Mechanical properties and decay resistance of Scots pine (Pinus sylvestris L.) sapwood modified by vinyl acetate-epoxidized linseed oil copolymer

Holzforschung ◽  
2016 ◽  
Vol 70 (9) ◽  
pp. 885-894 ◽  
Author(s):  
Shengzhen Cai ◽  
Mohamed Jebrane ◽  
Nasko Terziev ◽  
Geoffrey Daniel
Keyword(s):  
Mechanical Properties ◽  
Pinus Sylvestris ◽  
Vinyl Acetate ◽  
Scots Pine ◽  
Linseed Oil ◽  
Untreated Wood ◽  
Decay Resistance ◽  
Mechanical Tests ◽  
Slight Reduction ◽  
Epoxidized Linseed Oil

Abstract Equilibrium moisture content (EMC), mechanical properties, and durability of Scots pine (Pinus sylvestris L.) sapwood modified by vinyl acetate epoxidized linseed oil (WVA-ELO) have been studied. Microscopic observations revealed that the impregnated copolymer is mainly in cell walls, rays, resin canals, and a small fraction in the cell lumens. Under the same climate conditioning, the EMC of the treated wood was in the range of 6.0%–8.2%, which was significantly lower than that of untreated wood (about 12%). Mechanical tests performed on paired samples (control and treated) showed a slight reduction on the mechanical properties of WVA-ELO. The decay resistance against basidiomycete fungi of WVA-ELO was significantly improved as demonstrated by laboratory tests. It was found that 8% weight percentage gain (WPG) was sufficient to ensure decay resistance against the test fungi with <5% mass loss (ML), which led to durability class (DC) of 2.

scholarly journals Selected physical and mechanical properties of Scots pine (Pinus sylvestris L.) wood from stands of younger age classes as criteria for rational utilization of timber

2021 ◽  
Vol 27 (1) ◽  
Author(s):  
Przemysław Marcin Pikiński ◽  
Jaroslav Szaban ◽  
Gerda Šilingienė ◽  
Robert Korzeniewicz ◽  
Witold Pazdrowski
Keyword(s):  
Mechanical Properties ◽  
Pinus Sylvestris ◽  
Scots Pine ◽  
Bending Strength ◽  
Physical And Mechanical Properties ◽  
Growth Conditions ◽  
Tree Age ◽  
Coniferous Forests ◽  
Forest Site ◽  
Quality Coefficient

The aim of this study was to assess the quality of Scots pine (Pinus sylvestris L.) wood depending on the age of trees, forest site conditions and social class of tree position in the stand. Analyses were based on the determination of specific density and static bending strength, as well as the strength quality coefficient. It was to determine changes in physical and mechanical properties of timber depending on tree age as well as growth conditions reflected in the forest site such as fresh mixed coniferous forests and fresh mixed broadleaved forests. Experimental plots were established in 6 localities with 30, 40 and 60-year-old trees. In each of the stands, a 1-hectare experimental plot was established. Based on the measured DBH and tree height, dimensions of three mean sample trees were calculated, while the classification of social class of tree position in the stand developed by Kraft (1884) was also applied. Analyses were conducted on wood samples with 12% moisture content. Strength tests on wood samples were performed on an Instron 33RH204 universal strength testing machine. A detailed analysis showed properties of pine wood are improved with an increase of tree age in both forest sites. Statistically significant differences were observed for wood density and static bending strength. More advantageous properties were observed for wood of pines from the less fertile forest site, i.e., fresh mixed coniferous forests. Density and static bending strength were markedly determined by tree age and growth conditions. The static bending strength quality coefficient from pines growing in the fresh mixed coniferous forests increased between 30 and 40 years, similarly as it was for the fresh mixed broadleaved forests, while between 40 and 60 years, it deteriorated for the fresh mixed coniferous forests. Wood density from the fresh mixed coniferous forests was by 3% to 7% greater than pines growing in fresh mixed broadleaved forests. In turn, static bending strength of wood from pines growing in fresh mixed coniferous forests was by 4% to 10% greater than trees from the fresh mixed broadleaved forests.  Keywords: Scots pine, wood properties, forest site, Poland

Curing of wood treated with vinyl acetate-epoxidized linseed oil copolymer (VAc-ELO)

