Effect of Temperature on Column Bioleaching of a Refractory Gold Ore

2013 ◽  
Vol 825 ◽  
pp. 352-355 ◽  
Author(s):  
Zeng Ling Wu ◽  
Zhong Sheng Huang ◽  
Ren Man Ruan ◽  
Shui Ping Zhong ◽  
Brenda K.C. Chan
Keyword(s):  
Sulfide Oxidation ◽  
Effect Of Temperature ◽  
Low Grade ◽  
Key Factors ◽  
Gold Extraction ◽  
Gold Ores ◽  
Fraction Distribution ◽  
Higher Temperature ◽  
Liberation Analysis ◽  
Main Factor

Low-grade, finely disseminated refractory sulfide gold ores associated with high arsenic are ubiquitous resources all over the world. Since heap bio-oxidation is an economic and promising biotechnology to recover gold, low grade, high organic carbon and arsenic bearing gold ores from Zhesang Mines in China were chosen for this purpose to study the key factors that would affect biooxidation. Pyrite and arsenopyrite (particle size 0.002-0.22 mm) were the main minerals from Mineral Liberation Analysis (MLA). Column biooxidation and cyanidation of mineral size < 10 mm were evaluated for its potential for gold extraction. Results showed that temperature was the main factor influencing sulfide oxidation. 58-67 % of sulfide was oxidized at 35-45°C after > 240 days of biooxidation with mixed mesophiles, while higher sulfide-S dissolution (77%) was obtained at 60°C. Sulfide-S fraction distribution revealed higher mineral decomposition, finer fractions and eventually higher sulfide oxidation at 60°C. Jarosite and scorodite were found from the residues at 60°C by SEM and EDX, which implies higher temperature accelerated arsenic precipitation. No elemental sulfur was detected during the biooxidation at 35-60°C. After bio-oxidation, column cyanidation was successfully demonstrated recovery of gold from the residues, with gold extraction rate reaching 66%.

scholarly journals Designing of engineering solutions to enhance efficiency of high-copper gold-bearing ore processing

2021 ◽  
pp. 51-56
Author(s):  
M.V. Zalesov ◽  
V.A. Grigoreva ◽  
V.S. Trubilov ◽  
A.Ya. Boduen
Keyword(s):  
Alkali Metals ◽  
Raw Materials ◽  
Low Grade ◽  
Gold Extraction ◽  
Gold Ores ◽  
Gold Mines ◽  
Maximum Permissible Concentrations ◽  
Copper Gold ◽  
Enhance Efficiency ◽  
Flotation Concentration

The modern metals industry is characterised by a downward trend in the quality of ores involved in processing, and conventional methods of extracting useful components are inefficient for raw materials with complex composition. To maintain the growing level of metal production it is required to introduce new efficient technologies for processing of low-grade and refractory ores as well as man-made deposits. The article describes processing methods of refractory raw materials with high cyanide content using copper-gold ores as an example, where gold is the primary commodity, and copper is the accompanying useful component. The most common method of processing copper-gold ores is preconcentration followed by selective leaching of copper and gold. In some cases, technologies involving copper by-products and cyanide recovery from the cyanide leaching solutions offer equally effective options for processing of the copper-gold ores and concentrates. Copper-gold ores are processed at gold mines using the cyanide procedures, supplemented if required by gravity and flotation concentration. In all variations of the cyanide treatment, most of copper minerals actively react with cyanides of alkali metals, binding the CN– ions into the copper complex of [Cu(CN3)]2–. This reaction results in an increased solvent consumption, as well as in number of challenges related to cleaning tailings and slurries from highly toxic cyanide compounds and dissolved copper. In addition to technological complications associated with the need to meet strict requirements for the maximum permissible concentrations, copper accumulated in the cycling solutions also causes a decrease in gold extraction from the processed ores.

