scholarly journals Esterification of Waste Cooking Oil Using Ultrasonic: Kinetic Study

2019 ◽  
Vol 20 (2) ◽  
pp. 57-68
Author(s):  
Egi Agustian ◽  
Jessica Jessica ◽  
Pudji Untoro ◽  
Anny Sulaswatty
Keyword(s):  
Phosphoric Acid ◽  
Conventional Method ◽  
Acid Catalyst ◽  
Waste Cooking Oil ◽  
Reaction Rate Constant ◽  
Order Reaction ◽  
Second Order ◽  
Raw Material ◽  
Irreversible Reaction ◽  
Cooking Oil

Waste cooking oil (WCO) have a great potential as an alternative raw material for producing biodiesel. The literatures kinetic of the esterification of WCO in the presence of phosphoric acid catalyst with ultrasonic assisted are rare and most literatures used conventional method. This study aims to determine the optimum condition and the parameters of first and second order kinetics of the WCO esterification which was assisted by ultrasonic bath. Variables that used in this study are methanol/oil mole ratio, acid catalyst concentration and reaction temperature. The highest conversion was 42.08% with methanol/oil mole ratio of 15:1, a catalyst (phosphoric acid) concentration of 9% wt and temperature of 50oC within 90 minutes. The reaction time was reduced to 3 times (minute) compare to conventional method and fatty acid reduced 42%. Kinetic parameters were calculated with assumption that the esterification was the irreversible reaction. The reaction rate constant increasing with temperature. The value of activation energy for esterification of WCO is 42.94 kJ/mol for first order reaction and 35.30 kJ/mol for second order reaction.

Synthesis and Characterization of Heterogeneous Solid Acid Catalyst from Alstonia Scolaris Stalks for Biodiesel Production using Waste Cooking Oil

2020 ◽  
Vol 10 ◽  
Author(s):  
Charishma Venkata Sai Anne ◽  
Karthikeyan S. ◽  
Arun C.
Keyword(s):  
Reaction Time ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Wood Biomass ◽  
Waste Wood ◽  
X Ray ◽  
Cooking Oil

Background: Waste biomass derived reusable heterogeneous acid based catalysts are more suitable to overcome the problems associated with homogeneous catalysts. The use of agricultural biomass as catalyst for transesterification process is more economical and it reduces the overall production cost of biodiesel. The identification of an appropriate suitable catalyst for effective transesterification will be a landmark in biofuel sector Objective: In the present investigation, waste wood biomass was used to prepare a low cost sulfonated solid acid catalyst for the production of biodiesel using waste cooking oil. Methods: The pretreated wood biomass was first calcined then sulfonated with H2SO4. The catalyst was characterized by various analyses such as, Fourier-transform infrared spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray Spectroscopy (EDS) and X-ray diffraction (XRD). The central composite design (CCD) based response surface methodology (RSM) was applied to study the influence of individual process variables such as temperature, catalyst load, methanol to oil molar ration and reaction time on biodiesel yield. Results: The obtained optimized conditions are as follows: temperature (165 ˚C), catalyst loading (1.625 wt%), methanol to oil molar ratio (15:1) and reaction time (143 min) with a maximum biodiesel yield of 95 %. The Gas chromatographymass spectrometry (GC-MS) analysis of biodiesel produced from waste cooking oil was showed that it has a mixture of both monounsaturated and saturated methyl esters. Conclusion: Thus the waste wood biomass derived heterogeneous catalyst for the transesterification process of waste cooking oil can be applied for sustainable biodiesel production by adding an additional value for the waste materials and also eliminating the disposable problem of waste oils.

scholarly journals Innovative applications of waste cooking oil as raw material

2019 ◽  
Vol 102 (2) ◽  
pp. 153-160 ◽  
Author(s):  
Alberto Mannu ◽  
Monica Ferro ◽  
Maria Enrica Di Pietro ◽  
Andrea Mele
Keyword(s):  
Hazardous Waste ◽  
Industrial Application ◽  
Waste Cooking Oil ◽  
Review Article ◽  
Raw Material ◽  
Cooking Oil ◽  
Waste Cooking Oils ◽  
Cooking Oils ◽  
Recycled Waste

