The engineering geology of clay minerals: swelling, shrinking and mudrock breakdown

Clay Minerals ◽  
1986 ◽  
Vol 21 (3) ◽  
pp. 235-260 ◽  
Author(s):  
R. K. Taylor ◽  
T. J. Smith

AbstractSwelling, shrinking and physical breakdown processes are reviewed with reference to well-known mudrock and overconsolidated clay formations in the UK and USA. Swelling results from two processes: the equilibration of depressed porewater pressures following stress relief, and the physico-chemical (osmotic) response of component clay minerals. Expansion in Na-smectite, and to a lesser extent Ca-smectite, clays is governed by double-layer swelling, whereas in kaolinites it is purely a mechanical unloading phenomenon; illites show an intermediate response. Intraparticle swelling in mudrocks older than the Silurian in the UK, or Upper Mississippian in the USA, can be expected to be reduced because of the removal of expandable layers by burial diagenesis. Shrinkage, like mudrock breakdown, is restricted to the partly saturated zone. Suction pressure-moisture content curves of indurated mudrocks are shown to be different from mudrocks and clays with high proportions of expandable clay minerals. Classification of expansion potential based on activity ratio poses problems with indurated types, but with some modification of method reasonable predictions can be made. Controls on physical disintegration are identified as: (i) incidence of sedimentary structures and discontinuities, (ii) slaking (air breakage), (iii) expandable clay mineral content, especially smectite, and (iv) clay mineral fabric orientation. Exceptionally high exchangeable sodium percentages have been measured in Coal Measures rocks susceptible to breakdown.

2020 ◽  
Vol 45 (4) ◽  
Author(s):  
E.E.I. Irabor ◽  
A. K. Okunkpolor

The physico-chemical and mineralogical properties of a clay mineral deposit in Geheku, Kogi State, Nigeria were assessed. The results of the study revealed that the deposit consisted of phyllosilicate minerals- Illite, montmorillonite, kaolinite, halloysite, almandine; other minerals present were quartz and ramsdellite. The clay minerals exhibited good swelling property, medium plasticity, good thermal shock resistance and apparent porosity; it had refractoriness below 1200 oC. The properties of the clay reflected the combined properties of the constituent clay and non-clay minerals which recommends it for a variety of applications which requires the blend of property though the working temperature must be below 1200 oC. The clay mineral deposit colours were influenced by the minerals almadine and ramsdellite.


Clay Minerals ◽  
1993 ◽  
Vol 28 (3) ◽  
pp. 393-416 ◽  
Author(s):  
J. D. Platt

AbstractAuthigenic clay minerals in the German Rotliegend formed mainly at burial depths >1.5 km. Illite is the dominant cement, although kaolinite, dickite and early radial chlorite are abundant locally. Illites contain more AI and late chlorites more AI and Fe in sequences showing extensive grain dissolution. This relationship between clay chemistry and grain dissolution suggests that clay cementation is linked to grain dissolution. Sequences at relatively shallow burial depths (<3-5 km) contain less clay cement. In the more deeply buried sections, increased illite and kandite cementation, together with extensive grain dissolution, is evident where the Rotliegend is juxtaposed against Carboniferous Coal Measures. Faults also acted as important conduits for acidic fluids. Illite and kandite growth occurred at similar depths and from waters of similar isotopic composition (618O = 1-6‰ SMOW) throughout most of the Southern Permian Basin. However, the timing of illite growth varied between areas and corresponded to periods to tectonic activity.


Author(s):  
Lan Nguyen-Thanh ◽  
Rafael Ferreiro Mählmann ◽  
Thao Hoang-Minh ◽  
Rainer Petschick ◽  
Thomas Reischmann ◽  
...  

AbstractHydrothermally altered rhyolite rocks in the Permian Donnersberg Formation of a geothermal borehole in the Northern Upper Rhine Graben (Germany) were investigated to find out answers for the low hydraulic conductivity of the rocks. The composition of clay minerals and the temperature of smectite–illite transformation were carried out using X-ray diffraction, X-ray fluorescence, transmission electron microscopy, Fourier transform infrared spectroscopy, and polarized-light microscopy analyses. Clay mineral (CM) composition includes illite/muscovite (1M and 2M1 polytypes), illite–smectite interstratifications (IS-ml), smectite, and chlorite; and non-clay minerals such as quartz, feldspars, epidote, calcite, dolomite, and hematite were detected. The 2M1-polytype mica might be the only primary sheet silicates from the parent rocks, while the others occur as authigenic neo-formed CMs under heat flow and geothermal gradient. The development of CMs indicates different mechanisms of illitization and smectitization. Based on the texture, morphology, structure/polytype, and chemistry of rocks and minerals, in particular CMs, the study grouped the CM formation into three transformation processes: smectitization during magma cooling and possible contact metamorphisms with decreasing and low temperature, smectite illitization controlled by burial diagenesis and hydrothermal alteration, and illite smectitization followed exhumation and Cenozoic subsidence with decreasing temperature. The rhyolites were altered to all of the orders IS-R0, IS-R1, and IS-R3 by the dissolution-precipitation and layer-to-layer mechanisms. The first one supported small xenomorphic plates and flakes of 1Md, elongated particles of 1M, and pseudo-hexagonal forms of 2M1. The second one could lead to the platy particles of 1Md and 2M1 polytypes. The dominant temperature range for the transformation in the area has been 140–170 °C– ~ 230 °C.


