scholarly journals Water Mass Analysis of Effect of Climate Change on Air–Sea CO2 Fluxes: The Southern Ocean

2012 ◽  
Vol 25 (11) ◽  
pp. 3894-3908 ◽  
Author(s):  
Roland Séférian ◽  
Daniele Iudicone ◽  
Laurent Bopp ◽  
Tilla Roy ◽  
Gurvan Madec

Impacts of climate change on air–sea CO2 exchange are strongly region dependent, particularly in the Southern Ocean. Yet, in the Southern Ocean the role of water masses in the uptake of anthropogenic carbon is still debated. Here, a methodology is applied that tracks the carbon flux of each Southern Ocean water mass in response to climate change. A global marine biogeochemical model was coupled to a climate model, making 140-yr Coupled Model Intercomparison Project phase 5 (CMIP5)-type simulations, where atmospheric CO2 increased by 1% yr−1 to 4 times the preindustrial concentration (4 × CO2). Impacts of atmospheric CO2 (carbon-induced sensitivity) and climate change (climate-induced sensitivity) on the water mass carbon fluxes have been isolated performing two sensitivity simulations. In the first simulation, the atmospheric CO2 influences solely the marine carbon cycle, while in the second simulation, it influences both the marine carbon cycle and earth’s climate. At 4 × CO2, the cumulative carbon uptake by the Southern Ocean reaches 278 PgC, 53% of which is taken up by modal and intermediate water masses. The carbon-induced and climate-induced sensitivities vary significantly between the water masses. The carbon-induced sensitivities enhance the carbon uptake of the water masses, particularly for the denser classes. But, enhancement strongly depends on the water mass structure. The climate-induced sensitivities either strengthen or weaken the carbon uptake and are influenced by local processes through changes in CO2 solubility and stratification, and by large-scale changes in outcrop surface (OS) areas. Changes in OS areas account for 45% of the climate-induced reduction in the Southern Ocean carbon uptake and are a key factor in understanding the future carbon uptake of the Southern Ocean.

2011 ◽  
Vol 8 (5) ◽  
pp. 1031-1052 ◽  
Author(s):  
D. Iudicone ◽  
K. B. Rodgers ◽  
I. Stendardo ◽  
O. Aumont ◽  
G. Madec ◽  
...  

Abstract. The scientific motivation for this study is to understand the processes in the ocean interior controlling carbon transfer across 30° S. To address this, we have developed a unified framework for understanding the interplay between physical drivers such as buoyancy fluxes and ocean mixing, and carbon-specific processes such as biology, gas exchange and carbon mixing. Given the importance of density in determining the ocean interior structure and circulation, the framework is one that is organized by density and water masses, and it makes combined use of Eulerian and Lagrangian diagnostics. This is achieved through application to a global ice-ocean circulation model and an ocean biogeochemistry model, with both components being part of the widely-used IPSL coupled ocean/atmosphere/carbon cycle model. Our main new result is the dominance of the overturning circulation (identified by water masses) in setting the vertical distribution of carbon transport from the Southern Ocean towards the global ocean. A net contrast emerges between the role of Subantarctic Mode Water (SAMW), associated with large northward transport and ingassing, and Antarctic Intermediate Water (AAIW), associated with a much smaller export and outgassing. The differences in their export rate reflects differences in their water mass formation processes. For SAMW, two-thirds of the surface waters are provided as a result of the densification of thermocline water (TW), and upon densification this water carries with it a substantial diapycnal flux of dissolved inorganic carbon (DIC). For AAIW, principal formatin processes include buoyancy forcing and mixing, with these serving to lighten CDW. An additional important formation pathway of AAIW is through the effect of interior processing (mixing, including cabelling) that serve to densify SAMW. A quantitative evaluation of the contribution of mixing, biology and gas exchange to the DIC evolution per water mass reveals that mixing and, secondarily, gas exchange, effectively nearly balance biology on annual scales (while the latter process can be dominant at seasonal scale). The distribution of DIC in the northward flowing water at 30° S is thus primarily set by the DIC values of the water masses that are involved in the formation processes.


