Sustainable Materials Production for Oily Wastewater Treatment

The discharge of water from oil fields It has become one of the most significant environmental concerns associated with the oil sector. Hydrocarbon spills and crude oil fuel spills are a continual hazard to aquatic ecosystems. Inexpensive and sustainable sorbent materials are needed to mitigate the environmental damage of this pollution. To meet this need, this study features a low-density polysulfide polymer prepared by Sulfur and used cooking oils react directly. Since both sulfur and cooking oils are hydrophobic, the polymer is close to hydrocarbons such as crude oil and diesel fuel and can easily remove them from seawater. Oil can be recovered and polymer can be reused in oil spill treatment. Polysulfide is unique in that it is prepared from completely recycled waste. Sulfur is a by-product of the petroleum industry, and used cooking oil can also be used as a raw material. Therefore, waste sulfur from the petroleum industry is used to make effective anti-pollution adsorbents from the same sector According to the study’s findings, 98.55 percent of the oil was removed from the north.

Ethanolysis of Waste Cooking oils using KOH Catalyst

The transesterification of waste cooking oils (WCO) with ethanol was investigated by means of potassium hydroxide (KOH) as catalyst. This work aimed to study the influences of catalyst concentration, temperature, ethanol to WCO molar ratio, reaction time, and stirring rate on the biodiesel conversion. Gas chromatography (GC) was used during the process of transesterification to determine the evolution of ethyl esters concentration with time. Biodiesel with maximum yield was obtained (92.5%) when 2 wt% KOH, temperature of 75°C, and ethanol/oil molar ratio of 11:1 were utilized.

Metal Rod Surfaces after Exposure to Used Cooking Oils

Used cooking oils (UCOs) have a high potential as renewable fuels for the maritime shipping industry. However, their corrosiveness during storage and usage are some of the concerns yet to be investigated for addressing compatibility issues. Thus, the corrosion of steels and copper exposed to the UCOs was studied through the immersion of metal rods for different periods. The changes on the rod surfaces were analyzed with a scanning electron microscope (SEM). After the immersion, the copper concentration dissolved in the bio-oils was measured using inductively coupled plasma-optical emission spectrometry (ICP-OES). The free fatty acids and glycerides were analyzed using gas chromatography with flame ionization detection (GC-FID). The acid number (AN), water concentration, as well as density and kinematic viscosity of the bio-oils were determined with standard methods. The UCOs with the highest water content were corrosive, while the oils with lower water concentrations but higher ANs induced lower corrosion. After mixing two different UCOs, the metal corrosion decreased with an increasing concentration of the oil with lower corrosive properties. The lower corrosion properties were most likely due to the monounsaturated fatty acids, e.g., oleic acid in oils. These acids formed a barrier layer on the rod surfaces, thereby inhibiting the permeation of oxygen and water to the surface. Even adding 0.025 wt% of tert-butylamine decreased the corrosivity of UCO against polished steel rod. The results suggested that mixing several oil batches and adding a suitable inhibitor reduces the potential corrosive properties of UCOs.

Turning Waste Cooking Oils into Biofuels—Valorization Technologies: A Review

In search of a more sustainable society, humanity has been looking to reduce the environmental impacts caused by its various activities. The energy sector corresponds to one of the most impactful activities since most energies produced come from fossil fuels, such as oil and coal, which are finite resources. Moreover, their inherent processes to convert energy into electricity emit various pollutants, which are responsible for global warming, eutrophication, and acidification of soil and marine environments. Biofuels are one of the alternatives to fossil fuels, and the raw material used for their production includes vegetable oils, wood and agricultural waste, municipal waste, and waste cooking oils (WCOs). The conventional route for WCO valorization is the production of biodiesel, which, as all recovery technologies, presents advantages and disadvantages that must be explored from a technical and economic perspective. Despite its successful use in the production of biodiesel, it should be noticed that there are other approaches to use WCO. Among them, thermochemical technologies can be applied to produce alternative fuels through cracking or hydrocracking, pyrolysis, and gasification processes. For each technology, the best conditions were identified, and finally, projects and companies that work with this type of technology and use WCO were identified.

Effects of Repeated Frying on Physical Properties of Cooking Oil obtained from Local Markets in Makurdi Metropolis, Benue State, Nigeria.

The viscosity, density and specific gravity of different brands of cooking oil samples locally sourced for in Makurdi have been measured with respect to change in temperature. The viscosity of the different brands of cooking oil was measured with the instrumentality of Brookfield Viscometer. The density and specific gravity were evaluated using the mass of the sampled oil obtained with the help of the density bottle. The result showed a pattern of rapid decrease in viscosity with increase in temperature for the oil samples, while density decrease is observed to be almost linear with increase in temperature for all samples. Amongst the sampled cooking oils, palm kernel showed the least viscosity of 8.6 Pascal-second when measured at 45.200C. This illustrates that palm kernel oil has a relatively low viscous nature at 45.200C as compared to other samples used in this work but cannot be recommended to be used as lubricants in vehicles in place of gasoline because they have very low viscous nature within temperatures far less than 100 0C.

Catalytic Conversion of Glycerol into Hydrogen and Value-Added Chemicals: Recent Research Advances

In recent decades, the use of biomass as alternative resources to produce renewable and sustainable biofuels such as biodiesel has gained attention given the situation of the progressive exhaustion of easily accessible fossil fuels, increasing environmental concerns, and a dramatically growing global population. The conventional transesterification of edible, nonedible, or waste cooking oils to produce biodiesel is always accompanied by the formation of glycerol as the by-product. Undeniably, it is essential to economically use this by-product to produce a range of valuable fuels and chemicals to ensure the sustainability of the transesterification process. Therefore, recently, glycerol has been used as a feedstock for the production of value-added H2 and chemicals. In this review, the recent advances in the catalytic conversion of glycerol to H2 and high-value chemicals are thoroughly discussed. Specifically, the activity, stability, and recyclability of the catalysts used in the steam reforming of glycerol for H2 production are covered. In addition, the behavior and performance of heterogeneous catalysts in terms of the roles of active metal and support toward the formation of acrolein, lactic acid, 1,3-propanediol, and 1,2-propanediol from glycerol are reviewed. Recommendations for future research and main conclusions are provided. Overall, this review offers guidance and directions for the sufficient and economical utilization of glycerol to generate fuels and high value chemicals, which will ultimately benefit industry, environment, and economy.