Nucleation of Disorder in Fe3Al Alloys

1967 ◽  
Vol 25 ◽  
pp. 312-313
Author(s):  
P. R. Swann ◽  
W. R. Duff ◽  
R. M. Fisher
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Annealing Temperature ◽  
Antiphase Domain ◽  
Effect Of Temperature ◽  
Domain Structures ◽  
Transmission Electron ◽  
Domain Boundaries ◽  
Higher Temperature ◽  
The One

Recently we have investigated the phase equilibria and antiphase domain structures of Fe-Al alloys containing from 18 to 50 at.% Al by transmission electron microscopy and Mössbauer techniques. This study has revealed that none of the published phase diagrams are correct, although the one proposed by Rimlinger agrees most closely with our results to be published separately. In this paper observations by transmission electron microscopy relating to the nucleation of disorder in Fe-24% Al will be described. Figure 1 shows the structure after heating this alloy to 776.6°C and quenching. The white areas are B2 micro-domains corresponding to regions of disorder which form at the annealing temperature and re-order during the quench. By examining specimens heated in a temperature gradient of 2°C/cm it is possible to determine the effect of temperature on the disordering reaction very precisely. It was found that disorder begins at existing antiphase domain boundaries but that at a slightly higher temperature (1°C) it also occurs by homogeneous nucleation within the domains. A small (∼ .01°C) further increase in temperature caused these micro-domains to completely fill the specimen.

scholarly journals Spatio-Temporal Variation Characteristics of Snow Depth and Snow Cover Days over the Tibetan Plateau

Water ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 307
Author(s):  
Chi Zhang ◽  
Naixia Mou ◽  
Jiqiang Niu ◽  
Lingxian Zhang ◽  
Feng Liu
Keyword(s):  
Tibetan Plateau ◽  
Snow Cover ◽  
Snow Depth ◽  
Feedback Effect ◽  
Effect Of Temperature ◽  
The Tibetan Plateau ◽  
Reanalysis Dataset ◽  
Spatio Temporal ◽  
The Impact ◽  
Main Factor

Changes in snow cover over the Tibetan Plateau (TP) have a significant impact on agriculture, hydrology, and ecological environment of surrounding areas. This study investigates the spatio-temporal pattern of snow depth (SD) and snow cover days (SCD), as well as the impact of temperature and precipitation on snow cover over TP from 1979 to 2018 by using the ERA5 reanalysis dataset, and uses the Mann–Kendall test for significance. The results indicate that (1) the average annual SD and SCD in the southern and western edge areas of TP are relatively high, reaching 10 cm and 120 d or more, respectively. (2) In the past 40 years, SD (s = 0.04 cm decade−1, p = 0.81) and SCD (s = −2.3 d decade−1, p = 0.10) over TP did not change significantly. (3) The positive feedback effect of precipitation is the main factor affecting SD, while the negative feedback effect of temperature is the main factor affecting SCD. This study improves the understanding of snow cover change and is conducive to the further study of climate change on TP.

Study of Low-Grade Nickel Laterite Processing Using Palm Shell Charcoal as Reductant

2020 ◽  
Vol 1000 ◽  
pp. 436-446
Author(s):  
Bambang Suharno ◽  
Nolzha Primadha Ilman ◽  
Achmad Shofi ◽  
Deni Ferdian ◽  
Fajar Nurjaman
Keyword(s):  
Sodium Sulfate ◽  
Selective Reduction ◽  
Reduction Process ◽  
Low Grade ◽  
X Ray Diffraction ◽  
X Ray ◽  
Palm Shell ◽  
Higher Temperature ◽  
Nickel Grade

This study was conducted to investigate the effect of palm shell charcoal reductant in the selective reduction of nickel ore with the addition of additive at various temperatures and times. In this present work, 10 wt. % of sodium sulfate as additive and 5, 10, 15 wt. % of palm shell charcoal as reductants were used. The reduction of nickel ore was performed at 950oC, 1050oC, and 1150oC for 60, 90, and 120 minutes. A wet magnetic separation method was then carried out to separate the concentrates and tailings. Characterization of reduced ore was performed by X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM) with Energy Dispersive X-ray Spectroscopy (EDS), while the composition of ferronickel in concentrate was identified by X-Ray Fluorescence (XRF). The result showed that the higher temperature reduction, the higher of nickel grade, and its recovery at the concentrate. Nevertheless, the longer reduction time and the more reductant in nickel ore lowering the nickel grade and its recovery in the concentrate. The optimum condition in this selective reduction process was obtained with the addition of 5 wt. % of reductant and 10 wt. % of sodium sulfate in nickel ore, which was reduced at 1150oC for 60 minutes. It resulted in 4.60% and 73.23% for nickel grade and its recovery, respectively.