2017 ◽  
Author(s):  
Paula C. Pardo ◽  
Bronte Tilbrook ◽  
Clothilde Langlais ◽  
Tom W. Trull ◽  
Steve R. Rintoul

Abstract. Biogeochemical change in the water masses of the Southern Ocean, south of Tasmania, was assessed for the 16-year period between 1995 and 2011 using data from 4 summer repeats of the WOCE/JGOFS/CLIVAR/GO-SHIP SR03 hydrographic section (at ~ 140° E). Changes in temperature, salinity, oxygen, and nutrients were used to disentangle the effect of solubility, biology, circulation and anthropogenic carbon (CANT) uptake on the variability of dissolved inorganic carbon (DIC) for 8 water mass layers defined by neutral surfaces (ϒn). CANT was estimated using an improved back-calculation method. Warming (~ 0.0352 ± 0.0170 °C yr−1) of Subtropical Central Water (STCW) and Antarctic Surface Water (AASW) layers decreased their gas solubility, and accordingly DIC concentrations increased less rapidly than expected from equilibration with rising atmospheric CO2 (~ 0.86 ± 0.16 μmol kg−1 yr−1 versus ~ 1 ± 0.12 μmol kg−1 yr−1). An increase in apparent oxygen utilisation (AOU) occurred in these layers due to either remineralization of organic matter or intensification of upwelling. The range of estimates for the increases of CANT were 0.71 ± 0.08 to 0.93 ± 0.08 μmol kg−1 yr−1 for STCW and 0.35 ± 0.14 to 0.65 ± 0.21 μmol kg−1 yr−1 for AASW, with the lower values in each water mass obtained by assigning all the AOU change to remineralization. DIC increases in the Sub-Antarctic Mode Water (SAMW, 1.10 ± 0.14 μmol kg−1 yr−1) and Antarctic Intermediate Water (AAIW, 0.40 ± 0.15 μmol kg−1 yr−1) layers were similar to the calculated CANT trends. For SAMW, the CANT increase tracked rising atmospheric CO2. As a consequence of the general DIC increase, decreases in total pH (pHT) and aragonite saturation (ΩAr) were found in most water masses, with the upper ocean and the SAMW layer presenting the largest trends for pHT decrease (~ −0.0031 ± 0.0004 yr−1). DIC increases in deep and bottom layers (~ 0.24 ± 0.04 μmol kg−1 yr−1) resulted from the advection of old deep waters to resupply increased upwelling, as corroborated by increasing silicate (~ 0.21 ± 0.07 μmol kg−1 yr−1), which also reached the upper layers near the Antarctic Divergence (~ 0.36 ± 0.06 μmol kg−1 yr−1) and was accompanied by an increase in salinity. The observed changes in DIC over the 16-year span caused a shoaling (~ 340 m) of the aragonite saturation depth (ASD, ΩAr = 1) within Upper Circumpolar Deep Water that followed the upwelling path of this layer. From all our results, we conclude a scenario of increased transport of deep waters into the section and enhanced upwelling at high latitudes for the period between 1995 and 2011, probably linked to a positive trend in the Southern Annular Mode. Although enhanced upwelling lowered the capacity of the AASW layer to uptake atmospheric CO2, it did not limit that of the newly forming SAMW and AAIW, which exhibited CANT storage rates (~ 0.41 ± 0.20 mol m−2 yr−1) twice that of the upper layers.


2010 ◽  
Vol 23 (24) ◽  
pp. 6526-6541 ◽  
Author(s):  
Stephanie M. Downes ◽  
Nathaniel L. Bindoff ◽  
Stephen R. Rintoul

Abstract A multimodel comparison method is used to assess the sensitivity of Subantarctic Mode Water (SAMW) and Antarctic Intermediate Water (AAIW) formation to climate change. For the Intergovernmental Panel on Climate Change A2 emissions scenario (where atmospheric CO2 is 860 ppm at 2100), the models show cooling and freshening on density surfaces less than about 27.4 kg m−3, a pattern that has been observed in the late twentieth century. SAMW (defined by the low potential vorticity layer) and AAIW (defined by the salinity minimum layer) warm and freshen as they shift to lighter density classes. Heat and freshwater fluxes at the ocean surface dominate the projected buoyancy gain at outcrop regions of SAMW and AAIW, whereas the net increase in the Ekman flux of heat and freshwater contributes to a lesser extent. This buoyancy gain, combined with shoaling of the winter mixed layer, reduces the volume of SAMW subducted into the ocean interior by a mean of 8 Sv (12%), and the subduction of AAIW decreases by a mean of 14 Sv (23%; 1 Sv ≡ 106 m3 s−1). Decreases in the projected subduction of the key Southern Ocean upper-water masses imply a slow down in the Southern Ocean circulation in the future, driven by surface warming and freshening. A reduction in the subduction of intermediate waters implies a likely future decrease in the capacity of the Southern Ocean to sequester CO2.


