scholarly journals On the Formation of COS from H2S and CO2 in the Presence of Zeolite/Salt Compounds

1998 ◽  
Vol 16 (7) ◽  
pp. 577-581 ◽  
Author(s):  
Wolfgang Lutz ◽  
Andreas Seidel ◽  
Bruno Boddenberg

A gaseous mixture of hydrogen sulphide and carbon dioxide (20% H2S, 80% CO2) was brought into contact at 25°C with NaY and NaX zeolites in an as-synthesized form as well as after modification by the inclusion of salts (NaCl, NaBr) in the small cages of the aluminosilicate framework and ion exchange with aqueous CaCl2 solution. At small contact times (5 h), the degree of conversion of H2S according to the reaction H2S + CO2 → COS + H2O by the various samples was found to follow the sequence NaY/NaCl ≈ NaY/NaBr ≈ NaX/NaCl(CaCl2) < NaY « NaX/NaCl ≈ NaX. Long-term runs with NaY and NaY/NaBr revealed that the latter zeolite retained a very low level of H2S conversion for contact times as long as 250 h. It is concluded that such low H2S conversion requires the absence of low-coordinated sodium cations in the supercages or their replacement by calcium ions, and blocking of the β-cages with salt anions.

2005 ◽  
Author(s):  
K. Parker ◽  
S. Rose-Pehrsson ◽  
D. Kidwell

2013 ◽  
Vol 8 (4) ◽  
pp. 347-359
Author(s):  
Leszek Kucharski

This study presents the structure and tendencies in long-term unemployment in Poland in the years 2008-2012. This study identifies the groups of people with an increased risk of long-term unemployment. The analyses produced the following conclusions. The groups with the highest risk of long-term unemployment include: singles, people aged of 55 and above and people with a low level of education. Young people with university and general secondary education faced the lowest risk of long-term unemployment. 


1975 ◽  
Vol 10 (1) ◽  
pp. 33-41 ◽  
Author(s):  
J. Butcher ◽  
M. Boyer ◽  
CD. Fowle

Abstract Eleven small ponds, lined with polyethylene, were used to assess the consequences of applications of *DursbanR at 0.004, 0.030, 0.100 and 1.000 ppm and AbateR at 0.025 and 0.100 ppm active ingredient. The treated ponds showed a more pronounced long-term increase in pH and dissolved oxygen and decreasing total and dissolved carbon dioxide in comparison with untreated ponds. Algal blooms were of longer duration in treated ponds than in controls. Total photosynthetic productivity was higher in treated ponds but bacterial numbers did not change significantly. Photosynthetic productivity was estimated by following the changes in total carbon dioxide.


Author(s):  
Jaroslav Tir ◽  
Johannes Karreth

Two low-level armed conflicts, Indonesia’s East Timor and Ivory Coast’s post-2010 election crises, provide detailed qualitative evidence of highly structured intergovernmental organizations (IGOs) engaging in effective civil warpreventing activities in member-states. Highly structured IGOs threatened and sanctioned each of these states and offered (long-term) benefits conditional on successful crisis resolution. The governments were aware of and responded to these IGOs’ concerns, as did the rebels in these respective cases. The early stages of the conflict in Syria in 2011 provide a counterpoint. With Syria’s limited engagement in only few highly structured IGOs, the Syrian government ignored international calls for peace. And, without highly structured IGOs’ counterweight to curtail the government, the rebels saw little reason to stop their armed resistance. The result was a brutal and deadly civil war that continues today.


2003 ◽  
Vol 38 (4) ◽  
pp. 332-343 ◽  
Author(s):  
Anatoly I. TASKAEV ◽  
Edward R. LANDA ◽  
Denis V. GURYEV ◽  
Natalia GOLOVKO BUTLER ◽  
Thomas F. KRAEMER

2021 ◽  
Author(s):  
Ann Nakashima ◽  
Oshin Vartanian ◽  
Shawn G Rhind ◽  
Kristen King ◽  
Catherine Tenn ◽  
...  

ABSTRACT Introduction Recently, there has been increasing concern about the adverse health effects of long-term occupational exposure to low-level blast in military personnel. Occupational blast exposure occurs routinely in garrison through use of armaments and controlled blast detonations. In the current study, we focused on a population of breaching instructors and range staff. Breaching is a tactical technique that is used to gain entry into closed spaces, often through the use of explosives. Materials and Methods Initial measurements of blast overpressure collected during breaching courses found that up to 10% of the blasts for range staff and up to 32% of the blasts for instructors exceeded the recommended 3 psi exposure limit. Using a cross-sectional design, we used tests of balance, ataxia, and hearing to compare a sample of breachers (n = 19) to age-and sex-matched military controls (n = 19). Results There were no significant differences between the two groups on the balance and ataxia tests, although the average scores of both groups were lower than would be expected in a normative population. The prevalence of hearing loss was low in the breacher group (4 of 19), and hearing thresholds were not significantly different from the controls. However, the prevalence of self-reported tinnitus was significantly higher in the breacher group (12 of 19) compared with the controls (4 of 19), and all breachers who were identified as having hearing loss also reported tinnitus. Conclusions Our results suggest that basic tests of balance, ataxia, and hearing on their own were not sensitive to the effects of long-term occupational exposure to low-level blast. Some of the blast exposure levels exceeded limits, and there was a significant association of exposure with tinnitus. Future studies should supplement with additional information including exposure history and functional hearing assessments. These findings should be considered in the design of future acute and longitudinal studies of low-level blast exposure.


2021 ◽  
Vol 209 ◽  
pp. 104955
Author(s):  
Qianqian Zhang ◽  
Pengpeng Duan ◽  
Anna Gunina ◽  
Xi Zhang ◽  
Xiaoyuan Yan ◽  
...  
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