scholarly journals Morphological and FTIR Studies of Barium Oxalate Single Crystals

2017 ◽  
Vol 25 (2) ◽  
pp. 195-207
Author(s):  
M. R. Shedam ◽  
Rakesh M. Shedam ◽  
Shridhar N. Mathad
Keyword(s):  
Single Crystals ◽  
Feed Solution ◽  
Silica Gels ◽  
Effect Of Temperature ◽  
Nucleation Density ◽  
Gel Growth ◽  
Ftir Studies ◽  
Barium Oxalate ◽  
Oxalate Crystals ◽  
Higher Temperature

Abstract The conditions for the gel growth of barium oxalate single crystals in silica gels were studied in this paper. We describe the growth mechanism, effect concentration of feed solution, interchanging of the reactants, the effect of temperature and detailed study of microstructures of barium oxalate single crystals. At higher concentration of feed solution dense fibers were observed. With interchanged feed solution precipitate and spherulites have been obtained. The effect of temperature on growth barium oxalate crystals showed that there was a decrease in nucleation density at higher temperature. The crystals growth were observed under the electron microscope which revealed that the crystal have needle and spherulites structures. We also report the FTIR studies of barium oxalate crystals.

Nucleation of Disorder in Fe3Al Alloys

1967 ◽  
Vol 25 ◽  
pp. 312-313
Author(s):  
P. R. Swann ◽  
W. R. Duff ◽  
R. M. Fisher
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Annealing Temperature ◽  
Antiphase Domain ◽  
Effect Of Temperature ◽  
Domain Structures ◽  
Transmission Electron ◽  
Domain Boundaries ◽  
Higher Temperature ◽  
The One

Recently we have investigated the phase equilibria and antiphase domain structures of Fe-Al alloys containing from 18 to 50 at.% Al by transmission electron microscopy and Mössbauer techniques. This study has revealed that none of the published phase diagrams are correct, although the one proposed by Rimlinger agrees most closely with our results to be published separately. In this paper observations by transmission electron microscopy relating to the nucleation of disorder in Fe-24% Al will be described. Figure 1 shows the structure after heating this alloy to 776.6°C and quenching. The white areas are B2 micro-domains corresponding to regions of disorder which form at the annealing temperature and re-order during the quench. By examining specimens heated in a temperature gradient of 2°C/cm it is possible to determine the effect of temperature on the disordering reaction very precisely. It was found that disorder begins at existing antiphase domain boundaries but that at a slightly higher temperature (1°C) it also occurs by homogeneous nucleation within the domains. A small (∼ .01°C) further increase in temperature caused these micro-domains to completely fill the specimen.

Effect of Temperature on Column Bioleaching of a Refractory Gold Ore

2013 ◽  
Vol 825 ◽  
pp. 352-355 ◽  
Author(s):  
Zeng Ling Wu ◽  
Zhong Sheng Huang ◽  
Ren Man Ruan ◽  
Shui Ping Zhong ◽  
Brenda K.C. Chan
Keyword(s):  
Sulfide Oxidation ◽  
Effect Of Temperature ◽  
Low Grade ◽  
Key Factors ◽  
Gold Extraction ◽  
Gold Ores ◽  
Fraction Distribution ◽  
Higher Temperature ◽  
Liberation Analysis ◽  
Main Factor

Low-grade, finely disseminated refractory sulfide gold ores associated with high arsenic are ubiquitous resources all over the world. Since heap bio-oxidation is an economic and promising biotechnology to recover gold, low grade, high organic carbon and arsenic bearing gold ores from Zhesang Mines in China were chosen for this purpose to study the key factors that would affect biooxidation. Pyrite and arsenopyrite (particle size 0.002-0.22 mm) were the main minerals from Mineral Liberation Analysis (MLA). Column biooxidation and cyanidation of mineral size < 10 mm were evaluated for its potential for gold extraction. Results showed that temperature was the main factor influencing sulfide oxidation. 58-67 % of sulfide was oxidized at 35-45°C after > 240 days of biooxidation with mixed mesophiles, while higher sulfide-S dissolution (77%) was obtained at 60°C. Sulfide-S fraction distribution revealed higher mineral decomposition, finer fractions and eventually higher sulfide oxidation at 60°C. Jarosite and scorodite were found from the residues at 60°C by SEM and EDX, which implies higher temperature accelerated arsenic precipitation. No elemental sulfur was detected during the biooxidation at 35-60°C. After bio-oxidation, column cyanidation was successfully demonstrated recovery of gold from the residues, with gold extraction rate reaching 66%.

The Mechanical Characteristics and Sealing Performance Evaluation of Bolted Pipe Flange Connections With Metallic Flat Gaskets Subjected to Internal Pressure

2016 ◽  
Author(s):  
Koji Kondo ◽  
Koji Sato ◽  
Satomi Takahashi ◽  
Toshiyuki Sawa
Keyword(s):  
Plastic Deformation ◽  
Mechanical Characteristics ◽  
Experimental Results ◽  
Leak Rate ◽  
Effect Of Temperature ◽  
Load Factor ◽  
Stress Distributions ◽  
Bolt Preload ◽  
Sealing Performance ◽  
Higher Temperature