2009 ◽  
Vol 22 (12) ◽  
pp. 3289-3302 ◽  
Author(s):  
Stephanie M. Downes ◽  
Nathaniel L. Bindoff ◽  
Stephen R. Rintoul

Abstract Changes in the temperature, salinity, and subduction of Subantarctic Mode Water (SAMW) and Antarctic Intermediate Water (AAIW) between the 1950s and 2090s are diagnosed using the CSIRO Mark version 3.5 (Mk3.5) climate system model Caps under a CO2 forcing that reaches 860 ppm by the year 2100. These Southern Ocean upper-limb water masses ventilate the ocean interior, and changes in their properties have been related to climate change in numerous studies. Over time, the authors follow the low potential vorticity and salinity minimum layers describing SAMW and AAIW and find that the water column in the 2090s shifts to lighter densities by approximately 0.2 kg m−3. The model projects a reduction in the SAMW and AAIW annual mean subduction rates as a result of a combination of a shallower mixed layer, increased potential vorticity at the base of the mixed layer, and a net buoyancy gain. There is little change in the projected total volume of SAMW transported into the ocean interior via the subduction process; however, the authors find a significant decrease in the subduction of AAIW. The authors find overall that increases in the air–sea surface heat and freshwater fluxes mainly control the reduction in the mean loss of the SAMW and AAIW surface buoyancy flux when compared with the effect of changes supplied by Ekman transport because of increased zonal wind stress. In the A2 scenario, there are cooling and freshening on neutral density surfaces less than 27.3 kg m−3 in response to the warming and freshening observed at the ocean’s surface. The model projects deepening of density surfaces due to southward shifts in the outcrop regions and the downward displacement of these surfaces north of 45°S. The volume transport across 32°S is predicted to decrease in all three basins, with southward transport of SAMW and AAIW decreasing by up to 1.2 and 2.0 Sv (1 Sv ≡ 106 m3 s−1), respectively, in the Indian Ocean. These projected reductions in the subduction and transport of mode and intermediate water masses in the CSIRO Mk3.5 model could potentially decrease the absorption and storage of CO2 in the Southern Ocean.


2021 ◽  
Vol 14 (12) ◽  
pp. 7255-7285
Author(s):  
Karin Kvale ◽  
David P. Keller ◽  
Wolfgang Koeve ◽  
Katrin J. Meissner ◽  
Christopher J. Somes ◽  
...  

Abstract. We describe and test a new model of biological marine silicate cycling, implemented in the Kiel Marine Biogeochemical Model version 3 (KMBM3), embedded in the University of Victoria Earth System Climate Model (UVic ESCM) version 2.9. This new model adds diatoms, which are a key component of the biological carbon pump, to an existing ecosystem model. This new model combines previously published parameterizations of a diatom functional type, opal production and export with a novel, temperature-dependent dissolution scheme. Modelled steady-state biogeochemical rates, carbon and nutrient distributions are similar to those found in previous model versions. The new model performs well against independent ocean biogeochemical indicators and captures the large-scale features of the marine silica cycle to a degree comparable to similar Earth system models. Furthermore, it is computationally efficient, allowing both fully coupled, long-timescale transient simulations and “offline” transport matrix spinups. We assess the fully coupled model against modern ocean observations, the historical record starting from 1960 and a business-as-usual atmospheric CO2 forcing to the year 2300. The model simulates a global decline in net primary production (NPP) of 1.4 % having occurred since the 1960s, with the strongest declines in the tropics, northern midlatitudes and Southern Ocean. The simulated global decline in NPP reverses after the year 2100 (forced by the extended RCP8.5 CO2 concentration scenario), and NPP returns to 98 % of the pre-industrial rate by 2300. This recovery is dominated by increasing primary production in the Southern Ocean, mostly by calcifying phytoplankton. Large increases in calcifying phytoplankton in the Southern Ocean offset a decline in the low latitudes, producing a global net calcite export in 2300 that varies only slightly from pre-industrial rates. Diatom distribution moves southward in our simulations, following the receding Antarctic ice front, but diatoms are outcompeted by calcifiers across most of their pre-industrial Southern Ocean habitat. Global opal export production thus drops to 75 % of its pre-industrial value by 2300. Model nutrients such as phosphate, silicate and nitrate build up along the Southern Ocean particle export pathway, but dissolved iron (for which ocean sources are held constant) increases in the upper ocean. This different behaviour of iron is attributed to a reduction of low-latitude NPP (and consequently, a reduction in both uptake and export and particle, including calcite scavenging), an increase in seawater temperatures (raising the solubility of particulate iron) and stratification that “traps” the iron near the surface. These results are meant to serve as a baseline for sensitivity assessments to be undertaken with this model in the future.


