scholarly journals Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal Stability

Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1557
Author(s):  
Kim Waulthers ◽  
Ryan van Zandvoort ◽  
Sam Castermans ◽  
Jeroen Welzen ◽  
Evelien Baeten ◽  
...  
Keyword(s):  
Particle Size ◽  
Chain Length ◽  
Colloidal Stability ◽  
Polymer Particles ◽  
Polystyrene Nanoparticles ◽  
Sodium Chloride Solutions ◽  
Surface Functionality ◽  
Reactive Surfactants ◽  
Emulsion Polymerisation ◽  
The Impact

Reactive surfactants (surfmers), which are covalently attached to the surface of sub-micron sized polymer particles during emulsion polymerisation, are applied to tailor the surface functionality of polymer particles for an application of choice. We present a systematic study on the use of oligoglycidol-functionalised styrene macromolecules as surfmers in the emulsion polymerization of styrene. Firstly, we report the impact of the surfmer concentration on the particle size for polymerisations performed above and below the critical micelle concentration. Secondly, we report the influence of the oligoglycidol chain length on the particle size. Thirdly, we conducted experiments to analyse the influence of the surfmer concentration and its chain length on the colloidal stability of the aqueous polystyrene nanoparticles in sodium chloride solutions. We demonstrated that the size of polystyrene particles could be influenced by changing both the surfmer concentration and its chain length. Furthermore, we showed that the colloidal stability of the oligoglycidol-functionalized polystyrene particles is dependent on the particle size, and not directly related to the oligoglycidol chain length.

Impact of Molecular Chain Structure of Suspension Phase on Giant Electrorheological Performance

2022 ◽  
Author(s):  
Hanqi Xu ◽  
Jinbo Wu ◽  
Yaying Hong ◽  
Weijia Wen
Keyword(s):  
Yield Stress ◽  
Chain Length ◽  
Colloidal Stability ◽  
Chain Structure ◽  
Solid Particles ◽  
High Yield ◽  
Suspension Stability ◽  
Chain Lengths ◽  
The Impact ◽  
Oil Particles

Abstract We demonstrate the impact of diester structure, in particular the alkyl chain length and branching structure, on the giant electrorheological (GER) effect and suspension stability. The existence of oil-particles interaction is of critical importance to induce the GER effect. To quantify GER performance and colloidal stability, we examine the yield stress, current density, field-off viscosity and sedimentation ratio with respect to the variation of chain length and branching structure. The oil-particles interaction is quantitatively analyzed by investigating the cluster size of particles in different diesters by a multiple light scattering analyzer, along with the wettability of different chain lengths of diesters and solid particles by the Washburn method. Our results indicate that long chain lengths favor the formation of particle agglomerates, thereby enhancing the GER effect (such as high yield stress). The attachment of branches on diester causes the formation of electronic correlation between branches and main chain, depending on the position of branches located, and hence results in superior GER performance and favorable suspension stability. An optimal GER fluid constituted by bis(2-ethylhexyl) sebacate is acquired with the achieved yield stress of 113 kPa at electric field strength of 4 kV/ mm and the prominent integrated GER properties.

Synthesis and Characterization of Ultrafine Poly(vinylalcohol phosphate) Coated Magnetite Nanoparticles

2006 ◽  
Vol 6 (3) ◽  
pp. 823-829 ◽  
Author(s):  
Sasmita Mohapatra ◽  
Nabakumar Pramanik ◽  
Sudip K. Ghosh ◽  
Panchanan Pramanik
Keyword(s):  
Particle Size ◽  
Magnetite Nanoparticles ◽  
Room Temperature ◽  
Colloidal Stability ◽  
Spinel Phase ◽  
Aqueous Suspension ◽  
Polymer Concentration ◽  
Aqueous Dispersion ◽  
Oxide Surface ◽  
The Impact

Nanosized magnetite (Fe3O4) particles showing superparamagnetism at room temperature have been prepared by controlled coprecipitation of Fe2+ and Fe3+ in presence of highly hydrophilic poly(vinylalcohol phosphate)(PVAP). The impact of polymer concentration on particle size, size distribution, colloidal stability, and magnetic property has been extensively studied. The aqueous suspension of magnetite, prepared using 1% PVAP solution is stable for four weeks at pH 5–8. X-ray diffractograms show the formation of nanocrystalline inverse spinel phase magnetite. Transmission Electron Microscopy confirmed well dispersed cubic magnetite particles of size of about 5.8 nm. Dynamic Light Scattering measurement shows narrow distribution of hydrodynamic size of particle aggregates. Infrared spectra of samples show strong Fe—O—P bond on the oxide surface. UV-visible studies show aqueous dispersion of magnetite formed by using 1% PVAP solution is stable at least for four weeks without any detoriation of particle size. Magnetization measurements at room temperature show superparamagnetic nature of polymer coated magnetite nanoparticles.

