◽  
Structural And Magnetic Properties ◽  
Co Precipitation

Magnetite, Fe3O4, nanoparticles were synthesized using co-precipitation aqueous method at room temperature and at different pH, from 8 to 12.5. The pH value was found to influence greatly the resulting phases and has no significant effect on the particle size. In all cases, magnetite was found to be the main phase but the contribution of Goethite phase was identified clearly with the increase in pH. Significant reduction in saturation magnetization was evident. Structural and magnetic properties of the nanoparticles were examined using; XRD, TEM, Raman Spectroscopy and SQUID.

Seed-mediated synthesis and PEG coating of gold nanoparticles for controlling morphology and sizes

MRS Advances ◽  
2020 ◽  
Vol 5 (63) ◽  
pp. 3353-3360
Author(s):  
Susana Helena Arellano Ramírez ◽  
Perla García Casillas ◽  
Christian Chapa González
Keyword(s):  
Gold Nanoparticles ◽  
Polyethylene Glycol ◽  
Room Temperature ◽  
Colloidal Stability ◽  
Infrared Spectrometry ◽  
Ammonium Bromide ◽  
Chloroauric Acid ◽  
Vis Spectroscopy ◽  
Seed Mediated ◽  
Peg Coating

AbstractA significant area of research is biomedical applications of nanoparticles which involves efforts to control the physicochemical properties through simple and scalable processes. Gold nanoparticles have received considerable attention due to their unique properties that they exhibit based on their morphology. Gold nanospheres (AuNSs) and nanorods (AuNRs) were prepared with a seed-mediated method followed of polyethylene glycol (PEG)-coating. The seeds were prepared with 0.1 M cetyltrimethyl-ammonium bromide (CTAB), 0.005 M chloroauric acid (HAuCl4), and 0.01 M sodium borohydride (NaBH4) solution. Gold nanoparticles with spherical morphology was achieved by growth by aggregation at room temperature, while to achieve the rod morphology 0.1 M silver nitrate (AgNO3) and 0.1 M ascorbic acid solution were added. The gold nanoparticles obtained by the seed-mediated synthesis have spherical or rod shapes, depending on the experimental conditions, and a uniform particle size. Surface functionalization was developed using polyethylene glycol. Morphology, and size distribution of AuNPs were evaluated by Field Emission Scanning Electron Microscopy. The average size of AuNSs, and AuNRs was 7.85nm and 7.96 x 31.47nm respectively. Fourier transform infrared spectrometry was performed to corroborate the presence of PEG in the AuNPs surface. Additionally, suspensions of AuNSs and AuNRs were evaluated by UV-Vis spectroscopy. Gold nanoparticles were stored for several days at room temperature and it was observed that the colloidal stability increased once gold nanoparticles were coated with PEG due to the shield formed in the surface of the NPs and the increase in size which were 9.65±1.90 nm of diameter for AuNSs and for AuNRs were 29.03±5.88 and 8.39±1.02 nm for length and transverse axis, respectively.

The Impact of Bioconjugation on the Interfacial Activity of a Protein Biosurfactant

2018 ◽  
Author(s):  
Hossam H Tayeb ◽  
Marina Stienecker ◽  
Anton Middelberg ◽  
Frank Sainsbury
Keyword(s):  
Polyethylene Glycol ◽  
Colloidal Stability ◽  
Point Mutations ◽  
Pharmaceutical Formulations ◽  
Industrial Processes ◽  
Parent Molecule ◽  
Site Specific ◽  
Interfacial Activity ◽  
Surface Active ◽  
The Impact