2008 ◽  
Vol 21 (22) ◽  
pp. 5820-5834 ◽  
Author(s):  
R. J. Matear ◽  
A. Lenton

Abstract Climate change over the last several decades is suggested to cause a decrease in the magnitude of the uptake of CO2 by the Southern Ocean (Le Quere et al.). In this study, the atmospheric fields from NCEP R1 for the years 1948–2003 are used to drive an ocean biogeochemical model to probe how changes in the heat and freshwater fluxes and in the winds affect the Southern Ocean’s uptake of carbon. Over this period, the model simulations herein show that the increases in heat and freshwater fluxes drive a net increase in Southern Ocean uptake (south of 40°S) while the increases in wind stresses drive a net decrease in uptake. The total Southern Ocean response is nearly identical with the simulation without climate change because the heat and freshwater flux response is approximately both equal and opposite to the wind stress response. It is also shown that any change in the Southern Ocean anthropogenic carbon uptake is always opposed by a much larger change in the natural carbon air–sea exchange. For the 1948–2003 period, the changes in the natural carbon cycle dominate the Southern Ocean carbon uptake response to climate change. However, it is shown with a simple box model that when atmospheric CO2 levels exceed the partial pressure of carbon dioxide (pCO2) of the upwelled Circumpolar Deep Water (≈450 μatm) the Southern Ocean uptake response will be dominated by the changes in anthropogenic carbon uptake. Therefore, the suggestion that the Southern Ocean carbon uptake is a positive feedback to global warming is only a transient response that will change to a negative feedback in the near future if the present climate trend continues. Associated with the increased outgassing of carbon from the natural carbon cycle was a reduction in the aragonite saturation state of the high-latitude Southern Ocean (south of 60°S). In the simulation with just wind stress changes, the reduction in the high-latitude Southern Ocean aragonite saturation state (≈0.2) was comparable to the magnitude of the decline in the aragonite saturation state over the last 4 decades because of rising atmospheric CO2 levels (≈0.2). The simulation showed that climate change could significantly impact aragonite saturation state in the Southern Ocean.


2011 ◽  
Vol 24 (16) ◽  
pp. 4255-4275 ◽  
Author(s):  
Kirsten Zickfeld ◽  
Michael Eby ◽  
H. Damon Matthews ◽  
Andreas Schmittner ◽  
Andrew J. Weaver

Abstract Coupled climate–carbon models have shown the potential for large feedbacks between climate change, atmospheric CO2 concentrations, and global carbon sinks. Standard metrics of this feedback assume that the response of land and ocean carbon uptake to CO2 (concentration–carbon cycle feedback) and climate change (climate–carbon cycle feedback) combine linearly. This study explores the linearity in the carbon cycle response by analyzing simulations with an earth system model of intermediate complexity [the University of Victoria Earth System Climate Model (UVic ESCM)]. The results indicate that the concentration–carbon and climate–carbon cycle feedbacks do not combine linearly to the overall carbon cycle feedback. In this model, the carbon sinks on land and in the ocean are less efficient when exposed to the combined effect of elevated CO2 and climate change than to the linear combination of the two. The land accounts for about 80% of the nonlinearity, with the ocean accounting for the remaining 20%. On land, this nonlinearity is associated with the different response of vegetation and soil carbon uptake to climate in the presence or absence of the CO2 fertilization effect. In the ocean, the nonlinear response is caused by the interaction of changes in physical properties and anthropogenic CO2. These findings suggest that metrics of carbon cycle feedback that postulate linearity in the system’s response may not be adequate.


