Abstract. We investigate the optical properties of light-absorbing organic carbon
(brown carbon) from domestic wood combustion as a function of simulated
atmospheric aging. At shorter wavelengths (370–470 nm), light absorption by
brown carbon from primary organic aerosol (POA) and secondary organic
aerosol (SOA) formed during aging was around 10 % and 20 %,
respectively, of the total aerosol absorption (brown carbon plus black
carbon). The mass absorption cross section (MAC) determined for black carbon
(BC, 13.7 m2 g−1 at 370 nm, with geometric standard deviation GSD =1.1) was consistent with that
recommended by Bond et al. (2006). The corresponding MAC of POA
(5.5 m2 g−1; GSD =1.2) was higher than that of SOA
(2.4 m2 g−1; GSD =1.3) at 370 nm. However, SOA presents a
substantial mass fraction, with a measured average SOA ∕ POA mass ratio
after aging of ∼5 and therefore contributes significantly to the
overall light absorption, highlighting the importance of wood-combustion SOA
as a source of atmospheric brown carbon. The wavelength dependence of POA and
SOA light absorption between 370 and 660 nm is well described with
absorption Ångström exponents of 4.6 and 5.6, respectively.
UV-visible absorbance measurements of water and methanol-extracted OA were
also performed, showing that the majority of the light-absorbing OA is water
insoluble even after aging.