scholarly journals Application of numerical modelling to scaling-up of electrically induced extraction from an organic mixture using an ionic liquid

2016 ◽  
Vol 37 (1) ◽  
pp. 133-148 ◽  
Author(s):  
Kamil Kamiński ◽  
Laurence R. Weatherley ◽  
Jerzy Petera
Keyword(s):  
Ionic Liquid ◽  
Numerical Modelling ◽  
Azeotropic Distillation ◽  
Environmentally Friendly ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Simulation Software ◽  
Operating Conditions ◽  
Organic Mixture ◽  
Liquid Liquid Extraction

Abstract Liquid-liquid extraction provides an environmentally friendly process as an alternative to azeotropic distillation, pervaporation and reverse osmosis because these techniques require the use of large amounts of energy, may involve volatile organic compounds, and operation at high pressure. Ionic liquids (ILs) continue to gain wide recognition as potential environmentally friendly solvents due to their unique properties. However due to their current high cost, their use in industry is seriously limited without an efficient methodology for recovery and recycle. In this paper we describe an innovative methodology for a liquid-liquid extraction process based on an electrically induced emulsion of an ionic liquid as the extracting solvent dispersed in an organic mixture. This offers a most efficient exploitation of the solvent. On the other hand we present our own design of a pilot (semi-industrial) scale extractor based on this methodology and which demonstrates effective recovery of the ionic liquid. In order to achieve this goal we used a numerical modelling tool implemented using our own simulation software based on the finite element method. We also used our original previous experience with generating and investigating liquid-liquid electrosprays using phase Doppler anemometry. Finally we present recommendations for contactor geometry and for the preferred operating conditions for the extractor.

Liquid–liquid extraction process of amino acids by a new amide-based functionalized ionic liquid

2012 ◽  
Vol 14 (6) ◽  
pp. 1721 ◽  
Author(s):  
Li Huaxi ◽  
Li Zhuo ◽  
Yin Jingmei ◽  
Li Changping ◽  
Chi Yansheng ◽  
...  
Keyword(s):  
Amino Acids ◽  
Ionic Liquid ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Functionalized Ionic Liquid ◽  
Liquid Liquid Extraction

An ionic liquid extraction process for the separation of indole from wash oil

2015 ◽  
Vol 17 (7) ◽  
pp. 3783-3790 ◽  
Author(s):  
Tiantian Jiao ◽  
Xulei Zhuang ◽  
Hongyan He ◽  
Lihong Zhao ◽  
Chunshan Li ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Process Simulation ◽  
Environmentally Friendly ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Separation Process

Imidazolium-based ionic liquids (IBILs) were developed as an extraction medium to separate indole from wash oil. The process is environmentally friendly and the IBILs could be easily recycled. The extraction conditions are very mild. A separation process is proposed based on the process simulation.

scholarly journals Development of trace analysis for alkyl methanesulfonates in the delgocitinib drug substance using GC-FID and liquid–liquid extraction with ionic liquid

2020 ◽  
Vol 18 (1) ◽  
pp. 1020-1029
Author(s):  
Shinkichi Nomura ◽  
Yoshiharu Ito ◽  
Shigehiko Takegami ◽  
Tatsuya Kitade
Keyword(s):  
Ionic Liquid ◽  
Trace Analysis ◽  
Direct Injection ◽  
Liquid Extraction ◽  
Drug Substance ◽  
Flame Ionization ◽  
Liquid Liquid Extraction ◽  
Accuracy And Precision ◽  
Sensitivity And Selectivity ◽  
Chloride Water

