scholarly journals Removal of lindane from wastewater using liquid-liquid extraction process

2013 ◽  
Vol 15 (3) ◽  
pp. 81-84 ◽  
Author(s):  
Indrasing D. Patil ◽  
Yogita S. Patil ◽  
Bhausaheb L. Pangarkar
Keyword(s):  
Distribution Coefficient ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Ternary Mixtures ◽  
Triangular Diagram ◽  
Pesticide Pollution ◽  
Water Solvent ◽  
Liquid Liquid Extraction ◽  
Equilibrium Data ◽  
The Right

Abstract Pesticide pollution is a serious problem being faced. Harmful levels of pesticides are found in the water which is used for daily purposes. In the event of such a scenario, this paper presents a working solution for bringing down the Pesticide levels in the water to safe levels by using the method of liquid-liquid extraction. The experimental liquid-liquid equilibrium data on pesticide-water-solvent ternary mixtures at a temperature of 288.15 K are presented here. The pesticide used here is a chlorinated hydrocarbon called lindane found in the water (underground, land), beverages and foods. The solvents used are Petro-ether-Chloroform (1:1), Ethylene di chloride and n-hexane. The equilibrium generation diagram, triangular diagram, tie lines and bimodal curves as well as the distribution coefficient have been determined and reported. The petro-ether-chloroform was found to be the right solvent for the separation of lindane from wastewater because of high selectivity (25.36) and distribution coefficient (4). The extraction process is simulated into ‘C’ language

scholarly journals Application of a ternary phase diagram to the liquid-liquid extraction of ethanoic acid using ethyl ethanoate

2019 ◽  
Vol 44 (3) ◽  
pp. 43-49
Author(s):  
Aline Amaral Madeira
Keyword(s):  
Phase Diagram ◽  
Ternary Phase ◽  
Ternary Phase Diagram ◽  
Extraction Process ◽  
Distribution Coefficients ◽  
Liquid Extraction ◽  
Ethanoic Acid ◽  
Liquid Liquid Extraction ◽  
Equilibrium Data ◽  
Tie Lines

This article was elaborated in an approach to the liquid-liquid equilibrium of the extraction process of ethanoic acid (C2H4O2) in aqueous phase using ethyl ethanoate as solvent. The liquid-liquid extraction was modeled by the construction of a ternary phase diagram for the water-ethanoic acid- ethyl ethanoate system with the aid of the Origin software. The equilibrium data were obtained experimentally by titration at room temperature (298.15 K) and atmospheric pressure (101325 Pa) using four mixtures of water, ethanoic acid, and ethyl ethanoate. The determination of the composition of the extract and residue portions in the equilibrium of each mixture by of the tie-lines method allowed to examine the percentages of liquid-liquid extraction achieved. The distribution coefficients and separation factors calculated made it possible an evaluation of the distribution and of the mutual solubility of the solute in the aqueous and organic phases. The results showed a good performance of ethyl ethanoate in the extraction of ethanoic acid for concentrations of solute until 16% of the feed.

scholarly journals Liquid-Liquid Extraction in Systems Containing Butanol and Ionic Liquids – A Review

2017 ◽  
Vol 38 (1) ◽  
pp. 97-110 ◽  
Author(s):  
Artur Kubiczek ◽  
Władysław Kamiński
Keyword(s):  
Ionic Liquids ◽  
Room Temperature ◽  
Liquid Extraction ◽  
Butanol Production ◽  
Model Liquid ◽  
New Class ◽  
Liquid Liquid Extraction ◽  
Liquid Systems ◽  
Nrtl Equation ◽  
Equilibrium Data

AbstractRoom-temperature ionic liquids (RTILs) are a moderately new class of liquid substances that are characterized by a great variety of possible anion-cation combinations giving each of them different properties. For this reason, they have been termed as designer solvents and, as such, they are particularly promising for liquid-liquid extraction, which has been quite intensely studied over the last decade. This paper concentrates on the recent liquid-liquid extraction studies involving ionic liquids, yet focusing strictly on the separation of n-butanol from model aqueous solutions. Such research is undertaken mainly with the intention of facilitating biological butanol production, which is usually carried out through the ABE fermentation process. So far, various sorts of RTILs have been tested for this purpose while mostly ternary liquid-liquid systems have been investigated. The industrial design of liquid-liquid extraction requires prior knowledge of the state of thermodynamic equilibrium and its relation to the process parameters. Such knowledge can be obtained by performing a series of extraction experiments and employing a certain mathematical model to approximate the equilibrium. There are at least a few models available but this paper concentrates primarily on the NRTL equation, which has proven to be one of the most accurate tools for correlating experimental equilibrium data. Thus, all the presented studies have been selected based on the accepted modeling method. The reader is also shown how the NRTL equation can be used to model liquid-liquid systems containing more than three components as it has been the authors’ recent area of expertise.