2021 ◽  
Author(s):  
Andrew Meijers ◽  
David Munday ◽  
Tilla Roy ◽  
Jean-Baptiste Sallée

<p>We examine the representation of Southern Ocean water mass properties, circulation and transformation in an ensemble of CMIP6 models, under historical climate forcing conditions and under a range of future climate scenarios. By using a dynamically defined water mass classification scheme based on physical characteristics (salinity minimum, potential vorticity minimum etc) rather than fixed water mass properties, we are able to compare water masses across a range of models, often with significant water mass property differences, as well as within single models where water mass properties change under climate forcing. We find that under strong climate forcing scenarios (ssp585) the heat content of SubAntarctic Mode Water (SAMW), Antarctic Intermediate Water (AAIW) and Circumpolar Deep Water (CDW) all increase consistently across models, while Antarctic Bottom Water (AABW) does not change significantly. Importantly this change is strongly modulated by using dynamic definitions. Both SAMW and AAIW lighten significantly in density, and using time varying definitions their volumes remain relatively constant, whereas using a time invariant definition both experience extremely significant increases in volume and heat content. We show that dynamically it is the ocean interior, CDW and AAIW, that dominate heat uptake under strong forcing. Similarly, dissolved inorganic carbon uptake occurs predominantly in the CDW. In contrast AABW volumes decrease significantly.</p><p>There is a consistent ‘fingerprint’ of temperature change in density space across all models under strong forcing scenarios, with CDW experiencing surface intensified warming as it shoals to the south, and SAMW/AAIW demonstrating cooling and freshening in their subducted layers and a uniform warming in the surface layers. We show that the upper cell of the residual overturning circulation (calculated with the new availability of eddy parametrisation terms in CMIP6) consistently increases across all models evaluated, by 10-50% (up to 10 Sv in some models), while the lower cell is dramatically decreased in strength, declining by up to 70% in some models. We provide evidence that surface warming may be modulated by increased eddy driven upwelling, as well as surface freshening driving the shutdown of AABW formation. Finally we compute a Walin water mass budget, balancing surface forcing, interior storage and meridional export and inferring interior mixing between water masses, and contrast all findings with similar analyses in CMIP5.</p><p> </p>


2017 ◽  
Vol 14 (22) ◽  
pp. 5217-5237 ◽  
Author(s):  
Paula Conde Pardo ◽  
Bronte Tilbrook ◽  
Clothilde Langlais ◽  
Thomas William Trull ◽  
Stephen Rich Rintoul