Biosurfactants, are surface active molecules that can be produced by renewable, industrially scalable biologic processes. DAMP4, a designer biosurfactant, enables the modification of interfaces via genetic or chemical fusion to functional moieties. However, bioconjugation of addressable amines introduces heterogeneity that limits the precision of functionalization as well as the resolution of interfacial characterization. Here we designed DAMP4 variants with cysteine point mutations to allow for site-specific bioconjugation. The DAMP4 variants were shown to retain the structural stability and interfacial activity characteristic of the parent molecule, while permitting efficient and specific conjugation of polyethylene glycol (PEG). PEGylation results in a considerable reduction on the interfacial activity of both single and double mutants. Comparison of conjugates with one or two conjugation sites shows that both the number of conjugates as well as the mass of conjugated material impacts the interfacial activity of DAMP4. As a result, the ability of DAMP4 variants with multiple PEG conjugates to impart colloidal stability on peptide-stabilized emulsions is reduced. We suggest that this is due to constraints on the structure of amphiphilic helices at the interface. Specific and efficient bioconjugation permits the exploration and investigation of the interfacial properties of designer protein biosurfactants with molecular precision. Our findings should therefore inform the design and modification of biosurfactants for their increasing use in industrial processes, and nutritional and pharmaceutical formulations.

scholarly journals Waterfall Algorithm as a tool of investigation the geometrical features of granular porous media

2021 ◽  
Author(s):  
Wojciech Sobieski
Keyword(s):  
Particle Size ◽  
Porous Media ◽  
Lattice Boltzmann ◽  
Granular Media ◽  
Density Ratio ◽  
Geometrical Features ◽  
Granular Porous Media ◽  
Collision Density ◽  
Boltzmann Method ◽  
The Impact

AbstractThe paper describes the so-called Waterfall Algorithm, which may be used to calculate a set of parameters characterising the spatial structure of granular porous media, such as shift ratio, collision density ratio, consolidation ratio, path length and minimum tortuosity. The study is performed for 1800 different two-dimensional random pore structures. In each geometry, 100 individual paths are calculated. The impact of porosity and the particle size on the above-mentioned parameters is investigated. It was stated in the paper, that the minimum tortuosity calculated by the Waterfall Algorithm cannot be used directly as a representative tortuosity of pore channels in the Kozeny or the Carman meaning. However, it may be used indirect by making the assumption that a unambiguous relationship between the representative tortuosity and the minimum tortuosity exists. It was also stated, that the new parameters defined in the present study are sensitive on the porosity and the particle size and may be therefore applied as indicators of the geometry structure of granular media. The Waterfall Algorithm is compared with other methods of determining the tortuosity: A-Star Algorithm, Path Searching Algorithm, Random Walk technique, Path Tracking Method and the methodology of calculating the hydraulic tortuosity based on the Lattice Boltzmann Method. A very short calculation time is the main advantage of the Waterfall Algorithm, what meant, that it may be applied in a very large granular porous media.

scholarly journals Evaluation of Marblewood Dust’s (Marmaroxylon racemosum) Effect on Ignition Risk

2021 ◽  
Vol 11 (15) ◽  
pp. 6874
Author(s):  
Miroslava Vandličkova ◽  
Iveta Markova ◽  
Katarina Holla ◽  
Stanislava Gašpercová
Keyword(s):  
Particle Size ◽  
Dust Particles ◽  
Wood Dust ◽  
Sieve Analysis ◽  
Granulometric Analysis ◽  
Analysis Measurement ◽  
Risk Research ◽  
Minimum Ignition Temperature ◽  
The Impact

The paper deals with the selected characteristics, such as moisture, average bulk density, and fraction size, of tropical marblewood dust (Marmaroxylon racemosum) that influence its ignition risk. Research was focused on sieve analysis, granulometric analysis, measurement of moisture level in the dust, and determination of the minimum ignition temperatures of airborne tropical dust and dust layers. Samples were prepared using a Makita 9556CR 1400W grinder and K36 sandpaper for the purpose of selecting the percentages of the various fractions (<63, 63, 71, 100, 200, 315, 500 μm). The samples were sized on an automatic vibratory sieve machine Retsch AS 200. More than 65% of the particles were determined to be under 100 μm. The focus was on microfractions of tropical wood dust (particles with a diameter of ≤100 µm) and on the impact assessment of particle size (particle size <100 µm) on the minimum ignition temperatures of airborne tropical dust and dust layers. The minimum ignition temperature of airborne marblewood dust decreased with the particle size to the level of 400 °C (particle size 63 μm).

