Compositional variation in högbomites from north Connemara, Ireland

1985 ◽  
Vol 49 (354) ◽  
pp. 649-654 ◽  
Author(s):  
N. S. Angus ◽  
R. Middleton
Keyword(s):  
Chemical Composition ◽  
Regional Metamorphism ◽  
The Other ◽  
Partial Substitution ◽  
Compositional Variation ◽  
Physical Parameters ◽  
Chemical Heterogeneity ◽  
High Grade ◽  
Thermal Metamorphism ◽  
Mineral Assemblages

AbstractHögbomite occurs in two contrasting mineral assemblages within the Currywongaun-Dough-ruagh intrusion of north Connemara: a cordierite-rich pelitic xenolith and an orthopyroxenite. In the latter, högbomite and green spinel form blebs within magnetite-ilmenite grains. The högbomite displays significant compositional variation from grain to grain: TiO2 (3.0–6.3%), FeO (21.6–21.3%), MgO (10.0–7.5%), ZnO (3.6–2.4%). This chemical heterogeneity appears to represent variable degrees of partial substitution of Mg and Zn by Ti, in the replacement of spinel by högbomite. By contrast, in the cordierite-hornfels, the högbomite compositions are more notably enriched in iron: TiO2 (4.7–7.0%), FeO (29.6–24.3%), MgO (4.2–6.2%), ZnO (2.7–2.1%). This iron-rich högbomite appears to have formed primarily by interaction between opaque ore and adjacent cordierite, rather than by replacement of spinel.Two high-grade metamorphic episodes appear to be necessary for högbomite growth, one determining chemical composition and the other appropriate physical parameters. In the Connemara occurrences thermal metamorphism and partial melting, coupled with contamination of the surrounding magma, controlled the formation of mineral assemblages rich in Fe, Mg, Al, Ti, and Zn. Emplacement of the intrusion was accompanied by amphibolite facies regional metamorphism and it is to this metamorphic event that the growth of högbomite may be attributed.

Further Data on the Petrology of the Pelitic Hornfelses of the Carn Chuinneag–Inchbae Region, Ross-shire, with Special Reference to the Status of Almandine

1954 ◽  
Vol 91 (6) ◽  
pp. 445-462 ◽  
Author(s):  
R. I. Harker
Keyword(s):  
Special Reference ◽  
Regional Metamorphism ◽  
The Other ◽  
Contact Metamorphism ◽  
Chemical Data ◽  
Chemical Analyses ◽  
Thermal Metamorphism ◽  
Massive Structure ◽  
Mineral Assemblages ◽  
The Status

AbstractThe pelitic hornfelses surrounding the Carn Chuinneag–Inchbae complex have, with the other rocks in the area, been subjected to the regional metamorphism which affected the Moine Series as a whole. The minerals of the original hornfelses have reacted to form assemblages which are typical of regional rather than purely thermal metamorphism although the massive structure of the hornfelses is well preserved.By studying the changes which took place in the hornfelses during the regional metamorphism it has been possible to deduce the most likely mineral assemblages indigenous to the original hornfelses.The results of the chemical analyses of some of the pelitic hornfelses are presented and chemical data on some of the garnets are given. It is considered unlikely that all the garnets in the hornfelses, which are essentially almandines, formed as a result of the earlier contact metamorphism: some at least probably occur as a result of the later regional metamorphism.

XX.—The Metamorphism of the Deeside Limestone, Aberdeenshire

1933 ◽  
Vol 57 (2) ◽  
pp. 557-592 ◽  
Author(s):  
Arthur G. Hutchison
Keyword(s):  
Regional Metamorphism ◽  
High Grade ◽  
Thermal Metamorphism

The limestone to be described occurs in two separate areas (fig. 1)—one in Lower Deeside around Banchory, another in Middle Deeside around Aboyne. The whole of the Banchory and a large part of the Aboyne outcrops provide limestone types in a high grade of regional metamorphism (the associated schists contain sillimanite). In the latter outcrop the limestone has undergone thermal metamorphism at the contacts with Newer Granite intrusions. Many of the resulting hornfelses have suffered hydrothermal alterations with development of prehnite and zeolites. Newer Granite pegmatites, intruded at the time of hornfelsing, share in this hornfelsing and later hydrothermal modifications. In addition, they exercise exopneumatolytic and exohydrothermal metamorphism. Quite local metamorphisms take place at hornblende-schist and Older Granite contacts.