scholarly journals Tantalum and Niobium Selective Extraction by Alkyl-Acetophenone

Metals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 654 ◽  
Author(s):  
Moussa Toure ◽  
Guilhem Arrachart ◽  
Jean Duhamet ◽  
Stephane Pellet-Rostaing
Keyword(s):  
Extraction Efficiency ◽  
Methyl Isobutyl Ketone ◽  
Selective Extraction ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Waste Solution ◽  
Liquid Liquid Extraction ◽  
D Values

A study has been carried out on Ta and Nb recovery by a liquid-liquid extraction process using 4-methylacetophenone (4-MAcPh) as the organic phase. The 4-MAcPh was compared to methyl isobutyl ketone (MIBK) with respect to extraction efficiencies (D values) at different concentrations of H2SO4 in the aqueous phase. The results showed a similar extraction of Nb for both solvents. However, for Ta, extraction efficiency is increased by a factor of 1.3 for 4-MAcPh. In addition, the MIBK solubilized completely after 6 mol∙L−1 of H2SO4 against only a loss of 0.14–4% for 4-MAcPh between 6 and 9 mol∙L−1 of H2SO4. The potential of 4-MAcPh has also been studied to selectively recover Ta from a model capacitor waste solution. The results showed a selectivity for Ta in the presence of impurities such as Ag, Fe, Ni and Mn. The 4-MAcPh also presents the advantage of having physicochemical properties adapted to its use in liquid-liquid extraction technologies such as mixer-settlers.

scholarly journals Liquid–liquid extraction of gallium(III) with n-octylaniline from succinate media

2005 ◽  
Vol 70 (6) ◽  
pp. 853-867 ◽  
Author(s):  
T.N. Shilmkar ◽  
S.S. Kolekar ◽  
M.A. Anuse
Keyword(s):  
Extraction Process ◽  
Liquid Extraction ◽  
Tolerance Limit ◽  
Variation Method ◽  
Hydrogen Ions ◽  
Binary Separation ◽  
Liquid Liquid Extraction ◽  
Masking Agents ◽  
Increasing Temperature ◽  
Extraction Equilibria

The distribution equilibrium of gallium(III) between n-octylaniline dissolved in toluene and acidic aqueous succinate media has been investigated as a function of the concentration of extractant in the organic phase and concentration of hydrogen ions and gallium( III) ions in the aqueous phase. The stoichiometry of the extracted species was determined on the basis of slope analysis.Gallium(III) is extracted by the anion exchange mechanism as [RNH3+Ga(succinate)2]org. The temperature dependence of the extraction equilibria was examined by the temperature variation method. The extraction process is favoured with increasing temperature. It was found that a large number of cations and anions have a high tolerance limit. The selectivity of the extraction is increased by the use of suitable masking agents. The method affords the binary separation of gallium(III) from associated elements and was further extended to the analysis of a synthetic mixture.

scholarly journals Experimental investigation and modeling of thermophysical and extraction properties of choline chloride + DL-malic acid based deep eutectic solvent

2017 ◽  
Vol 82 (11) ◽  
pp. 1287-1302 ◽  
Author(s):  
Jelena Vuksanovic ◽  
Nina Todorovic ◽  
Mirjana Kijevcanin ◽  
Slobodan Serbanovic ◽  
Ivona Radovic
Keyword(s):  
Malic Acid ◽  
Atmospheric Pressure ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Ternary Mixtures ◽  
Extraction Ability ◽  
Experimental Phase ◽  
Liquid Liquid Extraction ◽  
Equilibrium Data ◽  
Extraction Properties

The ability of non-toxic and biodegradable deep eutectic solvent (DES) choline chloride + DL-malic acid in mole ratio 1:1, for the breaking of the azeotropes heptane + methanol and toluene + methanol by means of liquid? ?liquid extraction was evaluated. Ternary liquid?liquid equilibrium experiments were performed at 298.15 K and at atmospheric pressure. Densities, viscosities and refractive indices of DES + methanol and water + DES systems were experimentally determined over a wide temperature range and at atmospheric pressure. Additionally, the viscosities of DES + glycerol mixture were - determined at temperatures up to 363.15 K to check how much the addition of glycerol decreases high viscosities of DES. The results indicate that the addition of small amounts of water or glycerol as a third component significantly decreases the viscosity of the investigated deep eutectic solvent. Based on the selectivity and distribution ratio values, the extraction ability of the investigated deep eutectic solvent, in comparison with the conventionally used solvents, yields promising results. Non-random two-liquid (NRTL) and universal quasichemical (UNIQUAC) models were satisfactorily applied for correlation of experimental phase equilibrium data for two ternary mixtures.