AbstractAlkyl methanesulfonates are genotoxic impurities that should be limited to an intake of not more than 1.5 µg/day, as regulated by the International Council for Harmonization guideline M7. We herein report a trace analysis of methyl methanesulfonate (MMS), ethyl methanesulfonate (EMS), and isopropyl methanesulfonate (IPMS) in the delgocitinib drug substance using liquid–liquid extraction, with an ionic liquid as the sample-solving medium, and direct injection gas chromatography detected with a flame-ionization detector. The proposed method takes advantage of the fine solubility of ionic liquids toward the drug substance, the good extraction efficiency of alkyl methanesulfonates in liquid–liquid extraction using the Chem Elut cartridge with low-polar organic solvents, and the ability of alkyl methanesulfonates to concentrate in minimum amounts of organic solvent, resulting in excellent sensitivity and selectivity. Specifically, for the preparation of the sample solution, a mixture of 1-butyl-3-methylimidazolium chloride, water, and acetonitrile was used as the sample-solving media, extracted with diethyl ether, and the eluent was concentrated to 1 mL. The method showed good linearity, accuracy, and precision from 1 to 5 ppm, and the limits of detection of MMS, EMS, and IPMS were 0.1, 0.05, and 0.05 ppm, respectively.

Experimental and numerical investigation of electrostatic spray liquid-liquid extraction with ionic liquids

2012 ◽  
Vol 33 (1) ◽  
pp. 167-183 ◽  
Author(s):  
Marek Krawczyk ◽  
Kamil Kamiński ◽  
Jerzy Petera
Keyword(s):  
Ionic Liquids ◽  
Numerical Investigation ◽  
High Viscosity ◽  
Liquid Extraction ◽  
Separation Processes ◽  
Organic Mixture ◽  
Liquid Liquid Extraction ◽  
Key Factor ◽  
A New Technique ◽  
Electrostatic Spray

Experimental and numerical investigation of electrostatic spray liquid-liquid extraction with ionic liquids A new concept of an electrostatic spray column for liquid-liquid extraction was investigated. An important problem for separation processes is the presence of azeotropic or close-boiling mixtures in their production, for example heptane with ethanol, since the separation is impossible by ordinary distillation. The use of ionic liquids (IL) as a dispersed solvent specially engineered for any specific organic mixture in terms of selectivity is a key factor to successful separation. As IL present particularly attractive combination of favorable characteristics for the separation of heptane and ethanol, in this work we use 1-butyl-3-methylimidazolium methyl sulfate [BMIM][MeSO4]. Because of high viscosity and relatively high cost of IL a new technique was introduced, consisting in the electrostatically spray generation to enhance the mass transport between the phases. In order to optimally design the geometry of the contactor a series of numerical simulation was performed. Especially multi-nozzle variants for better exploitation of contactor volume were investigated. Experiments showed excellent possibility of control of the dispersion characteristics by applied voltage and thus control of the rate of extraction. The preliminary simulations based on our mathematical model for a three nozzle variant exhibited visual agreement with the theory of electrostatics.

scholarly journals Tantalum and Niobium Selective Extraction by Alkyl-Acetophenone

Metals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 654 ◽  
Author(s):  
Moussa Toure ◽  
Guilhem Arrachart ◽  
Jean Duhamet ◽  
Stephane Pellet-Rostaing
Keyword(s):  
Extraction Efficiency ◽  
Methyl Isobutyl Ketone ◽  
Selective Extraction ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Waste Solution ◽  
Liquid Liquid Extraction ◽  
D Values

A study has been carried out on Ta and Nb recovery by a liquid-liquid extraction process using 4-methylacetophenone (4-MAcPh) as the organic phase. The 4-MAcPh was compared to methyl isobutyl ketone (MIBK) with respect to extraction efficiencies (D values) at different concentrations of H2SO4 in the aqueous phase. The results showed a similar extraction of Nb for both solvents. However, for Ta, extraction efficiency is increased by a factor of 1.3 for 4-MAcPh. In addition, the MIBK solubilized completely after 6 mol∙L−1 of H2SO4 against only a loss of 0.14–4% for 4-MAcPh between 6 and 9 mol∙L−1 of H2SO4. The potential of 4-MAcPh has also been studied to selectively recover Ta from a model capacitor waste solution. The results showed a selectivity for Ta in the presence of impurities such as Ag, Fe, Ni and Mn. The 4-MAcPh also presents the advantage of having physicochemical properties adapted to its use in liquid-liquid extraction technologies such as mixer-settlers.

