Preparation and characterization of micro or nano cellulose fibers via electroless Ni-P composite coatings

Author(s):  
Yan-Fei Pan ◽  
Jin-Tian Huang ◽  
Xin Wang

Ni-P composite coatings were prepared on cellulose fiber surface via a simple electroless Ni-P approach. The metal-coated extent, dispersion extent of micro or nano cellulose fibers and crystalline structure of Ni-P composite coatings were investigated. The homogeneous hollow composite coatings and metal-coated extent of micro or nano cellulose fibers were improved with the increase in ultrasonic power, and the ideal composite coatings were obtained as ultrasonic up to 960 W. The metallization for cellulose fibers enhanced the dispersion extent of micro or nano cellulose fibers. A uniform coating, consisting of the hollow coating on cellulose fibers surface, could be obtained. At the same time, metallization did not damage the original structure and surface functional groups of cellulose fibers. The concentration of cellulose fibers and ultrasonic power had a direct influence on the metal-coated extent of cellulose fiber surface. The metal-coated extent, dispersion extent of micro or nano cellulose fibers and crystalline structure of Ni-P composite coatings exhibited excellent properties as the concentration of cellulose fibers and ultrasonic power were 2 g/L and 960 W, respectively.

2016 ◽  
Vol 147 ◽  
pp. 282-293 ◽  
Author(s):  
Bamdad Barari ◽  
Emad Omrani ◽  
Afsaneh Dorri Moghadam ◽  
Pradeep L. Menezes ◽  
Krishna M. Pillai ◽  
...  

Vacuum ◽  
2018 ◽  
Vol 155 ◽  
pp. 553-558 ◽  
Author(s):  
Bo Liu ◽  
Yanfei Pan ◽  
Guangming Sun ◽  
Jintian Huang

Author(s):  
Hossein Kazemi ◽  
Frej Mighri ◽  
Keun Wan Park ◽  
Slim Frikha ◽  
Denis Rodrigue

ABSTRACT In recent years, cellulose fibers have attracted considerable attention as biofillers for natural rubber (NR) composites. However, neat cellulose cannot be used as a substitute for conventional fillers due to its poor compatibility with NR. Therefore, a new surface treatment via maleic anhydride grafted to polyisoprene (MAPI) in solution was developed to improve the filler–matrix interaction. Different contents of carbon black (CB) and cellulose fibers (before and after modification) were used as a hybrid filler system to investigate the possibility of CB substitution in NR composites. First, contact angle, Fourier transformed infrared spectrometry (FTIR), and scanning electron microscopy (SEM) techniques were used to confirm the successful cellulose surface treatment. Second, morphological analysis, Payne effect, and swelling behavior of the rubber compounds in toluene confirmed the effect of cellulose treatment on improving the interfacial filler–matrix adhesion. Finally, the results showed that the composite filled with 20 phr modified cellulose and 20 phr CB (50% replacement of CB) exhibited even better results than the composite filled with 40 phr of CB, since the tensile strength was only 7% lower, but the elongation at break, tensile modulus at 100%, and storage modulus at 25 °C were respectively 35%, 24%, and 22% higher.


2014 ◽  
Vol 936 ◽  
pp. 784-788 ◽  
Author(s):  
Chao Dong ◽  
Ying Ye ◽  
Li Ying Qian ◽  
Bei Hai He ◽  
Hui Ning Xiao

Cyclodextrins (CDs) can form inclusion complexes with a variety of molecules making them very attractive in different areas, such as pharmaceutics, biochemistry, food chemistry and papermaking. In this communication the preparation of β-cyclodextrin-grafted cellulose fibers was carried out by reacting β-cyclodextrin with cellulose fiber via citric acid (CA). Both fourier transform infrared (FTIR) and cross polarization magic angle spinning solid state nuclear magnetic resonance (CP-MAS NMR) indicated that β-CDs had been chemically attached to cellulose backbone through the formation of ester bonds. Furthermore, the β-CD-grafted cellulose fibers formed inclusion complexes with ciprofloxacin hydrochloride (CipHCl). And the β-CD-grafted cellulose fibers loaded with CipHCl showed excellent antibacterial activity against E.coli and S.aureus.


2014 ◽  
Vol 10 (3) ◽  
pp. 427-436 ◽  
Author(s):  
Meng Li ◽  
Yan-Ling Cheng ◽  
Nan Fu ◽  
Dong Li ◽  
Benu Adhikari ◽  
...  

Abstract Cellulose fibers were obtained from corncob by using microwave-assisted chemical treatments (microwave-assisted alkaline pretreatment and microwave-assisted bleaching). These treatments efficiently removed the hemicellulose and lignin from the original corncob and increased the cellulose fiber content. The morphology, chemical structure, degree of crystallinity and thermal degradation characteristics of the resultant cellulose fibers were studied by using field emission scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction and thermogravimetric analysis. These microwave-assisted chemical treatments decreased the diameter of the cellulose fibers from 25–125 µm to 10–20 µm. The crystallinity of the corncob cellulose fibers increased from 32.7% to 73% due to the chemical treatments. The degradation temperature of the cellulose fibers was >260°C. The cellulose fibers obtained from these treatments can be used as biocomposites in reinforced polymer manufacturing.


2011 ◽  
Vol 1 (1) ◽  
pp. 19-26 ◽  
Author(s):  
Yongjian Yang ◽  
Weiwei Chen ◽  
Chungen Zhou ◽  
Huibin Xu ◽  
Wei Gao

2019 ◽  
Vol 20 (5) ◽  
pp. 556-562
Author(s):  
Young-Min Byoun ◽  
Jin-doo Yoon ◽  
Sang-Jo Na ◽  
Sun-Kyo Seo

2000 ◽  
Vol 225 (2) ◽  
pp. 455-459 ◽  
Author(s):  
Eduardo A. Toledo ◽  
Yoshitaka Gushikem ◽  
Sandra C. de Castro

Sign in / Sign up

Export Citation Format

Share Document