Evaporation and combustion of n-heptane droplets in supersonic combustor

2021 ◽  
pp. 095441002110376
Author(s):  
Amir Mahdi Tahsini ◽  
Seyed Saeid Nabavi
Keyword(s):  
Droplet Size ◽  
Combustion Efficiency ◽  
Single Step ◽  
Physical Situation ◽  
Finite Rate ◽  
Two Phase ◽  
Droplet Cloud ◽  
Opposite Behavior ◽  
Droplet Sizes ◽  
Single Step Reaction

The purpose of the present study is to investigate the combustion of the n-heptane droplet cloud in the supersonic combustor. The finite volume solver is developed to simulate the two-phase reacting compressible flow using single step reaction mechanism as finite rate chemistry. The focus is on the impacts of droplet size and cloud density on the performance of the scramjet. For the considered physical situation, the upper limit of the droplet size is determined to have higher combustion efficiency, and it is shown that the combustion mode is kinetic-controlled for small sizes and is evaporation-controlled for large droplet sizes. The variation of combustor’s exit total pressure and temperature is also investigated for different droplet cloud densities, demonstrating their apparent opposite behavior that must be considered to get optimum propulsion efficiency. In addition, it is illustrated that thermal choking is another criterion which should be avoided by controlling the fuel mass flow rate for intended flight conditions.

Computational Study on the Kinetics and Mechanisms of Unimolecular Reactions of (Z)-(Z)-N-(λ5-phosphanylidene) Formohydrazonic Formic Anhydride: Intramolecular aza-Wittig Reaction in Competition with Mumm Rearrangement

2020 ◽  
Vol 17 (11) ◽  
pp. 884-889
Author(s):  
Somayeh Mirdoraghi ◽  
Hamed Douroudgari ◽  
Farideh Piri ◽  
Morteza Vahedpour
Keyword(s):  
Rate Constants ◽  
Density Functional ◽  
Wittig Reaction ◽  
Computational Study ◽  
Single Step ◽  
Low Energy ◽  
Coupled Cluster ◽  
Unimolecular Reaction ◽  
Single Step Reaction ◽  
Good Agreement

For (Z)-(Z)-N-(λ5-phosphanylidene) formohydrazonic formic anhydride, Aza-Wittig reaction and Mumm rearrangement are studied using both density functional and coupled cluster theories. For this purpose, two different products starting from one substrate are considered that are competing with each other. The obtained products, P1 and P2, are thermodynamically favorable. The product of the aza-Wittig reaction, P1, is more stable than the product of Mumm rearrangement (P2). For the mentioned products, just one reliable pathway is separately proposed based on unimolecular reaction. Therefore, the rate constants based on RRKM theory in 300-600 K temperature range are calculated. Results show that the P1 generation pathway is a suitable path due to low energy barriers than the path P2. The first path has three steps with three transition states, TS1, TS2, and TS3. The P2 production path is a single-step reaction. In CCSD level, the computed barrier energies are 14.55, 2.196, and 10.67 kcal/mol for Aza-Wittig reaction and 42.41 kcal/mol for Mumm rearrangement in comparison with the corresponding complexes or reactants. For final products, the results of the computational study are in a good agreement with experimental predictions.

scholarly journals Numerical Simulation and Analysis on Spray Drift Movement of Multirotor Plant Protection Unmanned Aerial Vehicle

Energies ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 2399 ◽  
Author(s):  
Fengbo Yang ◽  
Xinyu Xue ◽  
Chen Cai ◽  
Zhu Sun ◽  
Qingqing Zhou
Keyword(s):  
Fluid Dynamics ◽  
Computational Fluid Dynamics ◽  
Droplet Size ◽  
Wind Field ◽  
Flow Model ◽  
Two Phase Flow ◽  
Plant Protection ◽  
Three Dimensional ◽  
Phase Flow ◽  
Two Phase

In recent years, multirotor unmanned aerial vehicles (UAVs) have become more and more important in the field of plant protection in China. Multirotor unmanned plant protection UAVs have been widely used in vast plains, hills, mountains, and other regions, and become an integral part of China’s agricultural mechanization and modernization. The easy takeoff and landing performances of UAVs are urgently required for timely and effective spraying, especially in dispersed plots and hilly mountains. However, the unclearness of wind field distribution leads to more serious droplet drift problems. The drift and distribution of droplets, which depend on airflow distribution characteristics of UAVs and the droplet size of the nozzle, are directly related to the control effect of pesticide and crop growth in different growth periods. This paper proposes an approach to research the influence of the downwash and windward airflow on the motion distribution of droplet group for the SLK-5 six-rotor plant protection UAV. At first, based on the Navier-Stokes (N-S) equation and SST k–ε turbulence model, the three-dimensional wind field numerical model is established for a six-rotor plant protection UAV under 3 kg load condition. Droplet discrete phase is added to N-S equation, the momentum and energy equations are also corrected for continuous phase to establish a two-phase flow model, and a three-dimensional two-phase flow model is finally established for the six-rotor plant protection UAV. By comparing with the experiment, this paper verifies the feasibility and accuracy of a computational fluid dynamics (CFD) method in the calculation of wind field and spraying two-phase flow field. Analyses are carried out through the combination of computational fluid dynamics and radial basis neural network, and this paper, finally, discusses the influence of windward airflow and droplet size on the movement of droplet groups.