Abstract. Biogeochemical change in the water masses of the Southern Ocean, south of Tasmania, was assessed for the 16-year period between 1995 and 2011 using data from four summer repeats of the WOCE–JGOFS–CLIVAR–GO-SHIP (Key et al., 2015; Olsen et al., 2016) SR03 hydrographic section (at ∼ 140° E). Changes in temperature, salinity, oxygen, and nutrients were used to disentangle the effect of solubility, biology, circulation and anthropogenic carbon (CANT) uptake on the variability of dissolved inorganic carbon (DIC) for eight water mass layers defined by neutral surfaces (γn). CANT was estimated using an improved back-calculation method. Warming (∼ 0.0352 ± 0.0170 °C yr−1) of Subtropical Central Water (STCW) and Antarctic Surface Water (AASW) layers decreased their gas solubility, and accordingly DIC concentrations increased less rapidly than expected from equilibration with rising atmospheric CO2 (∼ 0.86 ± 0.16 µmol kg−1 yr−1 versus ∼ 1 ± 0.12 µmol kg−1 yr−1). An increase in apparent oxygen utilisation (AOU) occurred in these layers due to either remineralisation of organic matter or intensification of upwelling. The range of estimates for the increases in CANT were 0.71 ± 0.08 to 0.93 ± 0.08 µmol kg−1 yr−1 for STCW and 0.35 ± 0.14 to 0.65 ±  0.21 µmol kg−1 yr−1 for AASW, with the lower values in each water mass obtained by assigning all the AOU change to remineralisation. DIC increases in the Sub-Antarctic Mode Water (SAMW, 1.10 ± 0.14 µmol kg−1 yr−1) and Antarctic Intermediate Water (AAIW, 0.40 ± 0.15 µmol kg−1 yr−1) layers were similar to the calculated CANT trends. For SAMW, the CANT increase tracked rising atmospheric CO2. As a consequence of the general DIC increase, decreases in total pH (pHT) and aragonite saturation (ΩAr) were found in most water masses, with the upper ocean and the SAMW layer presenting the largest trends for pHT decrease (∼ −0.0031 ± 0.0004 yr−1). DIC increases in deep and bottom layers (∼ 0.24 ± 0.04 µmol kg−1 yr−1) resulted from the advection of old deep waters to resupply increased upwelling, as corroborated by increasing silicate (∼ 0.21 ± 0.07 µmol kg−1 yr−1), which also reached the upper layers near the Antarctic Divergence (∼ 0.36 ± 0.06 µmol kg−1 yr−1) and was accompanied by an increase in salinity. The observed changes in DIC over the 16-year span caused a shoaling (∼ 340 m) of the aragonite saturation depth (ASD, ΩAr =  1) within Upper Circumpolar Deep Water that followed the upwelling path of this layer. From all our results, we conclude a scenario of increased transport of deep waters into the section and enhanced upwelling at high latitudes for the period between 1995 and 2011 linked to strong westerly winds. Although enhanced upwelling lowered the capacity of the AASW layer to uptake atmospheric CO2, it did not limit that of the newly forming SAMW and AAIW, which exhibited CANT storage rates (∼ 0.41 ± 0.20 mol m−2 yr−1) twice that of the upper layers.


2013 ◽  
Vol 9 (3) ◽  
pp. 1111-1140 ◽  
Author(s):  
M. Eby ◽  
A. J. Weaver ◽  
K. Alexander ◽  
K. Zickfeld ◽  
A. Abe-Ouchi ◽  
...  

Abstract. Both historical and idealized climate model experiments are performed with a variety of Earth system models of intermediate complexity (EMICs) as part of a community contribution to the Intergovernmental Panel on Climate Change Fifth Assessment Report. Historical simulations start at 850 CE and continue through to 2005. The standard simulations include changes in forcing from solar luminosity, Earth's orbital configuration, CO2, additional greenhouse gases, land use, and sulphate and volcanic aerosols. In spite of very different modelled pre-industrial global surface air temperatures, overall 20th century trends in surface air temperature and carbon uptake are reasonably well simulated when compared to observed trends. Land carbon fluxes show much more variation between models than ocean carbon fluxes, and recent land fluxes appear to be slightly underestimated. It is possible that recent modelled climate trends or climate–carbon feedbacks are overestimated resulting in too much land carbon loss or that carbon uptake due to CO2 and/or nitrogen fertilization is underestimated. Several one thousand year long, idealized, 2 × and 4 × CO2 experiments are used to quantify standard model characteristics, including transient and equilibrium climate sensitivities, and climate–carbon feedbacks. The values from EMICs generally fall within the range given by general circulation models. Seven additional historical simulations, each including a single specified forcing, are used to assess the contributions of different climate forcings to the overall climate and carbon cycle response. The response of surface air temperature is the linear sum of the individual forcings, while the carbon cycle response shows a non-linear interaction between land-use change and CO2 forcings for some models. Finally, the preindustrial portions of the last millennium simulations are used to assess historical model carbon-climate feedbacks. Given the specified forcing, there is a tendency for the EMICs to underestimate the drop in surface air temperature and CO2 between the Medieval Climate Anomaly and the Little Ice Age estimated from palaeoclimate reconstructions. This in turn could be a result of unforced variability within the climate system, uncertainty in the reconstructions of temperature and CO2, errors in the reconstructions of forcing used to drive the models, or the incomplete representation of certain processes within the models. Given the forcing datasets used in this study, the models calculate significant land-use emissions over the pre-industrial period. This implies that land-use emissions might need to be taken into account, when making estimates of climate–carbon feedbacks from palaeoclimate reconstructions.


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