The Impact of Bioconjugation on the Interfacial Activity of a Protein Biosurfactant

2018 ◽  
Author(s):  
Hossam H Tayeb ◽  
Marina Stienecker ◽  
Anton Middelberg ◽  
Frank Sainsbury
Keyword(s):  
Polyethylene Glycol ◽  
Colloidal Stability ◽  
Point Mutations ◽  
Pharmaceutical Formulations ◽  
Industrial Processes ◽  
Parent Molecule ◽  
Site Specific ◽  
Interfacial Activity ◽  
Surface Active ◽  
The Impact

Biosurfactants, are surface active molecules that can be produced by renewable, industrially scalable biologic processes. DAMP4, a designer biosurfactant, enables the modification of interfaces via genetic or chemical fusion to functional moieties. However, bioconjugation of addressable amines introduces heterogeneity that limits the precision of functionalization as well as the resolution of interfacial characterization. Here we designed DAMP4 variants with cysteine point mutations to allow for site-specific bioconjugation. The DAMP4 variants were shown to retain the structural stability and interfacial activity characteristic of the parent molecule, while permitting efficient and specific conjugation of polyethylene glycol (PEG). PEGylation results in a considerable reduction on the interfacial activity of both single and double mutants. Comparison of conjugates with one or two conjugation sites shows that both the number of conjugates as well as the mass of conjugated material impacts the interfacial activity of DAMP4. As a result, the ability of DAMP4 variants with multiple PEG conjugates to impart colloidal stability on peptide-stabilized emulsions is reduced. We suggest that this is due to constraints on the structure of amphiphilic helices at the interface. Specific and efficient bioconjugation permits the exploration and investigation of the interfacial properties of designer protein biosurfactants with molecular precision. Our findings should therefore inform the design and modification of biosurfactants for their increasing use in industrial processes, and nutritional and pharmaceutical formulations.

scholarly journals Waterfall Algorithm as a tool of investigation the geometrical features of granular porous media

2021 ◽  
Author(s):  
Wojciech Sobieski
Keyword(s):  
Particle Size ◽  
Porous Media ◽  
Lattice Boltzmann ◽  
Granular Media ◽  
Density Ratio ◽  
Geometrical Features ◽  
Granular Porous Media ◽  
Collision Density ◽  
Boltzmann Method ◽  
The Impact

AbstractThe paper describes the so-called Waterfall Algorithm, which may be used to calculate a set of parameters characterising the spatial structure of granular porous media, such as shift ratio, collision density ratio, consolidation ratio, path length and minimum tortuosity. The study is performed for 1800 different two-dimensional random pore structures. In each geometry, 100 individual paths are calculated. The impact of porosity and the particle size on the above-mentioned parameters is investigated. It was stated in the paper, that the minimum tortuosity calculated by the Waterfall Algorithm cannot be used directly as a representative tortuosity of pore channels in the Kozeny or the Carman meaning. However, it may be used indirect by making the assumption that a unambiguous relationship between the representative tortuosity and the minimum tortuosity exists. It was also stated, that the new parameters defined in the present study are sensitive on the porosity and the particle size and may be therefore applied as indicators of the geometry structure of granular media. The Waterfall Algorithm is compared with other methods of determining the tortuosity: A-Star Algorithm, Path Searching Algorithm, Random Walk technique, Path Tracking Method and the methodology of calculating the hydraulic tortuosity based on the Lattice Boltzmann Method. A very short calculation time is the main advantage of the Waterfall Algorithm, what meant, that it may be applied in a very large granular porous media.

scholarly journals Evaluation of Marblewood Dust’s (Marmaroxylon racemosum) Effect on Ignition Risk