scholarly journals 3D Printing of Drug Nanocrystals for Film Formulations

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 3941
Author(s):  
Giorgia Germini ◽  
Leena Peltonen
Keyword(s):  
Particle Size ◽  
3D Printing ◽  
Polymer Films ◽  
Film Studies ◽  
Polymer Concentration ◽  
Physicochemical Characterization ◽  
Methyl Cellulose ◽  
Polymeric Film ◽  
Content Uniformity ◽  
3D Printed

The aim of the study was to prepare indomethacin nanocrystal-loaded, 3D-printed, fast-dissolving oral polymeric film formulations. Nanocrystals were produced by the wet pearl milling technique, and 3D printing was performed by the semi-solid extrusion method. Hydroxypropyl methyl cellulose (HPMC) was the film-forming polymer, and glycerol the plasticizer. In-depth physicochemical characterization was made, including solid-state determination, particle size and size deviation analysis, film appearance evaluation, determination of weight variation, thickness, folding endurance, drug content uniformity, and disintegration time, and drug release testing. In drug nanocrystal studies, three different stabilizers were tested. Poloxamer F68 produced the smallest and most homogeneous particles, with particle size values of 230 nm and PI values below 0.20, and was selected as a stabilizer for the drug-loaded film studies. In printing studies, the polymer concentration was first optimized with drug-free formulations. The best mechanical film properties were achieved for the films with HPMC concentrations of 2.85% (w/w) and 3.5% (w/w), and these two HPMC levels were selected for further drug-loaded film studies. Besides, in the drug-loaded film printing studies, three different drug levels were tested. With the optimum concentration, films were flexible and homogeneous, disintegrated in 1 to 2.5 min, and released the drug in 2–3 min. Drug nanocrystals remained in the nano size range in the polymer films, particle sizes being in all film formulations from 300 to 500 nm. When the 3D-printed polymer films were compared to traditional film-casted polymer films, the physicochemical behavior and pharmaceutical performance of the films were very similar. As a conclusion, 3D printing of drug nanocrystals in oral polymeric film formulations is a very promising option for the production of immediate-release improved- solubility formulations.

Mechanical Response of Porous Copper Manufactured by Lost Carbonate Sintering Process

2007 ◽  
Vol 539-543 ◽  
pp. 1863-1867 ◽  
Author(s):  
X.F. Tao ◽  
Li Ping Zhang ◽  
Y.Y. Zhao
Keyword(s):  
Particle Size ◽  
Flexural Strength ◽  
Relative Density ◽  
Mechanical Response ◽  
Compaction Pressure ◽  
Absorption Capacity ◽  
Energy Absorption Capacity ◽  
Three Point Bending ◽  
Porous Copper ◽  
The Impact

This paper investigated the mechanical response of porous copper manufactured by LCS under three-point bending and Charpy impact conditions. The effects of the compaction pressure and K2CO3 particle size used in producing the porous copper samples and the relative density of the samples were studied. The apparent modulus, flexural strength and energy absorption capacity in three-point bending tests increased exponentially with increasing relative density. The impact strength was not markedly sensitive to relative density and had values within 7 – 9 kJ/m2 for the relative densities in the range 0.17 – 0.31. The amount of energy absorbed by a porous copper sample in the impact test was much higher than that absorbed in the three-point bending test, impling that loading strain rate had a significant effect on the deformation mechanisms. Increasing compaction pressure and increasing K2CO3 particle size resulted in significant increases in the flexural strength and the bending energy absorption capacity, both owing to the reduced sintering defects.

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