The Mechanical Characteristics and Sealing Performance Evaluation of Bolted Pipe Flange Connections With Metallic Flat Gaskets Subjected to Internal Pressure

2016 ◽  
Author(s):  
Koji Kondo ◽  
Koji Sato ◽  
Satomi Takahashi ◽  
Toshiyuki Sawa
Keyword(s):  
Plastic Deformation ◽  
Mechanical Characteristics ◽  
Experimental Results ◽  
Leak Rate ◽  
Effect Of Temperature ◽  
Load Factor ◽  
Stress Distributions ◽  
Bolt Preload ◽  
Sealing Performance ◽  
Higher Temperature

Bolted pipe flange connections with metallic gaskets have been used under higher pressure as well as higher temperature. However, a few researches on the mechanical characteristics in connections with metallic gaskets have been carried out. It is necessary to examine the mechanical characteristics such as the contact gasket stress distributions which govern the sealing performance, the deformation of the metallic gaskets, changes in axial bolt forces and the hub stress under higher pressure and temperature. In the present paper, the objectives are to examine the changes in axial bolt forces, the hub stress and the contact gasket stress distributions and the sealing performance of the pipe flange connections with metallic flat gaskets. Firstly, the mechanical characteristics of the connections under higher pressure are analyzed using FEA. Then, experiments were carried out to measure the load factor, the hub stress and the leak rate (the sealing performance). The relationship between the average contact gasket stress and the leak rate was measured using platen device at room temperature. The FEA results are fairly coincided with the experimental results. It is shown that the leak rate decreases as the contact gasket stress increases and when the plastic deformation of gaskets occurs, the sealing performance increases. The leak rate was measured in the range of 10−4∼10−7 [Pa·m3/s]. It is found that the sealing performance increases as the gasket width increase in the elastic deformation range while it is independent of the gasket width when the plastic deformation occurs. The effect of temperature on the mechanical characteristics of the connection is also examined. The FEA results are in a fairly good agreement with the experimental results. It is found that the sealing performance increases as the temperature increases. In addition, a method how to determine the bolt preload for increasing the sealing performance is proposed.

scholarly journals Effect of temperature on bamboo oxidant-processing

2015 ◽  
Vol 19 (4) ◽  
pp. 1361-1364
Author(s):  
Jia-Jia Fu ◽  
Xiao-Ying Du ◽  
Jing-Wei Ma ◽  
Zheng-Fan Li ◽  
Chong-Wen Yu
Keyword(s):  
Effect Of Temperature ◽  
Main Factor

Oxidant-processing was applied to treat bamboo to remove bamboo?s lignin. Various oxidants were adopted to investigate the possibility of oxidizing bamboo lignin. The paper concluded that temperature is the main factor of oxidant performance.

scholarly journals Effect of High Temperature on the Electrochemical and Optical Properties of Emeraldine Salt Doped with DBSA and Sulfuric Acid

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Salma Gul ◽  
Anwar-ul-Haq Ali Shah ◽  
Salma Bilal
Keyword(s):  
Thermal Stability ◽  
Cyclic Voltammetry ◽  
Sulfuric Acid ◽  
Effect Of Temperature ◽  
Visible Spectroscopy ◽  
Emeraldine Salt ◽  
Higher Temperature ◽  
Stability Effect ◽  
Thermal Stability Of ◽  
Comprehensive Study