Holzforschung ◽  
2016 ◽  
Vol 70 (4) ◽  
pp. 305-312 ◽  
Author(s):  
Shengzhen Cai ◽  
Mohamed Jebrane ◽  
Nasko Terziev
Keyword(s):  
Vinyl Acetate ◽  
Linseed Oil ◽  
Curing Temperature ◽  
Attenuated Total Reflectance ◽  
Linear Relationships ◽  
Reflectance Ftir ◽  
New Formulation ◽  
Time Linear ◽  
Ir Bands ◽  
Epoxidized Linseed Oil

Abstract Scots pine sapwood was treated with a new formulation consisting of vinyl acetate (VAc) and epoxidized linseed oil (ELO) catalyzed by potassium persulfate to impart protection to wood. The effects of various curing temperatures, durations, and solution uptakes on dimensional stability (DS) and leachability were studied. The new formulation provided good anti-swelling efficiency (ASE) ranging from 35% to 47% with negligible leaching of the treating agent after four cycles of water soaking and oven drying (2%–2.5%). The extent of polymerization in wood was observed by FTIR-attenuated total reflectance (FTIR-ATR) by evaluation of the areas below typical IR bands as a function of curing temperature and time. Linear relationships were found with high R2 values. The FTIR data of extracted samples were interpreted that chemical reactions took place between the resulting copolymer and wood components.

Knotwood as a window to the indirect measurement of the decay resistance of Scots pine heartwood

Holzforschung ◽  
2007 ◽  
Vol 61 (5) ◽  
pp. 600-604 ◽  
Author(s):  
Outi Karppanen ◽  
Martti Venäläinen ◽  
Anni M. Harju ◽  
Stefan Willför ◽  
Suvi Pietarinen ◽  
...  
Keyword(s):  
Pinus Sylvestris ◽  
Mass Loss ◽  
Scots Pine ◽  
Total Phenolics ◽  
Decay Resistance ◽  
Indirect Measurement ◽  
The Other ◽  
Extractive Content ◽  
Standing Trees ◽  
Further Development

Abstract There is wide variation in the extractive content and decay resistance of Scots pine (Pinus sylvestris L.) heartwood. The heartwood is not visible in standing trees and only poorly visible in timber. Therefore, it is difficult to identify extractive-rich trees, and consequently the most decay-resistant heartwood. On the other hand, knots are clearly visible in standing trees and timber. In the present paper we studied the possibility of measuring the decay resistance of Scots pine heartwood indirectly on the basis of the extractive concentration of knotwood. The material investigated consisted of 40 felled trees with a wide between-tree variation for extractive content and decay resistance of their heartwood. The extractive content of knotwood was found to be four- to five-fold higher than that of heartwood. Statistically significant correlations were found between the mass loss of heartwood and the concentrations of total phenolics and stilbenes in knotwood (r=-0.54, P<0.001 and r=-0.40, P=0.011, respectively), and for the concentration of total phenolics (r=0.42, P=0.008) and stilbenes (r=0.39, P=0.012) between heartwood and knotwood. We suggest further development of this technique in the context of rapid industrial screening of durable pine heartwood.

Significant enhancement of fracture toughness and mechanical properties of epoxy resin using CTBN‐grafted epoxidized linseed oil

2019 ◽  
Vol 137 (2) ◽  
pp. 48276 ◽  
Author(s):  
Quang‐Vu Bach ◽  
Cuong Manh Vu ◽  
Huong Thi Vu ◽  
Hoa Binh Vu ◽  
Tuyen Van Nguyen ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Epoxy Resin ◽  
Linseed Oil ◽  
Significant Enhancement ◽  
Epoxidized Linseed Oil

scholarly journals Dimensional stability, fungal resistance and mechanical properties of radiata pine after combined thermo-mechanical compression and oil heat-treatment

Holzforschung ◽  
2016 ◽  
Vol 70 (8) ◽  
pp. 793-800 ◽  
Author(s):  
Manoj Kumar Dubey ◽  
Shusheng Pang ◽  
Shakti Chauhan ◽  
John Walker
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Dimensional Stability ◽  
Linseed Oil ◽  
Treated Wood ◽  
Untreated Wood ◽  
Radiata Pine ◽  
Fungal Resistance ◽  
Compression Set ◽  
Decay Test

