Ni3S2/Ni(OH)2 Directly Grown on Ni Foam for Battery-Type Electrode with Super Long Cycle Stability

2020 ◽  
Vol 20 (8) ◽  
pp. 4722-4729
Author(s):  
Chunli Guo ◽  
Li Wang ◽  
Zeying Yan ◽  
Yuyu Zhang ◽  
Jie Li ◽  
...  

The Ni3S2/Ni(OH)2 electrode could deliver a high areal capacity of 1.58 C/cm2 at 2 mA/cm2, along with outstanding cycling stability (113% capacity retention after 30,000 cycles). The energy density of the Ni3S2/Ni(OH)2//AC hybrid device was 30.23 Wh/kg at a power density of 155 W/kg (15.5 Wh/kg at 3,875 W/kg). Compared with other Ni(OH)2 composites on Ni foam, these results indicate that Ni3S2/Ni(OH)2 directly grown on Ni foam opens up the potential application for energystorage devices with high areal capacity and high cycling performance.

2018 ◽  
Vol 54 (83) ◽  
pp. 11773-11776 ◽  
Author(s):  
Qian Liu ◽  
Ling Fan ◽  
Ruifang Ma ◽  
Suhua Chen ◽  
Xinzhi Yu ◽  
...  

An Sb@G@C electrode exhibits an outstanding long cycle stability over 800 cycles with a capacity retention as high as 72.3%.


RSC Advances ◽  
2015 ◽  
Vol 5 (129) ◽  
pp. 107098-107104 ◽  
Author(s):  
Chuanshen Wang ◽  
Yi Xi ◽  
Chenguo Hu ◽  
Shuge Dai ◽  
Mingjun Wang ◽  
...  

A β-NiMoO4 NW supercapacitor lights one LED for 260 s and delivers a large specific capacitance (414.7 F g−1 at 0.25 A g−1), high energy density (36.86 W h kg−1), a maximum power density of 1100 W kg−1 and 65.96% capacity retention after 6000 cycles.


Author(s):  
Jun Song ◽  
Lijun Du ◽  
Jingyi Wang ◽  
Huaiping Zhang ◽  
Yaodong Zhang ◽  
...  

The NiS nanosheets were fabricated using one-step microwave approach with the microwave radiation of 800 W for 1.5 min. Impressively, the NiS nanosheets revealed praiseworthy electrochemical performance, with a capacitance value of 1082.8 F ⋅ g[Formula: see text] at 1 A ⋅ g[Formula: see text] and 77.8% retention over 5000 cycles at 5 A ⋅ g[Formula: see text]. Moreover, an asymmetric supercapacitor was assembled with NiS as the positive electrode and activated carbon (AC) as the negative electrode. It shows 80.42% capacity retention after 8000 cycles and an energy density of 19.45 W ⋅ h ⋅ kg[Formula: see text] at a power density of 801.05 W ⋅ kg[Formula: see text].


2013 ◽  
Vol 1540 ◽  
Author(s):  
Jong-Moon Lee ◽  
Soon-Kie Hong ◽  
Won Il Cho ◽  
In-Hyeong Yeo ◽  
Sun-il Mho

ABSTRACTIn order to improve the charge/discharge cycling performance of the LiMn2O4 cathode, the spinel LiMn2O4 is coated on the structurally stable SiO2 nanosphere cores, LiMn2O4@SiO2. The core-shell LiMn2O4@SiO2 nanosphere cathodes are prepared by the MnCO3 precipitation on the silica surface and the following solid state reaction of MnCO3@SiO2 with a lithium salt. The charge/discharge cycle stability has improved by the nanostructural characteristics of the LiMn2O4@ shell on the SiO2 core. The cathode composed of LiMn2O4@SiO2 nanospheres exhibits higher capacity retention of 97% than that of LiMn2O4 nanoparticles of 89%, after 100 battery cycles at a 10C rate.


2017 ◽  
Vol 251 ◽  
pp. 235-243 ◽  
Author(s):  
Zeying Yan ◽  
Chunli Guo ◽  
Feng Yang ◽  
Chunchen Zhang ◽  
Yuqiong Mao ◽  
...  
Keyword(s):  
Ni Foam ◽  

2015 ◽  
Vol 3 (16) ◽  
pp. 8636-8642 ◽  
Author(s):  
Dongxue Wang ◽  
Nan Chen ◽  
Malin Li ◽  
Chunzhong Wang ◽  
Helmut Ehrenberg ◽  
...  

Long-cycle stability with a capacity retention of 62% after 3000 cycles at a high charge rate of 10 C (2 A g−1).


RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 20545-20553 ◽  
Author(s):  
V. Senthilkumar ◽  
Yong Soo Kim ◽  
S. Chandrasekaran ◽  
Balasubramaniyan Rajagopalan ◽  
Eui Jung Kim ◽  
...  

(a)–(c) FE-SEM images of CuO nanoplates on Ni foam, flower-shaped CuO and bud-shaped CuO. (d) Specific capacitance and (d) and (e) Ragone plots of power density vs. energy density according to CuO electrodes in an asymmetrical device.


RSC Advances ◽  
2021 ◽  
Vol 11 (50) ◽  
pp. 31557-31565
Author(s):  
Rodrigo Henríquez ◽  
Alifhers S. Mestra-Acosta ◽  
Eduardo Muñoz ◽  
Paula Grez ◽  
Elena Navarrete-Astorga ◽  
...  

This work presents for the first time a CdCO3/CdO/Co3O4@nickel foam based supercapacitor with high both specific capacitance and energy density, a widespread potential window and a long cycle life.


2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Shouzheng Zhang ◽  
Ning Zhong ◽  
Xing Zhou ◽  
Mingjie Zhang ◽  
Xiangping Huang ◽  
...  

AbstractThe lithium-sulfur battery is the subject of much recent attention due to the high theoretical energy density, but practical applications are challenged by fast decay owing to polysulfide shuttle and electrode architecture degradation. A comprehensive study of the sulfur host microstructure design and the cell architecture construction based on the MXene phase (Ti3C2Tx nanosheets) is performed, aiming at realize stable cycling performance of Li–S battery with high sulfur areal loading. The interwoven KB@Ti3C2Tx composite formed by self-assembly of MXene and Ktejen black, not only provides superior conductivity and maintains the electrode integrality bearing the volume expansion/shrinkage when used as the sulfur host, but also functions as an interlayer on separator to further retard the polysulfide cross-diffusion that possibly escaped from the cathode. The KB@Ti3C2Tx interlayer is only 0.28 mg cm−2 in areal loading and 3 μm in thickness, which accounts a little contribution to the thick sulfur electrode; thus, the impacts on the energy density is minimal. By coupling the robust KB@Ti3C2Tx cathode and the effective KB@Ti3C2Tx modified separator, a stable Li–S battery with high sulfur areal loading (5.6 mg cm−2) and high areal capacity (6.4 mAh cm−2) at relatively lean electrolyte is achieved.


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