Bolted pipe flange connections with metallic gaskets have been used under higher pressure as well as higher temperature. However, a few researches on the mechanical characteristics in connections with metallic gaskets have been carried out. It is necessary to examine the mechanical characteristics such as the contact gasket stress distributions which govern the sealing performance, the deformation of the metallic gaskets, changes in axial bolt forces and the hub stress under higher pressure and temperature. In the present paper, the objectives are to examine the changes in axial bolt forces, the hub stress and the contact gasket stress distributions and the sealing performance of the pipe flange connections with metallic flat gaskets. Firstly, the mechanical characteristics of the connections under higher pressure are analyzed using FEA. Then, experiments were carried out to measure the load factor, the hub stress and the leak rate (the sealing performance). The relationship between the average contact gasket stress and the leak rate was measured using platen device at room temperature. The FEA results are fairly coincided with the experimental results. It is shown that the leak rate decreases as the contact gasket stress increases and when the plastic deformation of gaskets occurs, the sealing performance increases. The leak rate was measured in the range of 10−4∼10−7 [Pa·m3/s]. It is found that the sealing performance increases as the gasket width increase in the elastic deformation range while it is independent of the gasket width when the plastic deformation occurs. The effect of temperature on the mechanical characteristics of the connection is also examined. The FEA results are in a fairly good agreement with the experimental results. It is found that the sealing performance increases as the temperature increases. In addition, a method how to determine the bolt preload for increasing the sealing performance is proposed.

RBS/Channeling Diffusion Studies of High Energy Au Implanted Mg Single Crystals

1991 ◽  
Vol 235 ◽  
Author(s):  
R. C. Da Selva ◽  
M. F. Da Silva ◽  
L. Thomé ◽  
A. A. Melo ◽  
J. C. Soares
Keyword(s):  
Single Crystals ◽  
Temperature Regime ◽  
High Energy ◽  
Back Diffusion ◽  
Thermally Activated ◽  
Diffusion Studies ◽  
Higher Temperature ◽  
Diffusion Behaviour ◽  
Thermally Activated Process

ABSTRACTRBS/channeling analyses of high energy Au implantation into Mg are presented. The diffusion behaviour of Au was studied and the occurrence of essentially two distinct regimes were observed: the segregation regime at lower temperatures correlated with the damage introduced by the high energy implantation and the higher temperature regime as a normal thermally activated process of back-diffusion.

Behaviour of Implanted Hydrogen in Gallium Phosphide Single Crystals

1988 ◽  
Vol 144 ◽  
Author(s):  
J. M. Zavada ◽  
R. G. Wilson ◽  
S. W. Novak ◽  
S. J. Pearton ◽  
A. R. Von Neida
Keyword(s):  
Mass Spectrometry ◽  
Single Crystals ◽  
Diffusion Coefficients ◽  
Gallium Phosphide ◽  
Secondary Ion Mass Spectrometry ◽  
Furnace Annealing ◽  
Higher Temperature ◽  
Redistribution Of Hydrogen ◽  
Secondary Ion ◽  
Post Implantation

ABSTRACTIn this paper we report on the depth distributions of implanted hydrogen in GaP crystals and the subsequent changes produced by post- implantation furnace annealing. A sulfur doped n+ GaP wafer has been implanted with 333 keV protons to a fluence of 5E15/cm+2. A similar wafer was implanted with 350 keV deuterons to the same fluence. Portions of each wafer have been furnace annealed at temperatures up to 500°C. The implanted hydrogen and the dopant S atoms were then depth profiled using secondary ion mass spectrometry (SIMS). The measurements show that the redistribution of hydrogen begins with annealing at about 300°C and proceeds both towards the surface and deeper into the substrate. The overall behavior is similar to that found previously for hydrogen in GaAs. However, in GaP crystals this redistribution begins at a higher temperature and proceeds more slowly in the implanted region. Based on the SIMS profiles, diffusion coefficients for hydrogen migrating into substrate are obtained.

scholarly journals Effect of High Temperature on the Electrochemical and Optical Properties of Emeraldine Salt Doped with DBSA and Sulfuric Acid

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Salma Gul ◽  
Anwar-ul-Haq Ali Shah ◽  
Salma Bilal
Keyword(s):  
Thermal Stability ◽  
Cyclic Voltammetry ◽  
Sulfuric Acid ◽  
Effect Of Temperature ◽  
Visible Spectroscopy ◽  
Emeraldine Salt ◽  
Higher Temperature ◽  
Stability Effect ◽  
Thermal Stability Of ◽  
Comprehensive Study

A comprehensive study of thermally treated polyaniline in its emeraldine salt form is presented here. It offers an understanding of the thermal stability of the polymer. Emeraldine salt was prepared by a novel emulsion polymerization pathway using dodecylbenzene sulfonic acid and sulfuric acid together as dopants. The effect of temperature and heating rate on the degradation of this emeraldine salt was studied via thermogravimetric analysis. The thermally analyzed sample was collected at various temperatures, that is, 250, 490, 500, and 1000°C. The gradual changes in the structure of the emeraldine salt were followed through cyclic voltammetry, Fourier transform infrared spectroscopy, and ultraviolet-visible spectroscopy. Results demonstrate that emeraldine salt shows high thermal stability up to 500°C. This is much higher working temperature for the use of emeraldine salt in higher temperature applications. Further heat treatment seems to induce deprotonation in emeraldine salt. Cyclic voltammetry and ultraviolet-visible spectroscopy revealed that complete deprotonation takes place at 1000°C where it loses its electrical conductivity. It is interesting to note that after the elimination of the dopants, the basic backbone of emeraldine salt was not destroyed. The results reveal that the dopants employed have a stability effect on the skeleton of emeraldine salt.

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