Study of Garnets by ALCHEMI

2001 ◽  
Vol 7 (S2) ◽  
pp. 358-359
Author(s):  
János L. Lábár ◽  
Lajos Tόth ◽  
István Dόdony ◽  
Jerzy Morgiel
Keyword(s):  
Crystal Structure ◽  
Chemical Composition ◽  
High Sensitivity ◽  
Unit Cell ◽  
Previous Literature ◽  
The Other ◽  
Axial Orientation ◽  
Partial Substitution ◽  
X Ray ◽  
Oxygen Atoms

Garnets were one of the first materials in which an occupation of separate lattice sites by different atomic species was determined with an ALCHEMI technique proposed by Spence and Tafto in l982. The reason of so much interest in this material was twofold, i.e. first its known high sensitivity of X-ray generation depending on orientation especially in the axial orientation and second its complicated crystal structure allowing different atomic arrangements in the unit cell depending on its chemical composition. The dodecahedral (X), octahedral (Y) and tetrahedral (Z) sites between the relatively large oxygen atoms can be filled with a variety of small cations in accordance with the formula X3Y2Z3O12. Partial substitution of one cation with another is common in this structure. The results presented in the previous literature indicated that ALCHEMI can only separate the Y-sites from the sum of the other two (X+Z), while the latter has to remain unresolved.

The Genesis of Oligoclase in Certain Schists

1933 ◽  
Vol 70 (12) ◽  
pp. 529-541 ◽  
Author(s):  
F. J. Turner
Keyword(s):  
Chemical Composition ◽  
Bulk Composition ◽  
Regional Metamorphism ◽  
Slight Modification ◽  
Igneous Rocks ◽  
Calcic Plagioclase ◽  
Irregular Distribution ◽  
Thermal Metamorphism

The mineralogical changes in green schists and related quartzofelspathic schists of sedimentary origin are discussed, and the following conclusions are reached as to the conditions of formation of oligoclase in these rocks:—(1) Oligoclase normally appears as a product of dynamothermal metamorphism at relatively high grades such as prevail in the zones of almandine and perhaps kyanite. It is accompanied either by deeply-coloured hornblende, hornblende and biotite, or biotite and muscovite, according to the chemical composition of the rocks in which it occurs.(2) Sodic oligoclase containing 10 per cent to 15 per cent of anorthite may occur with pale aluminous hornblende in green schists lying within the more strongly metamorphosed portion of the chlorite zone. The rocks in question are low in potash and have been formed by reconstitution, at a higher grade, of chlorite-epidotealbite-schists containing calcite. This oligoclase-hornblende association is not to be confused with the actinolite-epidote-albite-chlorite assemblage which is formed at any grade within the zone of chlorite, by direct reconstitution of basic igneous rocks without change in bulk composition and in the absence of CO2. A slight modification of Tilley’s subdivision of the green schist facies of Eskola is therefore introduced.(3) A zone of oligoclase representing a grade of metamorphism higher than that attained in the biotite zone, may be recognized for quartzo-felspathic schists of appropriate composition and for many green schists, in areas of progressive regional metamorphism. In the latter case, blue-green hornblende often accompanied by biotite is also present.(4) Oligoclase or more calcic plagioclase and deeply-coloured hornblende form readily during purely thermal metamorphism of only medium grade in the absence of stress. This accounts for the irregular distribution of both these minerals in districts where purely thermal and regional metamorphism have both occurred during the same period of orogeny.

Epidiorite–limestone contact relations at Burawai, Hazara District, West Pakistan

1965 ◽  
Vol 34 (268) ◽  
pp. 82-91
Keyword(s):  
Regional Metamorphism ◽  
Thermal Metamorphism ◽  
Mineral Assemblages

SummarySpecial mineral assemblages in calcareous rocks 0–6 ft from the contact of an epidiorite sill are interpreted as the result of polymetamorphism–regional metamorphism superimposed on an earlier thermal metamorphism in which metasomatism, especially migration of potassium, was important.

The Glen Dessarry Marble and its Associated Calc-Silicate Rocks.

1951 ◽  
Vol 88 (6) ◽  
pp. 393-403 ◽  
Author(s):  
W. T. Harry
Keyword(s):  
Regional Metamorphism ◽  
The Other ◽  
High Grade ◽  
Potash Feldspar ◽  
White Marble ◽  
Silicate Rocks

AbstractWhite marble in Glen Dessarry, West Highlands of Scotland, occurs as three lenses associated with schists and calc-silicate rocks. The minerals identified in all these rocks are apatite, biotite, calcite, chondrodite, clinochlore, clinozoisite, diopsidic-pyroxene, dolomite, epidote, forsterite, garnet, hornblende, magnetite, phlogopite, plagioclase, potash-feldspar, pyrites, quartz, scapolite, sillimanite, sphene, vesuvianite, zoisite.Two parageneses may be distinguished. One, due to high-grade regional metamorphism, apparently with little or no introduction of material, is a diopsidic-pyroxene, forsterite, phlogopite, calcite, dolomite association forming white marble. The other association occurs as veinlets and small irregular bodies in the white marble. It appears to be due to circulating solutions in which pyroxene and forsterite were unstable. Minerals of this paragenesis include potash-feldspar, plagioclase, scapolite, hornblende, minerals of the epidote group, calcite, and quartz. In certain localities scapolite formed at the expense of plagioclase and was succeeded by crystallization of epidote.

