scholarly journals Synthesis and Study the Chelating Activity of some Polymers Containing Heterocyclic Rings, The Derivatives from 1,2,4- trizol Levofloxacin acid

2018 ◽  
Vol 34 (4) ◽  
pp. 2031-2042 ◽  
Author(s):  
Tahseen Saddam Fandi Al-Mathkuri ◽  
Hamid Mohammed Saleh Al-Jubori ◽  
Ali Taha Saleh
Keyword(s):  
Schiff Bases ◽  
Treatment Time ◽  
Phenol Formaldehyde ◽  
Thermal Studies ◽  
Structural Features ◽  
Batch Method ◽  
Synthetic Compounds ◽  
Chelating Activity ◽  
Effect Of Treatment ◽  
Chelating Polymers

The compound 6-amino-5-mercapto-4H-1,2,4-triazol-3-yl)-9-fluoro-3-methyl-10-(4-methylpiperazin-1-yl)-2,3-dihydro-7H-[1,4] oxazino[2,3,4-ij] quinolin-7-one (M1) synthesize from the reaction of thiocarbohydrazide with levofloxacin acid by using ethanol as a solvent, phenolic Schiff bases (Z)-9-fluoro-6-(4-((4-hydroxybenzylidene) amino)-5-mercapto4H1,2,4-triazol-3-yl)-3-methyl-10-(4-methylpiperazin-1-yl)-2,3-dihydro-7H-[1,4]oxazino[2,3,4-ij] quinolin-7-one (M2), (Z)-6-(4-((2,4-dihydroxybenzylidene) amino)-5-mercapto-4H-1,2,4-triazol-3-yl)-9-fluoro-3-methyl-10-(4-methylpiperazin-1-yl)-2,3-dihydro-7H-[1,4] oxazino[2,3,4-ij]quinolin-7-one (M3) and (Z)-6-(4-((5-chloro-2-hydroxybenzylidene) amino)-5-mercapto-4H-1,2,4-triazol-3-yl)-9-fluoro-3-methyl-10-(4-methylpiperazin-1-yl)-2,3-dihydro-7H- [1,4] oxazino[2,3,4-ij] quinolin-7-one (M4) were prepared from the reaction of trizol derivative of [M1] compound with the appropriate phenolic aldehydes by using ethanol as a solvent. The synthetic Schiff bases used to prepare numbers of phenolic polymers [M5-M7] from the reaction of Schiff bases [M2-M4] with phenol formaldehyde. The analytical efficiency of the synthetic chelating polymers studied by the batch method with different transition metals ions (Cd2+, Fe3+, Cu2+), in terms of the effect of treatment time and the pH on the loading capacity of the polymers, controlling the other factors such as temperature, ions concentration and quantity of polymers. The result shows that the capacity of the polymer increased with increasing of the pH and treating time. The synthetic compounds were characterized by various instrumental techniques like FTIR, 1H-NMR, DTG and TGA studies.These spectral and thermal studies provide very valuable information about the structural features.

scholarly journals 214 The effects of an 18-hour transit or complete feed and water restriction on feed bunk displacements and need preferences in growing feedlot steers

2020 ◽  
Vol 98 (Supplement_3) ◽  
pp. 5-5
Author(s):  
Katie J Heiderscheit ◽  
Erin Deters ◽  
Alyssa Freestone ◽  
Joshua Peschel ◽  
Stephanie L Hansen
Keyword(s):  
Repeated Measures ◽  
Dry Matter ◽  
Treatment Time ◽  
Dry Matter Intake ◽  
Feed Restriction ◽  
Water Restriction ◽  
Trained Observer ◽  
Aggressive Interactions ◽  
Feedlot Steers ◽  
Effect Of Treatment