A comprehensive study of thermally treated polyaniline in its emeraldine salt form is presented here. It offers an understanding of the thermal stability of the polymer. Emeraldine salt was prepared by a novel emulsion polymerization pathway using dodecylbenzene sulfonic acid and sulfuric acid together as dopants. The effect of temperature and heating rate on the degradation of this emeraldine salt was studied via thermogravimetric analysis. The thermally analyzed sample was collected at various temperatures, that is, 250, 490, 500, and 1000°C. The gradual changes in the structure of the emeraldine salt were followed through cyclic voltammetry, Fourier transform infrared spectroscopy, and ultraviolet-visible spectroscopy. Results demonstrate that emeraldine salt shows high thermal stability up to 500°C. This is much higher working temperature for the use of emeraldine salt in higher temperature applications. Further heat treatment seems to induce deprotonation in emeraldine salt. Cyclic voltammetry and ultraviolet-visible spectroscopy revealed that complete deprotonation takes place at 1000°C where it loses its electrical conductivity. It is interesting to note that after the elimination of the dopants, the basic backbone of emeraldine salt was not destroyed. The results reveal that the dopants employed have a stability effect on the skeleton of emeraldine salt.

Effect of Temperature on Tool Wear During Milling of Ti64

2021 ◽  
Vol 143 (7) ◽  
Author(s):  
Q. Lagarde ◽  
V. Wagner ◽  
G. Dessein ◽  
M. Harzallah
Keyword(s):  
Tool Wear ◽  
Cutting Temperature ◽  
Cutting Speed ◽  
Effect Of Temperature ◽  
Fundamental Parameter ◽  
Ir Camera ◽  
Radial Depth ◽  
Higher Temperature ◽  
Two Parameters ◽  
Machining Productivity

Abstract In recent years, the development of new, increasingly resistant materials limit machining productivity. This observation is especially true for titanium alloys. The state-of-the-art shows that one of the phenomena responsible for tool wear is temperature. The high temperature is explained by the low thermal conductivity of the alloy and its high mechanical properties. Consequently, high temperatures generated when cutting speeds are increasing lead to very rapid wear phenomena. However in milling, the period during which the insert is not in contact with the material may allow it to cool but its effect is not clearly established. In order to correlate tool wear and cutting temperatures in milling, an experimental bench has been developed. In turning and therefore with a fixed tool, the milling conditions are recreated and allow to measure the temperatures on the cutting face. Two parameters were tested: (i) radial depth, which influences the tooth stress time, and (ii) the cutting speed, which is the fundamental parameter of the cutting temperature. Experimentally, it appears that increasing radial engagement and cutting speed reduces tool life and increases temperatures. However, the phenomenological analysis is not immediate. The relationship between these phenomena is based on a heat balance of the cutting process. The use of an infrared (IR) camera in this problem and a specific analysis method allow observing the temperature gradients on the cutting face making the analysis more robust compared to the thermocouple technic. It thus appears that the increase in radial engagement leads to a higher tool temperature, but the analyses show above all a higher temperature within the insert and therefore more difficult to evacuate.

Copper Recovery by Bioleaching of Chalcopyrite: A Microcalorimetric Approach for the Fast Determination of Bioleaching Activity

2013 ◽  
Vol 825 ◽  
pp. 322-325
Author(s):  
Beate Krok ◽  
Axel Schippers ◽  
Wolfgang Sand
Keyword(s):  
Enrichment Culture ◽  
Sulfide Oxidation ◽  
Exothermic Reaction ◽  
Metal Sulfide ◽  
Copper Recovery ◽  
Heat Output ◽  
Low Grade ◽  
Non Invasive ◽  
Pure Cultures ◽  
Invasive Method

Low grade copper ores containing chalcopyrite are increasingly used for copper recovery via biomining. Since metal sulfide oxidation is an exothememic process, bioleaching activity can be measured due to the heat output by microcalorimetry, which is a non-destructive and non-invasive method. The bioleaching activity of pure cultures ofSulfolobus metallicus,Metallosphaera hakonensisand a moderate thermophilic enrichment culture on high grade chalcopyrite was evaluated. Chalcopyrite leaching by microorganisms showed a higher copper recovery than sterile controls. Chemical chalcopyrite leaching by acid produced heat due to the exothermic reaction, the heat output was increased while metal sulfide oxidation by microorganisms.

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