scholarly journals Numerical analysis of pulverized biomass combustion

2021 ◽  
Vol 321 ◽  
pp. 01001
Author(s):  
Cansu Deniz Canal ◽  
Erhan Böke ◽  
Ali Cemal Benim
Keyword(s):  
Gas Phase ◽  
Radiative Heat ◽  
Particle Dispersion ◽  
Single Step ◽  
Biomass Combustion ◽  
Phase Conversion ◽  
Two Phase ◽  
Dissipation Model ◽  
Turbulent Particle Dispersion ◽  
Step Mechanism

Combustion of pulverized biomass in a laboratory swirl burner is computationally investigated. The two-phase flow is modelled by an Eulerian-Lagrangian approach. The particle size distribution and turbulent particle dispersion are considered. The radiative heat transfer is modelled by the P1 method. For modelling turbulence, different RANS modelling approaches are applied. The pyrolysis of the solid fuel is modelled by a single step mechanism. For the combustion of the volatiles a two-step reaction mechanism is applied. The gas-phase conversion rate is modelled by the Eddy Dissipation Model, combined with kinetics control. The results are compared with measurements.

Droplet size impact on lactofen and acifluorfen efficacy for Palmer amaranth (Amaranthus palmeri) control

2019 ◽  
Vol 34 (3) ◽  
pp. 416-423
Author(s):  
Lucas X. Franca ◽  
Darrin M. Dodds ◽  
Thomas R. Butts ◽  
Greg R. Kruger ◽  
Daniel B. Reynolds ◽  
...  
Keyword(s):  
Droplet Size ◽  
Pulse Width Modulation ◽  
Effective Means ◽  
Cost Effective ◽  
Palmer Amaranth ◽  
Target Movement ◽  
Spray Droplet ◽  
Spray Droplets ◽  
Droplet Sizes ◽  
Biomass Reduction

AbstractHerbicide applications performed with pulse width modulation (PWM) sprayers to deliver specific spray droplet sizes could maintain product efficacy, minimize potential off-target movement, and increase flexibility in field operations. Given the continuous expansion of herbicide-resistant Palmer amaranth populations across the southern and midwestern United States, efficacious and cost-effective means of application are needed to maximize Palmer amaranth control. Experiments were conducted in two locations in Mississippi (2016, 2017, and 2018) and one location in Nebraska (2016 and 2017) for a total of 7 site-years. The objective of this study was to evaluate the influence of a range of spray droplet sizes [150 (Fine) to 900 μm (Ultra Coarse)] on lactofen and acifluorfen efficacy for Palmer amaranth control. The results of this research indicated that spray droplet size did not influence lactofen efficacy on Palmer amaranth. Palmer amaranth control and percent dry-biomass reduction remained consistent with lactofen applied within the aforementioned droplet size range. Therefore, larger spray droplets should be used as part of a drift mitigation approach. In contrast, acifluorfen application with 300-μm (Medium) spray droplets provided the greatest Palmer amaranth control. Although percent biomass reduction was numerically greater with 300-μm (Medium) droplets, results did not differ with respect to spray droplet size, possibly as a result of initial plant injury, causing weight loss, followed by regrowth. Overall, 900-μm (Ultra Coarse) droplets could be used effectively without compromising lactofen efficacy on Palmer amaranth, and 300-μm (Medium) droplets should be used to achieve maximum Palmer amaranth control with acifluorfen.

Understanding Fundamental Physics of Aqueous Droplet Generation Mechanisms in the Aqueous Environment

2017 ◽  
Author(s):  
Mohammad Mastiani ◽  
Seokju Seo ◽  
Sofia Melgar Jimenez ◽  
Nick Petrozzi ◽  
Myeongsub (Mike) Kim
Keyword(s):  
Droplet Formation ◽  
Phase System ◽  
Aqueous Environment ◽  
Flow Focusing ◽  
Two Phase ◽  
Droplet Sizes ◽  
Generation Mechanisms ◽  
Hydrodynamic Behaviors ◽  
Aqueous Droplet ◽  
Droplet Generators

Recent advent of Aqueous-Two-Phase-System (ATPS), more biologically friendly compared to conventional oil-water systems, has shown great potential to rapidly generate aqueous droplets without tedious post-processing. However, understanding of underlying physics of droplet formation in ATPS is still in its infancy. In this paper, we investigate hydrodynamic behaviors and mechanisms of all-aqueous droplet formation in two flow-focusing droplet generators. Two incompatible polymers namely polyethylene glycol (PEG) and dextran (DEX) are mixed in water to make ATPS. The influence of inlet pressures and flow-focusing configurations on droplet sizes, and thread breakup length is studied. Flow regime mapping for two different configurations of droplet generators possessing junction angles of 30° and 90° is also obtained. The results show that droplet size is very susceptible to the junction angle while inlet pressures of the PEG and DEX flows readily control four main flow regimes including back flow, dripping, jetting and stratified.

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