Economic Optimization of Rare Earth Element Leaching Kinetics from Phosphogypsum with Sulfuric Acid

Author(s):  
Thomas Gaetjens ◽  
Haijun Liang ◽  
Patrick Zhang ◽  
Ryan Moser ◽  
Haley Thomasson ◽  
...  

Abstract Frequently optimizations of chemical processes are presented in terms of the maximization of fractional conversion, but the primary concern when implementing a process is much more likely to be the economic viability. These are distinct optima that tend to occur at very different points. It was the purpose of this paper to integrate leaching experimental data with cost analysis to arrive upon economically optimized leaching conditions for the recovery of rare earth elements from phosphogypsum, a water phosphate byproduct. The variables under consideration were the number of leaching reactors and the residence time of each reactor. The modeling results indicated that the optimum residence time was 270 minutes and that the optimum number of stages was one.

1990 ◽  
Vol 27 (1) ◽  
pp. 57-71 ◽  
Author(s):  
D. C. Gosselin ◽  
J. J. Papike ◽  
C. K. Shearer ◽  
Z. E. Peterman ◽  
J. C. Laul

The Little Elk Granite (2549 Ma) and granite at Bear Mountain (BMG) (~2.5 Ga) of the Black Hills formed as a result of a collisional event along the eastern margin of the Wyoming Province during the late Archean. Geochemical modelling and Nd isotopic data indicate that the Little Elk Granite was generated by the partial melting of a slightly enriched (εNd = −1.07 to −3.69) granodioritic source that had a crustal residence time of at least 190 Ma. The medium-grained to pegmatitic, peraluminous, leucocratic BMG was produced by melting a long-lived (>600 Ma), compositionally variable, enriched (εNd = −7.6 to −12.3) crustal source. This produced a volatile-rich, rare-earth-element-poor magma that experienced crystal–melt–volatile fractionation, which resulted in a lithologically complex granite.The production of volatile-rich granites, such as the BMG and the younger Harney Peak Granite (1715 Ma), is a function of the depositional and post-depositional tectonic environment of the sedimentary source rock. These environments control protolith composition and the occurrence of dehydration and melting reactions that are necessary for the generation of these volatile-rich leucocratic granites. These types of granites are commonly related to former continental–continental accretionary boundaries, and therefore their occurrence may be used as signatures of ancient continental suture zones.


2014 ◽  
Vol 146 ◽  
pp. 133-137 ◽  
Author(s):  
Chul-Joo Kim ◽  
Ho-Sung Yoon ◽  
Kyung Woo Chung ◽  
Jin-Young Lee ◽  
Sung-Don Kim ◽  
...  

Alloy Digest ◽  
2015 ◽  
Vol 64 (9) ◽  

Abstract Elektron EQ21 is a casting high strength magnesium alloy developed as a heat treatable alloy with rare earth element additions. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and compressive, shear, and bend strength as well as creep. It also includes information on high temperature performance and corrosion resistance as well as casting, forming, heat treating, machining, joining, and surface treatment. Filing Code: Mg-80. Producer or source: Magnesium Elektron Wrought Products, North America.


2016 ◽  
Author(s):  
Shayantani Ghosal ◽  
◽  
Sudha Agrahari ◽  
Debashish Sengupta

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