Developing Mix Proportions for Class C Fly Ash-Based Alkali-Activated 3D-Printed Concrete Mixtures

Author(s):  
Fareh Abudawaba ◽  
Eslam Gomaa ◽  
Ahmed Gheni ◽  
Mohamed ElGawady

This study investigated the use of class C fly ash (FA) as a precursor for alkali-activated mortar (AAM) for 3D-printed concrete (3DPC). AAMs with different water-to-FA (W/FA), alkaline activator-to-FA (Alk/FA), and sodium silicate-to-sodium hydroxide (SS/SH) ratios were examined to develop mixtures that can be tailored for different structural applications of 3DPC. The fresh properties, including extrudability and buildability, were evaluated through the open time (OT) and immediate deformation tests, respectively. Different cycle times (CTs) were applied to achieve a strain limit state necessary to maintain the printed shape. The strength of AAMs in different directions at different CTs was examined. Scanning electron microscopy (SEM) was carried out on AAM specimens having different CTs for a better understanding of the bond area. OTs ranging from 2.5 min to 31 min and axial strains ranging from 0.17% to 11.2% were achieved depending on the proportions of the AAMs and CT, which offers flexibility in optimizing the speed of printing and strength of concrete for different projects. The 3DPC specimens displayed anisotropic behavior compared with full-height specimens, where the compressive strength of full-height specimens was higher by 0.2% to 18% and 0.9% to 28% than 3DPC specimens when tested parallel and normal to the printing directions, respectively. SEM images and line scan indicated an approximately even intensity of the element concentration at the interfacial zones of AAMs having short CTs, which explained the relatively high compressive strength of those specimens. For AAMs having long CTs, there was a significant change in the intensity of the element concentration at the interfacial bond zone, and voids were observed resulting in low compressive strength of those specimens.

2021 ◽  
Vol 11 (7) ◽  
pp. 3032
Author(s):  
Tuan Anh Le ◽  
Sinh Hoang Le ◽  
Thuy Ninh Nguyen ◽  
Khoa Tan Nguyen

The use of fluid catalytic cracking (FCC) by-products as aluminosilicate precursors in geopolymer binders has attracted significant interest from researchers in recent years owing to their high alumina and silica contents. Introduced in this study is the use of geopolymer concrete comprising FCC residue combined with fly ash as the requisite source of aluminosilicate. Fly ash was replaced with various FCC residue contents ranging from 0–100% by mass of binder. Results from standard testing methods showed that geopolymer concrete rheological properties such as yield stress and plastic viscosity as well as mechanical properties including compressive strength, flexural strength, and elastic modulus were affected significantly by the FCC residue content. With alkali liquid to geopolymer solid ratios (AL:GS) of 0.4 and 0.5, a reduction in compressive and flexural strength was observed in the case of geopolymer concrete with increasing FCC residue content. On the contrary, geopolymer concrete with increasing FCC residue content exhibited improved strength with an AL:GS ratio of 0.65. Relationships enabling estimation of geopolymer elastic modulus based on compressive strength were investigated. Scanning electron microscope (SEM) images and X-ray diffraction (XRD) patterns revealed that the final product from the geopolymerization process consisting of FCC residue was similar to fly ash-based geopolymer concrete. These observations highlight the potential of FCC residue as an aluminosilicate source for geopolymer products.


The investigative studies on mechanical performance & behaviour, of Geopolymer Concrete (GPC) before and after the exposure to elevated temperatures (of 200 0 C -1000 0 C with an increment of 100 0 C). Indicate that the GPC Specimens Exhibited better Compressive strength at higher temperatures than that of those made by regular OPC Concrete with M30 Grade. The chronological changes in the geopolymeric structure upon exposure to these temperatures and their reflections on the thermal behaviour have also been explored. The SEM images indicate GPC produced by fly ash , metakaolin and silica fume, under alkaline conditions form Mineral binders that are not only non-flammable and but are also non-combustible resins and binders. Further the Observations drawn disclose that the mass and compressive strength of concrete gets reduced with increase in temperatures.


2011 ◽  
Vol 287-290 ◽  
pp. 1237-1240
Author(s):  
Lan Fang Zhang ◽  
Rui Yan Wang

The aim of this paper is to study the influence of lithium-slag and fly ash on the workability , setting time and compressive strength of alkali-activated slag concrete. The results indicate that lithium-slag and fly-ash can ameliorate the workability, setting time and improve the compressive strength of alkali-activated slag concrete,and when 40% or 60% slag was replaced by lithium-slag or fly-ash, above 10 percent increase in 28-day compressive strength of concrete were obtained.


2019 ◽  
Vol 276 ◽  
pp. 01014
Author(s):  
I Made Alit Karyawan Salain ◽  
I Nyoman Sutarja ◽  
Teguh Arifmawan Sudhiarta

This experimental study presents the properties of highperformance concrete (HPC) made by partially replacing type I Portland cement (OPC) with class C fly ash (CFA). The purpose of this study is to examine, with hydration time, the development of the compressive strength, the splitting tensile strength and the permeability of HPC utilizing different quantity of CFA. Four HPC mixtures, C1, C2, C3, and C4, were made by utilizing respectively 10%, 20%, 30% and 40% of CFA as replacement of OPC, by weight. One control mixture, C0, was made with 0% CFA. The mix proportion of HPC was 1.00 binder: 1.67 fine aggregate: 2.15 coarse aggregate with water to binder ratio 0.32. In each mixture, it was added 5% silica fume and 0.6% superplasticizer of the weight of the binder. Tests of HPC properties were realized at the age of 1, 3, 7, 28, and 90 days. The results indicate that CFA used to partially replace OPC in HPC shows adequate cementitious and pozzolanic properties. The compressive strength and the splitting tensile strength of HPC increase while the permeability coefficient decreases with increasing hydration time. It is found that the optimum replacement of OPC with CFA is 10%, however the replacement up to 20% is still acceptable to produce HPC having practically similar harden properties with control mixture. At this optimum replacement and after 90 days of hydration, the compressive strength, the splitting tensile strength and the permeability coefficient can reach 68.9 MPa, 8.3 MPa and 4.6 E-11 cm/sec respectively. These results are 109%, 101%, and 48% respectively of those of control mixture.


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