The consideration towards waste cooking oils is changing from hazardous waste to valuable raw material for industrial application. During the last 5 years, some innovative processes based on the employment of recycled waste cooking oil have appeared in the literature. In this review article, the most recent and innovative applications of recycled waste cooking oil are reported and discussed. These include the production of bioplasticizers, the application of chemicals derived from waste cooking oils as energy vectors and the use of waste cooking oils as a solvent for pollutant agents.

scholarly journals The Utilization of Waste Cooking Oil (WCO) as A Mixture of Polyol Sourcein. The Production of Polyurethane Using Toluene Diisocyanate

2019 ◽  
Vol 35 (1) ◽  
pp. 221-227
Author(s):  
Maulida Lubis ◽  
Mara Bangun Harahap ◽  
Iriany Iriany ◽  
Muhammad Hendra S. Ginting ◽  
Iqbal Navissyah Lazuardi ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Impact Strength ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Toluene Diisocyanate ◽  
Elongation At Break ◽  
Cooking Oil ◽  
A Value ◽  
Stirring Time

Cooking oil waste that has been disposed could contamine the environment. However, if it is processed well, it can potentially become a raw material of polyurethane. The aim of this study was to determine the best polyurethane on the tensile strength, impact strength, elongation at break, water absorption, characterization of Fourier Transform Infra-Red (FTIR) and the characterization of Scanning Electron Microscopy (SEM). The variables used in this study were ambient process temperature with 440 rpm stirring speed, 1-minute stirring time, the ratio of polyoland WCO was 7:3 (% w/w), and the ratio of Toluene Diisocyanate (TDI) and WCO was 1:1; 1:2; 1:3; 1:4 (% w/w). The results obtained from the analysis of the best tensile strength against the polyurethane synthetic was in the 1:1 ratio of mixed variations between oil and TDI with a value of 0.403 MPa. The best impact strength was in the ratio of mixed variations between oil and TDI with 1:4 (% w/w) with a value of 600.975 J/m2. The best elongation at break against polyurethane foam synthetic was in the 1:3 ratio of mixture variations of oil and TDI with a value of 4.506%.

scholarly journals Optimization of Biodiesel Production from Waste Cooking Oil Using S–TiO2/SBA-15 Heterogeneous Acid Catalyst

Catalysts ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 67 ◽  
Author(s):  
Muhammad Hossain ◽  
Md Siddik Bhuyan ◽  
Abul Md Ashraful Alam ◽  
Yong Seo
Keyword(s):  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Catalyst Loading ◽  
Esterification Reaction ◽  
Impregnation Method ◽  
Cooking Oil ◽  
Heterogeneous Acid Catalyst

The aim of this research was to synthesize, characterize, and apply a heterogeneous acid catalyst to optimum biodiesel production from hydrolyzed waste cooking oil via an esterification reaction, to meet society’s future demands. The solid acid catalyst S–TiO2/SBA-15 was synthesized by a direct wet impregnation method. The prepared catalyst was evaluated using analytical techniques, X-ray diffraction (XRD), Scanning electron microscopy (SEM) and the Brunauer–Emmett–Teller (BET) method. The statistical analysis of variance (ANOVA) was studied to validate the experimental results. The catalytic effect on biodiesel production was examined by varying the parameters as follows: temperatures of 160 to 220 °C, 20–35 min reaction time, methanol-to-oil mole ratio between 5:1 and 20:1, and catalyst loading of 0.5%–1.25%. The maximum biodiesel yield was 94.96 ± 0.12% obtained under the optimum reaction conditions of 200 °C, 30 min, and 1:15 oil to methanol molar ratio with 1.0% catalyst loading. The catalyst was reused successfully three times with 90% efficiency without regeneration. The fuel properties of the produced biodiesel were found to be within the limits set by the specifications of the biodiesel standard. This solid acid catalytic method can replace the conventional homogeneous catalyzed transesterification of waste cooking oil for biodiesel production.

Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst

2020 ◽  
Vol 226 ◽  
pp. 113366
Author(s):  
Shatesh Kumar ◽  
Mohd Razali Shamsuddin ◽  
M.S Ahmad Farabi ◽  
Mohd Izham Saiman ◽  
Zulkarnain Zainal ◽  
...  
Keyword(s):  
Methyl Esters ◽  
Acid Catalyst ◽  
Waste Cooking Oil ◽  
Chicken Fat ◽  
Cooking Oil

scholarly journals Evolution of Waste Cooking Oil Collection in an Area with Long-Standing Waste Management Problems

2020 ◽  
Vol 12 (20) ◽  
pp. 8578
Author(s):  
Giovanni De Feo ◽  
Aurelio Di Domenico ◽  
Carmen Ferrara ◽  
Salvatore Abate ◽  
Libero Sesti Osseo
Keyword(s):  
Waste Management ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Economic Damage ◽  
Private Company ◽  
Campania Region ◽  
Awareness Campaigns ◽  
Cooking Oil ◽  
Management Problems ◽  
Collection Program

Waste cooking oil (WCO) can be a useful secondary raw material, if properly managed. On the contrary, uncontrolled disposal generates negative environmental impacts as well as economic loss. Therefore, improving WCO recovery rate, with the cooperation of citizens and effective collection programs, is fundamental. The aim of the study was to investigate the reason for the low recovery of WCO in those areas suffering serious waste management problems such as the Campania region in Southern Italy. For this purpose, the case of a WCO collection program adopted in Angri, a town of around 34,000 people with a high population density, was studied. In 2015, the collection program was managed by a social cooperative, while, in 2016, after the change of the local government, the collection of WCO was entrusted to a private company. In 2015, the households’ participation in the collection program was surveyed through a structured questionnaire. The results revealed that the collection of WCO was practiced by 53% of the respondents. Among those not collecting WCO, 76% of the sample wrongly disposed of WCO in their home (kitchen or toilet). Misinformation was the main reason why they did not adhere to the collection program. Therefore, it was suggested to support information and environmental education campaigns to promote environmental awareness of citizens. Unfortunately, the change of management, together with serious problems in the collection of municipal waste in the whole region, due to the continuous closures of the mechanical and biological plants, produced a sharp decline in the collection from 7730 kg in 2015 to an average of 3800 kg for the period 2016–2019, with a loss of more than 15,000 kg of WCO wrongly disposed with consequent environmental and economic damage. Therefore, information and awareness campaigns are important but the form of entrusting the collection service is equally important, especially in areas with long-standing waste management problems.

An Investigation into the Conversion of Propylene Glycol to 2,4-dimethyl-1,3-dioxolane over an Acid Catalyst Using Gas Chromatography

2013 ◽  
Vol 850-851 ◽  
pp. 82-85
Author(s):  
Zuo You Zhang ◽  
Hui Chen ◽  
Xia Li ◽  
Zhao Hui Yang ◽  
Bao Chen Liang
Keyword(s):  
Aqueous Solution ◽  
Reaction Rate ◽  
Acid Catalyst ◽  
Reaction Rate Constant ◽  
Order Reaction ◽  
Molar Ratio ◽  
Temperature Reaction ◽  
Gas Chromatograph ◽  
Second Order Reaction ◽  
Operational Parameters

In the presence of an acid catalyst, PG react reversibly with acetaldehyde to form 2,4-dim-ethyl-1,3-dioxolane (24DMD). The effects of different operational parameters on PG conversion had been analyzed in paper, parameters included temperature, reaction time, amount of catalyst and aqueous acetaldehyde/PG molar ratio. Under optimal condition, 85% conversion of PG in aqueous solution was achieved within 180 min of reaction. The analysis of PG was conducted by gas chromatograph. Furthermore, reaction followed the second-order reaction kinetics, and the reaction rate constant was found to be 29.68min-1.

