The influence of functionalization time of carbon nanotube on the mechanical properties of the epoxy composites

2017 ◽  
Vol 51 (12) ◽  
pp. 1693-1701 ◽  
Author(s):  
EA Zakharychev ◽  
EN Razov ◽  
Yu D Semchikov ◽  
NS Zakharycheva ◽  
MA Kabina
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Tensile Strength ◽  
Elastic Modulus ◽  
Carbon Nanotube ◽  
Composite Materials ◽  
Polymer Composites ◽  
Epoxy Composites ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

This paper investigates the structure, length, and percentage of functional groups of multi-walled carbon nanotubes (CNT) depending on the time taken for functionalization in HNO3 and H2SO4 mixture. The carbon nanotube content and influence of functionalization time on mechanical properties of polymer composite materials based on epoxy matrix are studied. The extreme dependencies of mechanical properties of carbon nanotube functionalization time of polymer composites were established. The rise in tensile strength of obtained composites reaches 102% and elastic modulus reaches 227% as compared to that of unfilled polymer. The composites exhibited best mechanical properties by including carbon nanotube with 0.5 h functionalization time.

Preparation and Properties of Graphene and its Nanocomposites

2015 ◽  
Vol 719-720 ◽  
pp. 141-144
Author(s):  
Chen Chi M. Ma ◽  
Sheng Tsung Hsiao ◽  
Wei Hao Liao ◽  
Shin Ming Li ◽  
Yu Sheng Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Tensile Strength ◽  
Hybrid Materials ◽  
Epoxy Composites ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Fractured Surface ◽  
Scanning Electron

This study proposed a method to improve the mechanical properties and thermal conductivity of epoxy composites by incorporating multi-walled carbon nanotubes (MWCNTs) and multi-graphene platelets (MGPs) hybrid materials. The MWCNT can bridge adjacent MGPs and inhibit their aggregation effectively, leading to an increased contact surface area between MGP/MWCNT hybrid materials and epoxy matrix. From observing the fractured surface of composite by scanning electron microscope, MWCNT/MGP hybrid materials exhibited better compatibility than individual MWCNT and MGP did.The tensile strength of GD400-MWCNT/MGP/epoxy composites was 35.4% higher than that of epoxy, compared to only a 0.9% increase in tensile strength for MGP/epoxy composites. Thermal conductivity enhanced by 146.9% through incorporating MWCNT/MGP hybrid materials and 23.9% for MGP fillers, compared to non-derivatised epoxy.

Preparation and Characterization of Polyesteramide Composited by Carbon Nanotube

2013 ◽  
Vol 562-565 ◽  
pp. 764-769
Author(s):  
Yi He ◽  
Lan Ma ◽  
Peng Hai ◽  
Jin Bo Li
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Tensile Strength ◽  
Carbon Nanotube ◽  
Tensile Testing ◽  
Elongation At Break ◽  
Multi Walled Carbon Nanotubes ◽  
In Suit ◽  
Walled Carbon Nanotubes

Polyesteramide (PEA) have good mechanical properties, compositing with multi-walled carbon nanotubes (MWNTs) can further improve the mechanical properties of the polymer. In this paper, PEA/MWNTs were synthesized in-suit using the reinforcement of nanocomposite. SEM and tensile testing were used to characterize the composited polyesteramides. The results show that MWNTs can be uniformly dispersed in the composited polyesteramides, the PEA/MWNTs tensile strength and Elongation at break increased.