Effect Of Compositional Variation Of The Physical Parameters Of Ge-Se-In Glass System

2014 ◽  
Vol 2 (1) ◽  
pp. 1-6
Author(s):  
Surbhi Sharma ◽  
◽  
Amit Sarin ◽  
Navjeet Sharma ◽  
◽  
...  
Keyword(s):  
Glass System ◽  
Compositional Variation ◽  
Physical Parameters

Plasma parameters in atomic-emission spectral analysis of phosphate concentrates of the fission products

2019 ◽  
Vol 85 (2) ◽  
pp. 17-22
Author(s):  
M. I. Khamdeev ◽  
E. A. Erin
Keyword(s):  
Spectral Analysis ◽  
Chemical Composition ◽  
Reference Materials ◽  
Fission Products ◽  
Atomic Emission ◽  
Electric Arc ◽  
Physical Parameters ◽  
Arc Plasma ◽  
Atomic Emission Spectral Analysis ◽  
Excitation Processes

Physical parameters of electric arc plasma as well as their time dependences are calculated when analyzing phosphate precipitates of the fission products of irradiated nuclear fuel. Phosphate concentrates of the fission products are known for their complex chemical composition and high thermal and chemical stability. Hence, direct atomic emission spectral analysis of phosphate powders without transferring them into solutions is advisable. Different conditions of sample preparation and synthesis of the reference materials determine the different chemical forms of the elements to be determined. This, in turn, affects the kinetics of their evaporation in the electrode crate and excitation processes in the plasma. The known mechanisms of those processes cannot always be transferred to specific conditions of the given method of analysis thus entailing the necessity of studying the effect of the samples chemical composition on the results of determination, proper choice of spectroscopic carriers, detailed study of spectra excitation processes in spectral analysis, and analysis of the physical parameters of the electric arc plasma. We used the lines Zn I 307.206 nm and Zn I 307.589 nm to measure the effective temperature of the central hot sections of the arc in a range of4500 - 6500 K. NaCl, BaCl2 and NaCl + T1C1 were studied to reduce the effect of the sample elemental composition on excitation conditions of the spectra and their stabilization as a spectroscopic carrier. In control experiments we used carrier-free samples. The coincidence of the values of the plasma physical parameters within the measurement error not exceeding 20%, as well as the identity of the nature of the kinetic curves for samples of phosphate precipitates and synthetic reference materials prove their correctness. The result of the study substantiate correctness of the direct atomic-emission spectral procedure in analysis of phosphate concentrates of fission when using synthetic reference materials.

scholarly journals Biofoam of Spittlebug, Poophilus costalis (Walker): Preferential Sites, Temperature Regulation, Chemical Composition and Antimicrobial Activity

Insects ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 340
Author(s):  
Kitherian Sahayaraj ◽  
Balakrishnan Saranya ◽  
Samy Sayed ◽  
Loko Yêyinou Laura Estelle ◽  
Koilraj Madasamy
Keyword(s):  
Antimicrobial Activity ◽  
Chemical Composition ◽  
High Performance ◽  
Host Plants ◽  
Ground Level ◽  
College Campus ◽  
The Other ◽  
Mimosa Pudica ◽  
Ft Ir ◽  
Gas Chromatography Mass Spectroscopy

The foam produced by nymphs of Poophilus costalis on eleven different host plants belonging to eight families on St. Xavier’s College campus in India was studied over five months. The chemical composition and antimicrobial activity of these biofoams were investigated. The results revealed that P. costalis preferred Theporsia purpurea and Mimosa pudica for laying their eggs and producing foam, over the other tested plants. P. costalis produce their foam on either nodes or internodes on monocotyledons (30%) (p < 0.05), whereas on dicotyledons, they produce more foam on the stems (63.8%) than on the leaves (6.2%) (p < 0.01). The number of nymphs in each piece of foam from P. costalis varied from 1 to 3 (mean = 1.8 per plant). They produced their foam (5.7 to 45.2 cm) from the ground level on a plant. The length and breadth of a piece of foam ranged from 1.0 to 3.9 cm and 0.6 to 4.7 cm, respectively. The foam tended to be cooler than the environment. Qualitative profiling showed that the foam consists of carbohydrates, including maltose; trypsin; amino acids; protease. The foam was also analyzed using a spectrophotometer, Fourier transform infrared spectroscopy (FT-IR), gas chromatography–mass spectroscopy (GC-MS), and high-performance liquid chromatography (HPLC). The antimicrobial activity of the biofoam was the greatest against Staphylococcus aureus, the growth of which was reduced by 55.9 ± 3.9%, suggesting that the foam could be used as an antimicrobial product. However, no activities were observed against Fusarium oxysporum and Candida albicans.

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