2021 ◽  
Vol 11 (15) ◽  
pp. 6874
Author(s):  
Miroslava Vandličkova ◽  
Iveta Markova ◽  
Katarina Holla ◽  
Stanislava Gašpercová
Keyword(s):  
Particle Size ◽  
Dust Particles ◽  
Wood Dust ◽  
Sieve Analysis ◽  
Granulometric Analysis ◽  
Analysis Measurement ◽  
Risk Research ◽  
Minimum Ignition Temperature ◽  
The Impact

The paper deals with the selected characteristics, such as moisture, average bulk density, and fraction size, of tropical marblewood dust (Marmaroxylon racemosum) that influence its ignition risk. Research was focused on sieve analysis, granulometric analysis, measurement of moisture level in the dust, and determination of the minimum ignition temperatures of airborne tropical dust and dust layers. Samples were prepared using a Makita 9556CR 1400W grinder and K36 sandpaper for the purpose of selecting the percentages of the various fractions (<63, 63, 71, 100, 200, 315, 500 μm). The samples were sized on an automatic vibratory sieve machine Retsch AS 200. More than 65% of the particles were determined to be under 100 μm. The focus was on microfractions of tropical wood dust (particles with a diameter of ≤100 µm) and on the impact assessment of particle size (particle size <100 µm) on the minimum ignition temperatures of airborne tropical dust and dust layers. The minimum ignition temperature of airborne marblewood dust decreased with the particle size to the level of 400 °C (particle size 63 μm).

Mechanical Response of Porous Copper Manufactured by Lost Carbonate Sintering Process

2007 ◽  
Vol 539-543 ◽  
pp. 1863-1867 ◽  
Author(s):  
X.F. Tao ◽  
Li Ping Zhang ◽  
Y.Y. Zhao
Keyword(s):  
Particle Size ◽  
Flexural Strength ◽  
Relative Density ◽  
Mechanical Response ◽  
Compaction Pressure ◽  
Absorption Capacity ◽  
Energy Absorption Capacity ◽  
Three Point Bending ◽  
Porous Copper ◽  
The Impact

This paper investigated the mechanical response of porous copper manufactured by LCS under three-point bending and Charpy impact conditions. The effects of the compaction pressure and K2CO3 particle size used in producing the porous copper samples and the relative density of the samples were studied. The apparent modulus, flexural strength and energy absorption capacity in three-point bending tests increased exponentially with increasing relative density. The impact strength was not markedly sensitive to relative density and had values within 7 – 9 kJ/m2 for the relative densities in the range 0.17 – 0.31. The amount of energy absorbed by a porous copper sample in the impact test was much higher than that absorbed in the three-point bending test, impling that loading strain rate had a significant effect on the deformation mechanisms. Increasing compaction pressure and increasing K2CO3 particle size resulted in significant increases in the flexural strength and the bending energy absorption capacity, both owing to the reduced sintering defects.

scholarly journals Effect of Particle Size Distribution on Powder Packing and Sintering in Binder Jetting Additive Manufacturing of Metals

2017 ◽  
Vol 139 (8) ◽  
Author(s):  
Yun Bai ◽  
Grady Wagner ◽  
Christopher B. Williams
Keyword(s):  
Particle Size ◽  
Additive Manufacturing ◽  
Large Degree ◽  
Full Density ◽  
Powder Particle Size ◽  
Powder Mixtures ◽  
Fine Powders ◽  
Sintering Shrinkage ◽  
The Impact ◽  
Binder Jetting

The binder jetting additive manufacturing (AM) process provides an economical and scalable means of fabricating complex parts from a wide variety of materials. While it is often used to fabricate metal parts, it is typically challenging to fabricate full density parts without large degree of sintering shrinkage. This can be attributed to the inherently low green density and the constraint on powder particle size imposed by challenges in recoating fine powders. To address this issue, the authors explored the use of bimodal powder mixtures in the context of binder jetting of copper. A variety of bimodal powder mixtures of various particle diameters and mixing ratios were printed and sintered to study the impact of bimodal mixtures on the parts' density and shrinkage. It was discovered that, compared to parts printed with monosized fine powders, the use of bimodal powder mixtures improves the powder's packing density (8.2%) and flowability (10.5%), and increases the sintered density (4.0%) while also reducing the sintering shrinkage (6.4%).

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