scholarly journals Removal of lindane from wastewater using liquid-liquid extraction process

2013 ◽  
Vol 15 (3) ◽  
pp. 81-84 ◽  
Author(s):  
Indrasing D. Patil ◽  
Yogita S. Patil ◽  
Bhausaheb L. Pangarkar
Keyword(s):  
Distribution Coefficient ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Ternary Mixtures ◽  
Triangular Diagram ◽  
Pesticide Pollution ◽  
Water Solvent ◽  
Liquid Liquid Extraction ◽  
Equilibrium Data ◽  
The Right

Abstract Pesticide pollution is a serious problem being faced. Harmful levels of pesticides are found in the water which is used for daily purposes. In the event of such a scenario, this paper presents a working solution for bringing down the Pesticide levels in the water to safe levels by using the method of liquid-liquid extraction. The experimental liquid-liquid equilibrium data on pesticide-water-solvent ternary mixtures at a temperature of 288.15 K are presented here. The pesticide used here is a chlorinated hydrocarbon called lindane found in the water (underground, land), beverages and foods. The solvents used are Petro-ether-Chloroform (1:1), Ethylene di chloride and n-hexane. The equilibrium generation diagram, triangular diagram, tie lines and bimodal curves as well as the distribution coefficient have been determined and reported. The petro-ether-chloroform was found to be the right solvent for the separation of lindane from wastewater because of high selectivity (25.36) and distribution coefficient (4). The extraction process is simulated into ‘C’ language

scholarly journals Liquid–liquid extraction of gallium(III) with n-octylaniline from succinate media

2005 ◽  
Vol 70 (6) ◽  
pp. 853-867 ◽  
Author(s):  
T.N. Shilmkar ◽  
S.S. Kolekar ◽  
M.A. Anuse
Keyword(s):  
Extraction Process ◽  
Liquid Extraction ◽  
Tolerance Limit ◽  
Variation Method ◽  
Hydrogen Ions ◽  
Binary Separation ◽  
Liquid Liquid Extraction ◽  
Masking Agents ◽  
Increasing Temperature ◽  
Extraction Equilibria

The distribution equilibrium of gallium(III) between n-octylaniline dissolved in toluene and acidic aqueous succinate media has been investigated as a function of the concentration of extractant in the organic phase and concentration of hydrogen ions and gallium( III) ions in the aqueous phase. The stoichiometry of the extracted species was determined on the basis of slope analysis.Gallium(III) is extracted by the anion exchange mechanism as [RNH3+Ga(succinate)2]org. The temperature dependence of the extraction equilibria was examined by the temperature variation method. The extraction process is favoured with increasing temperature. It was found that a large number of cations and anions have a high tolerance limit. The selectivity of the extraction is increased by the use of suitable masking agents. The method affords the binary separation of gallium(III) from associated elements and was further extended to the analysis of a synthetic mixture.

scholarly journals EXTRACTION OF COLORED SUBSTANCES FROM MATE (ILEX PARAGUARIENSIS)

1998 ◽  
Vol 6 (6) ◽  
pp. 45-51
Author(s):  
Vania Regina Gabbi Polli ◽  
Alnei Ramos Prochnow ◽  
Juliane Zimmernan Tamanini
Keyword(s):  
Organic Solvents ◽  
Diethyl Ether ◽  
Sodium Lauryl Sulfate ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Ilex Paraguariensis ◽  
Lauryl Sulfate ◽  
Liquid Liquid Extraction

Liquid-liquid extraction of pigments present in mate (flex Paraguariensis) was studied using various organic solvents and different concentrations. The best results were obtained using diethyl ether and sodium lauryl sulfate. The effect of the addition of ethanol on the extraction process was also analyzed.

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