Abstract The objective was to investigate effects of 18 h feed and water restriction or transit on cattle behavior. Angus-cross steers (36; 353 ± 33 kg) were housed in pens of 6 and assigned to treatments: control (CON), full access to feed and water; deprived (DEPR), no feed or water for 18 h; or transported (TRANS), trucked for 18 h. Individual BW (n = 12 steers/treatment) was recorded on d 0, 1, 3, 8, and 14, and individual dry matter intake (DMI) was determined via GrowSafe bunks. Bunk displacements on d 1 were recorded for each pen (n = 2 pens/treatment) by one trained observer continuously for 2 h in 10 min intervals via video analysis. Steer need preferences were assessed as time individuals took to perform behaviors (eat, drink, lay) after treatments ended on d 1. Data were analyzed using Proc Mixed of SAS with fixed effect of treatment; displacements, BW, and DMI were analyzed as repeated measures. Upon return to pens, time to eat or drink did not differ between DEPR and TRANS (P ≥ 0.17), but time to lay was 70.5 min for DEPR vs. 16.5 min for TRANS (P = 0.01). Displacements were greater for DEPR than CON or TRANS during the first 90 min after accessing feed, while CON displaced more frequently than TRANS for the first 30 min (treatment × time; P = 0.02). While DMI for TRANS was not recovered until d 2, DEPR and CON had similar DMI on d 1 (treatment × day; P < 0.01). Similarly, TRANS BW were, and DEPR tended to be, lesser than CON on d 1; however, BW among treatments were not different on other days (treatment × day; P < 0.01). Thus, restricting feed increases aggressive interactions at the bunk and cattle trucked long distances are quick to lay down when allowed. These behaviors should be considered when managing an unintentional feed restriction event or receiving cattle into the feedlot.

scholarly journals Selective Removal of Toxic Metals like Copper and Arsenic from Drinking Water Using Phenol-Formaldehyde Type Chelating Resins

2009 ◽  
Vol 6 (4) ◽  
pp. 1035-1046 ◽  
Author(s):  
Debasis Mohanty ◽  
Shashadhar Samal
Keyword(s):  
Drinking Water ◽  
Schiff Bases ◽  
Toxic Metals ◽  
Metal Ion ◽  
Phenol Formaldehyde ◽  
Low Cost ◽  
Arsenic Concentration ◽  
Copper Ion ◽  
Toxic Metal ◽  
Chelating Resins

The concentration of different toxic metals has increased beyond environmentally and ecologically permissible levels due to the increase in industrial activity. More than 100 million people of Bangladesh and West Bengal in India are affected by drinking ground water contaminated with arsenic and some parts of India is also affected by poisoning effect of copper, cadmium and fluoride. Different methods have been evolved to reduce the arsenic concentration in drinking water to a maximum permissible level of 10 μg/L where as various methods are also available to separate copper from drinking water. Of the proven methods available today, removal of arsenic by polymeric ion exchangers has been most effective. While chelating ion exchange resins having specific chelating groups attached to a polymer have found extensive use in sorption and pre concentration of Cu2+ions. Both the methods are coupled here to separate and preconcentrate toxic metal cation Cu2+and metal anion arsenate(AsO4–) at the same time. We have prepared a series of low-cost polymeric resins, which are very efficient in removing copper ion from drinking water and after coordinating with copper ion they act as polymeric ligand exchanger, which are efficiently removing arsenate from drinking water. For this purpose Schiff bases were prepared by condensingo-phenylenediamine witho-,m-, andp-hydroxybenzaldehydes. Condensing these phenolic Schiff bases with formaldehyde afforded the chelating resins in high yields. These resins are loaded with Cu2+, Ni2+2+, and Fe3+ions. The resins and the polychelates are highly insoluble in water. In powdered form the metal ion-loaded resins are found to very efficiently remove arsenate ion from water at neutral pH. Resins loaded with optimum amount of Cu2+ion is more effective in removing arsenate ions compared to those with Fe3+ion, apparently because Cu2+is a stronger Lewis acid than Fe3+. Various parameters influencing the removal of the arsenate ion from drinking water to a concentration level below 20 μg/L are studied.

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