scholarly journals KRITERIA RUMAH MAKAN SUPPLIER MINYAK JELANTAH DALAM RANGKA PERENCANAAN BAHAN BAKU BIODIESEL

2019 ◽  
Vol 1 (1) ◽  
pp. 27-33
Author(s):  
D.U.M. Susilo ◽  
Th. Candra Wasis A.S. ◽  
Zakwan .
Keyword(s):  
Raw Materials ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Biodiesel Production ◽  
Analytic Hierarchy ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
A Value ◽  
Many Sources ◽  
The City

The using of biodiesel as an environmentally friendly fuel has received attention from consumers to producers. So, a lot of research was done on the potential raw material to become biodiesel. One of the raw materials for biodiesel was waste cooking oil. Pontianak City have many sources including waste cooking oil from restaurants. Therefore restaurants in the city of Pontianak might be used as suppliers of waste cooking oil in biodiesel production. This study aims to determine the priority of criteria and sub-criteria for restaurants as suppliers and determine good restaurants as suppliers of used cooking in Pontianak City . Purposive technique sampling using a sample of 61 house dining, interviewed to obtain alternative data suppliers. Expert survey questionnaire contains priority weighting of criteria and supplier criteria, analyzed using AHP ( Analytic Hierarchy Process ). Grouping of restaurants based on alternative supplier values ​​is used to determine good restaurants to be suppliers. The priority criteria for restaurants as consecutive suppliers are experience (0.289), quality (0.279), capacity (0.231), service (0.148) and price (0.053). Sub-criteria priority of restaurants as suppliers in a row is the time span of used cooking oil sold(0.161), length of time used cooking oil (0.155), income (0.129), type of cooking oil (0.107), type of fried food products (0.092), volume of cooking oil (0.090), frying volume (0.085), transaction convenience (0.082), subject to used cooking oil (0.056), used cooking oil price (0.030) and ease of payment (0.013). A value of ≥ 0.325 is a dining value that shows a very better priority as a supplier. The number of restaurants as suppliers is 8 % of the population of restaurants in the city of Pontianak..

scholarly journals PENGARUH MASSA KATALIS DAN WAKTU REAKSI PADA PEMBUATAN BIODIESEL DARI LIMBAH MINYAK JELANTAH DENGAN MENGGUNAKAN KATALIS HETEROGEN K2O DARI LIMBAH KULIT KAKAO

2017 ◽  
Vol 6 (2) ◽  
pp. 24-29
Author(s):  
Jefry R Turnip ◽  
Trio F. L. Tarigan ◽  
Mersi Suriani Sinaga
Keyword(s):  
Reaction Time ◽  
Corn Oil ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
National Standard ◽  
Solid Catalyst ◽  
Waste Oil ◽  
Cooking Oil ◽  
High Level ◽  
Cooking Oils

Waste cooking oil is a waste oil that comes from many types of cooking oils such as corn oil, vegetable oil, ect. The purpose of this research is to waste cooking oil as a raw material to form biodiesel with K2O as the solid catalyst from cocoa pod ash (CPA) which is calcined on temperature 650 oC within 4 hours. This oil contains a high level of Free Fatty Acid (FFA) that is 3.13%. Therefore, pretreatment should be done by using activated carbon (1% w/w) to reduce levels of FFA. The research will be observed the effect of reaction time and the mass of catalyst. The characteristics of biodiesel is analyzed according to the levels of methyl ester in biodiesel, density, and viscosity based on the Indonesian National Standard (SNI). The best conditions of biodiesel are obtained with the amount of catalyst is 6% (w/w) that is calcined at 650 °C, reaction time 180 minutes, ratio mol of alcohol : oil is 12: 1, and 65 oC reaction of temperature, resulting the purity and yield of biodiesel is 99,8% and 92,68%. The results of this research indicates that the use of waste cooking as a raw material is suitable in the manufacture of biodiesel.

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