scholarly journals EXTRACTION OF COLORED SUBSTANCES FROM MATE (ILEX PARAGUARIENSIS)

1998 ◽  
Vol 6 (6) ◽  
pp. 45-51
Author(s):  
Vania Regina Gabbi Polli ◽  
Alnei Ramos Prochnow ◽  
Juliane Zimmernan Tamanini
Keyword(s):  
Organic Solvents ◽  
Diethyl Ether ◽  
Sodium Lauryl Sulfate ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Ilex Paraguariensis ◽  
Lauryl Sulfate ◽  
Liquid Liquid Extraction

Liquid-liquid extraction of pigments present in mate (flex Paraguariensis) was studied using various organic solvents and different concentrations. The best results were obtained using diethyl ether and sodium lauryl sulfate. The effect of the addition of ethanol on the extraction process was also analyzed.

Polymers for electronics: a new process under development

OPE Journal ◽  
2021 ◽  
Vol 11 (37) ◽  
pp. 20-20
Keyword(s):  
Extraction Process ◽  
Liquid Extraction ◽  
Liquid Liquid Extraction ◽  
New Process

The experts at Seqens are working on the implementation of a continuous liquid-liquid extraction process. In OPE journal, the company provides an update on the development

Recovery of Tea Polyphenols from Green Tea Waste by Liquid-Liquid Extraction

2011 ◽  
Vol 396-398 ◽  
pp. 1592-1595
Author(s):  
Zhong Jian Li ◽  
Zhe Wei ◽  
Wei Xiao ◽  
Jun Wang ◽  
Fu An Wu
Keyword(s):  
Distribution Coefficient ◽  
Green Tea ◽  
Ph Value ◽  
New Technology ◽  
Selective Extraction ◽  
Extraction Process ◽  
Tea Polyphenols ◽  
Extraction Temperature ◽  
Tea Waste ◽  
Equilibrium Data

Tea (Camellia sinensis L.) has became one of the most consumed beverages in the world in the past five thousand years, and tea polyphenols (TPs) are important organic acids widely used in chemical, pharmaceutical, food and other industries, which have been shown to exhibit various biological and pharmacological properties. In order to look for new technology of downstream process for TPs separation from green tea waste, selective extraction of TPs with 12 varieties of solvents were carried out, the distribution coefficient and equilibrium experiments at various temperatures were described by extraction isotherms model. The results indicated that the optimum solvent conditions were as follow: extractent was glyceryl triacetate, extraction temperature range was 20~30°C, pH value of crude TPs and reextractant were 3.17 and 9, respectively. Equilibrium data of TPs were successfully fitted to Henry isotherm, the distribution coefficient decreases with the increasing of the temperature, which showing an exothermic adsorption process. The data obtained is useful in the designing of solvent extraction process for the recovery of TPs from green tea waste.

STUDIES OF SOLVENT EXTRACTION AND SUPPORTED LIQUID MEMBRANE WITH REACTIVE DYES FROM AQUEOUS SOLUTIONS USING ALIQUOT 336 AS CARRIER

2015 ◽  
Vol 1 (01) ◽  
pp. 54-60
Author(s):  
G Muthuraman
Keyword(s):  
Solvent Extraction ◽  
Liquid Membrane ◽  
Reactive Dyes ◽  
Extraction Process ◽  
Liquid Extraction ◽  
Supported Liquid Membrane ◽  
Liquid Liquid Extraction ◽  
Dye Transport ◽  
Stage Process ◽  
The Stability

The liquid-liquid extraction (LLE) and supported liquid membrane (SLM) studies of reactive dyes namely Gold Yellow (GYHE-R) and Reactive Green HE 4BD (RGHE-4BD) from aqueous solution using Aliquot 336 as the carrier has been investigated. Polytetrafluoroethylene (PTFE) membrane with 0.5 μm pore size has been used after impregnated with Aliquot 336 in dichloromethane. In liquid liquid extraction the following parameters had been optimized; pH of feed, diluent, carrier , strip and dye concentration and the same parameters have been applied to supported liquid membrane (SLM) study to transport dye from aqueous solution.The main advantages SLM study is; the extraction and stripping as single stage process and low consumption of carrier in the membrane phase compared to the solvent extraction process. The other parameters such as transport time, stirring speed and mechanism of dye transport has also studied by SLM. The percentage of transport of dye and flux rate increases with increasing time. The stability of membrane is satisfactory over 5 days.

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