Static and Fatigue Strengths of Carbon Nanotube/Epoxy Composites under Hygrothermal Environments

2013 ◽  
Vol 284-287 ◽  
pp. 204-210
Author(s):  
Yi Ming Jen ◽  
Chien Yang Huang
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Stress Concentration ◽  
Interfacial Adhesion ◽  
Epoxy Composites ◽  
Hygrothermal Effect ◽  
Multi Walled Carbon Nanotubes ◽  
Hygrothermal Environments ◽  
Stress Concentration Effect ◽  
Walled Carbon Nanotubes

This study experimentally analyzed the hygrothermal effect on the static and fatigue strengths of acid-treated multi-walled carbon nanotubes (CNTs)/epoxy composites. The nanocomposite specimens with various CNT contents (0., 0.5, and 1.0 wt.%) were statically and fatigue-tested under three different hygrothermal conditions (25 °C/60% RH, 25° C/85% RH, and 40 °C/85% RH) to investigate the influences of hygrothermal conditions and CNT contents on the tensile static and fatigue strengths of the studied nanocomposites. The results show that the static and fatigue strengths decreased slightly at 25 °C/85% RH environments compared with those tested under the 25 °C/60% RH condition. However, the static and fatigue strengths of the studied nanocomposites decreased substantially under the 40 °C/85% RH condition. The combined temperature and humidity environments weaken the interfacial adhesion between the CNT surfaces and the epoxy matrix. Moreover, the experimental results show that the addition of 0.5 wt.% of carbon nanotubes improved the static and fatigue strengths considerably under the same hygrothermal environments. However, when an excessive amount of CNTs was used (1.0 wt.%), the nanocomposite exhibited the lowest strengths compared with the specimens with 0 and 0.5 wt.% CNTs. The stress concentration effect caused by the CNT aggregates was detrimental to the static and fatigue strengths of the studied nanocomposites.

scholarly journals INFLUENCE OF FUNCTIONALIZED MULTI-WALLED CARBON NANOTUBES ON FILTERABILITY AND MECHANICAL PROPERTIES OF RAYON NANOCOMPOSITE FILAMENTS

2016 ◽  
Vol 3 (01) ◽  
Author(s):  
Holia Onggo ◽  
Rike Yudianti ◽  
Endang Ruchiat
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Electron Microscope ◽  
Carbon Nanotube ◽  
Carbon Nanotube Dispersion ◽  
Transmission Electron ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Nanotube Dispersion ◽  
Scanning Electron

Carbon nanotube-rayon composite filaments was fabricated by spinning and coagulation of the mixture of 100mL functionalized carbon nanotube dispersion (containing 0.72 g FCNT) and cellulose xanthate in NaOH solution using viscose process. In the process, CNT was functionalized using mixture of acidic solution ( H2SO4/HNO3, 3:1 v/v). Influence of functionalized (FCNT) and non-functionalized carbon nanotubes (nFCNT) on the fabrication of rayon nanocomposite filament was studied. Physical and morphological properties of the nanocomposite filaments were characterized by single filament tenacity tester, photo micrograph, scanning electron microscope (SEM) and transmission electron microscope (TEM). Filterability and mechanical properties of FCNT-rayon nanocomposite filament greatly improved by reducing clogging constant from 1689 to 153 and increasing tenacity from 2.72 to 3.01 g/denier and decreasing elongation from 57.1 to 36.5% respectively compared with those of nFCNT-rayon nanocomposite filament.Keywords: functionalized multi-walled carbon nanotubes, nanocomposite filament, mechanical properties, filterability, dispersion  ABSTRAKRayon nanocomposite filaments telah dibuat melalui proses pemilinan (spinning) dan koagulasi (coagulation) dari campuran 100 mL larutan functionalized carbon nanotube dispersion (FCNT=0,72 g), selulosa santat dalam larutan NaOH melalui proses viskosa. CNT di functionalisasi (FCNT) menggunakan campuran larutan asam (H2SO4/HNO3, 3:1 v/v). Pengaruh fungsionalisasi CNT pada pembuatan rayon nanocomposite filaments dipelajari dengan cara membandingkannya dengan CNT tanpa fungsionalisasi (nFCNT). Sifat fisik dan morfologi dari rayon-nanocomposite filaments dikarakterisasi menggunakan tenacity tester, photo micrograph, scanning electron microscope (SEM) dan transmission electron microscope (TEM). Viskosa FCNT memiliki daya saring (Kw) cukup baik yaitu 155, sedangkan viskosa nFCNT  memiliki daya saring 1689 (tidak baik). Kekuatan mekanik dari FCNT-rayon nanocomposite filaments berturut turut adalah 3,01 g/denier (tenacity), dan 36,5% (elongation), lebih baik dibandingkan dengan nFCNT-rayon nanocomposite filament: 2,72 g/denier (tenacity) dan 57,1% (elongation).Kata kunci: fungsionalisasi multi-walled carbon nanotubes, rayon-nanocomposite filament, sifat mekanik, daya saring, dispersi