Abstract The dimensional stability and mechanical properties of radiata pine (Pinus radiata) has been investigated after thermo-mechanically compression (TMC) followed by oil heat-treatment (OHT). Wood specimens were first compressed in the radial direction then heat-treated in a linseed oil bath at 160–210°C. Spring-back percentage, water repellence efficiencies, and compression set recovery percentage were determined as indicators of dimensional stability. The resistance of treated wood against a brown rot fungi was assessed based on an accelerated laboratory fungal decay test. Strength, stiffness and hardness were determined as a function of different treatment parameters. After TMC, high compression set (39%) was achieved without any surface checks and cracks. Specimens undergoing TMC followed by OHT showed relatively less swelling and low compression set recovery under high moisture conditions. The fungal resistance of wood after TMC+OHT slightly increased compared to untreated wood and TMC wood. The mechanical properties of TMC+OHT wood were inferior to those of TMC wood.

scholarly journals Response of <i>Pinus sylvestris</i> roots to sheet-erosion exposure: an anatomical approach

2008 ◽  
Vol 8 (2) ◽  
pp. 223-231 ◽  
Author(s):  
J. M. Rubiales ◽  
J. M. Bodoque ◽  
J. A. Ballesteros ◽  
A. Diez-Herrero
Keyword(s):  
Pinus Sylvestris ◽  
Scots Pine ◽  
Growth Ring ◽  
First Year ◽  
Slight Reduction ◽  
Tree Roots ◽  
Homogeneous Groups ◽  
Erosion Rates ◽  
The Moment ◽  
Sheet Erosion

Abstract. Anatomical changes of exposed tree roots are valuable tools to date erosion events, but the responses of diverse species under different types of erosion need still to be studied in detail. In this paper we analyze the histological changes that occur in roots of Scots pine (Pinus sylvestris L.) subjected to continuous denudation. A descriptive and quantitative study was conducted in the Senda Schmidt, a popular trail located on the northern slope of the Sierra de Guadarrama (Central Iberian System, Spain). Measurement of significant parameters allowed the moment of exposure of the roots to be identified. These parameters were: a) width of the growth ring; b) number of cells per ring; c) percentage of latewood and d) diameter of cellular light in earlywood. A one-way analysis ANOVA was also carried out in order to establish statistically significant differences between homogeneous groups of measurements in pre-exposed and exposed roots. Based on these analyses, Scots pine roots show a remarkable anatomical response to sheet-erosion exposure. Increased growth in the ring is accompanied by a slight reduction of the cell lumina of the earlywood tracheids. At the end of the ring, several rows of thick-walled tracheids define latewood tissue and visible annual borders very clearly. Furthermore, resin ducts often appear in tangential rows, increasing resin density in the tissue. All of these indicators made it possible to determine with precision the first year of exposure and to estimate precisely sheet erosion rates.

Structure and Property of PGMA/Wood Composite

2009 ◽  
Vol 87-88 ◽  
pp. 456-461 ◽  
Author(s):  
Yong Feng Li ◽  
Yi Xing Liu ◽  
Jiang Tao Shi ◽  
Gang Li
Keyword(s):  
Mechanical Properties ◽  
Dimensional Stability ◽  
Cell Walls ◽  
Cellular Structure ◽  
Untreated Wood ◽  
Decay Resistance ◽  
Modulus Of Rupture ◽  
Test Results ◽  
Tight Contact ◽  
Wood Based Composite

In order to prepare a wood-based composite material which, as a type of multifunctional and natural bio-based material, possesses satisfactory mechanical properties, excellent durability (i.e., decay resistance and dimensional stability), and Aenvironmental characteristic, the study presents a new method which is based on the cellular structure of wood by initiating polymerizable monomers for in situ polymerization. Glycidyl methacrylate (GMA) as a multifunctional and polymerizable monomer was chosen, and impregnated into the porous structure of wood. After a thermal-catalyst process, the wood-based composite, PGMA/Wood, was prepared. The structure of this material was analyzed by SEM, FTIR and XRD; and its performance was also determined. The analyzing results show that GMA not only polymerized in the cellular structure in a solid form and amorphous form, which fully and uniformly filled in wood cell lumen, but also sufficiently grafted onto wood cell walls in a chemical level, resulting in tight contact between wood cell walls and resultant polymers (PGMA) without any obvious cracks. The test results of mechanical properties show that the modulus of rupture (MOR), modulus of elasticity (MOE), compression strength, and hardness of PGMA/Wood increased by 82%, 122%, 139%, and 348% over those of untreated wood, respectively. The test results of durability show that the dimensional stability and decay resistance of PGMA/Wood improved 44% and 91% than those of untreated wood, respectively. Such composite could be widely applied in the fields of construction, furniture and traffic.

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