Detritus ◽  
2020 ◽  
pp. 100-113
Author(s):  
Mercedes Regadío ◽  
Jonathan A. Black ◽  
Steven F. Thornton

Engineered synthetic liners on their own cannot protect the environment and human health against landfill leachate pollution. Despite their initial impermeability, they are susceptible to failure during and after installation and have no attenuation properties. Conversely, natural clay liners can attenuate leachate pollutants by sorption, redox transformations, biodegradation, precipitation, and filtration, decreasing the pollutant flux. Depending on the clay, significant differences exist in their shrinkage potential, sorption capacity, erosion resistance and permeability to fluids, which affects the suitability and performance of the potential clay liner. Here, the physico-chemical, mineralogical and geotechnical characteristics of four natural clayey substrata were compared to discuss their feasibility as landfill liners. To study their chemical compatibility with leachate and rainwater, hydraulic conductivities were measured every ≈2 days spread over 7 weeks of centrifugation at 25 gravities. At field-scale, this is equivalent to every 3.4 yrs spread over 80 yrs. All the clayey substrata had favourable properties for the attenuation of leachate pollutants, although different management options should be applied for each one. London Clay (smectite-rich) is the best material based on the sorption capacity, hydraulic conductivity and low erodibility, but has the greatest susceptibility to excessive shrinkage and alterable clay minerals that partially collapse to illitic structures. Oxford Clay (illite rich) is the best material for buffering acid leachates and supporting degradation of organic compounds. The Coal Measures Clays (kaoline-rich) have the lowest sorption capacity, but also the lowest plasticity and have the most resistant clay minerals to alteration by leachate exposure.


Detrital clay minerals alter systematically during burial diagenesis. Smectites evolve via intermediate ‘illite-smectites’ to illite. Trioctahedral ‘smectite-chlorites’ or ‘vermiculite-chlorites’ evolve towards true (polytype Ib) chlorites. In other reactions, authigenic clays (kaolinite, illite, chlorite) precipitate directly from aqueous solution rather than by continuous modification of some precursor lattice. In yet others, one mineral replaces another. Many of these reactions are influenced by organic matter and the various low molecular mass soluble products of its diagenetic and thermal maturation. Carbon dioxide and organic acids influence pore-water pH and this, in turn, affects the solubility of clay minerals. Trioctahedral phyllosilicates are particularly sensitive. In contrast, organic matter also acts as a reducing agent when iron (III) oxides are destabilized to produce Fe 2+ and a marked increase in alkalinity. This reaction stabilizes trioctahedral clays such as chamosite. The balance between these different reactions affects the course of clay mineral diagenesis and itself varies systematically with burial depth and temperature.


2003 ◽  
Vol 53 (2) ◽  
pp. 195-213 ◽  
Author(s):  
K. Majoros

The study introduces a Hungarian economic thinker, István Varga*, whose valuable activity has remained unexplored up to now. He became an economic thinker during the 1920s, in a country that had not long before become independent of Austria. The role played by Austria in the modern economic thinking of that time was a form of competition with the thought adhered to by the UK and the USA. Hungarian economists mainly interpreted and commented on German and Austrian theories, reasons for this being that, for example, the majority of Hungarian economists had studied at German and Austrian universities, while at Hungarian universities principally German and Austrian economic theories were taught. István Varga was familiar not only with contemporary German economics but with the new ideas of Anglo-Saxon economics as well — and he introduced these ideas into Hungarian economic thinking. He lived and worked in turbulent times, and historians have only been able to appreciate his activity in a limited manner. The work of this excellent economist has all but been forgotten, although he was of international stature. After a brief summary of Varga’s profile the study will demonstrate the lasting influence he has had in four areas — namely, business cycle research and national income estimations, the 1946 Hungarian stabilisation program, corporate profit, and consumption economics — and will go on to summarise his most important achievements.


Author(s):  
Marco M. Fontanella ◽  
Giorgio Saraceno ◽  
Ting Lei ◽  
Joshua B. Bederson ◽  
Namkyu You ◽  
...  
Keyword(s):  
The Usa ◽  

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