Effect of carbon nanotube modification on poly (butylene terephthalate)-based composites

2016 ◽  
Vol 70 (6) ◽  
Author(s):  
Agnieszka Piegat ◽  
Anna Jędrzejewska ◽  
Robert Peƚech ◽  
Iwona Peƚech
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Lower Amount ◽  
Butylene Terephthalate ◽  
The Matrix ◽  
Multi Walled Carbon Nanotubes ◽  
Modified Carbon Nanotubes ◽  
Walled Carbon Nanotubes

AbstractThe influence of the chemical modification of carbon nanotubes on the mechanical, thermal and electrical properties of poly(butylene terephthalate)-based composites was investigated. Polymer composites based on poly(butylene terephthalate) were obtained via in situ polymerisation or extrusion. Commercially available multi-walled carbon nanotubes (Nanocyl NC7000) at different loadings (mass %: 0.05, 0.25, 1, 2) were used as fillers. The functionalisation process took place under a chlorine atmosphere followed by a reaction with sodium hydroxide. The effect of carbon nanotube modification was analysed according to the changes in the polymer thermal and mechanical properties. An addition of modified carbon nanotubes in the amount of 0.05 mass % improved the mechanical properties of the composites in terms of both Young’s modulus and tensile strength by 5–10 % and 17–30 % compared with composites with unmodified carbon nanotubes and neat poly(butylene terephthalate), respectively. The in situ method of composite preparation was a more effective technique for enhancing the matrix–filler interactions, although a significantly lower amount of fillers were used than in the extrusion method.

scholarly journals Key factors limiting carbon nanotube strength: Structural characterization and mechanical properties of multi-walled carbon nanotubes

2017 ◽  
Vol 4 (5) ◽  
pp. 17-00029-17-00029 ◽  
Author(s):  
Keiichi SHIRASU ◽  
Itaru TAMAKI ◽  
Takamichi MIYAZAKI ◽  
Go YAMAMOTO ◽  
Raman BEKAREVICH ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Structural Characterization ◽  
Key Factors ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

scholarly journals Carbon Nanotubes Dispersion Assessment in Nanocomposites by Means of a Pulsed Thermographic Approach

Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5649
Author(s):  
Nicola Montinaro ◽  
Mario Fustaino ◽  
Antonio Pantano
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Polymer Composites ◽  
Reference Sample ◽  
Thermal Response ◽  
Destructive Testing ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
First Time ◽  
Non Destructive

The extensive production of polymer composites reinforced by carbon nanotube is limited by the absence of non-destructive evaluation (NDE) methods capable of assessing product quality to guarantee compliance with specifications. It is well known that the level of dispersion of carbon nanotubes (CNTs) in the polymer matrix is the parameter that, much more than others, can influence their enhancement capabilities. Here an active Infrared Thermography Non Destructive Testing(IR-NDT) inspection, joined with pulsed phase thermography (PPT), were applied for the first time to epoxy-CNT composites to evaluate the level of dispersion of the nanoparticles. The PPT approach was tested on three groups of epoxy nanocomposite samples with different levels of dispersion of the nanoparticles. The phasegrams obtained with the presented technique clearly show clusters, or bundles, of CNTs when present, so a comparison with the reference sample is not necessary to evaluate the quality of the dispersion. Therefore, the new NDE approach can be applied to verify that the expected dispersion levels are met in products made from epoxy and Multi-Walled Carbon Nanotubes (MWCNTs). The mechanisms underlying the effects of the dispersion of carbon nanotube on the thermal response of polymer composites have been identified.

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