scholarly journals Physicochemical Properties of Melts Used for the Electrodeposition of Niobium

2007 ◽  
Vol 62 (9) ◽  
pp. 540-544 ◽  
Author(s):  
Blanka Kubikova ◽  
Vladimir Danek ◽  
Marcelle Gaune-Escard
Keyword(s):  
Surface Tension ◽  
Phase Equilibrium ◽  
Ternary System ◽  
Physicochemical Properties ◽  
Binary Systems ◽  
Limited Solubility

Formation of oxyfluoroniobium compounds in the binary systems KF-Nb2O5 and K2NbF7-Nb2O5 and in the ternary system KF-K2NbF7-Nb2O5 has been expected. Therefore the phase equilibrium and surface tension of the above systems have been determined. The three systems have only been investigated up to 20 mol% Nb2O5 because of its limited solubility. The obtained results have confirmed the formation of oxyfluoroniobium compounds.

scholarly journals Two-phase equilibrium in binary and ternary systems II. The system methane-ethylene III. The system methane-ethane-ethylene

1940 ◽  
Vol 176 (964) ◽  
pp. 140-152 ◽  
Keyword(s):  
Phase Equilibrium ◽  
Ternary System ◽  
Binary Systems ◽  
Ternary Systems ◽  
Two Phase ◽  
Composition Diagram ◽  
Wide Range ◽  
Binary And Ternary Systems

The liquid-vapour equilibrium of the system methane-ethylene has been determined at 0, -42 , -78, -88 and -104° C over a wide range of pressures and the results are shown on a pressure-composition-temperature diagram and by a series of pressure-composition curves. The liquid-vapour equilibrium of the ternary system methane-ethane-ethylene has been determined at -104, -78 and 0° C. Values for the two binary systems methane-ethane and methane-ethylene and for the ternary system methane-ethane-ethylene are shown on a composite pressure-composition diagram.

Densities, Excess Volumes, Surface Tensions, Viscosities, and Dielectric Constants of the Systems: Methanol–Cyclohexane, Acetone–Methanol, Acetone–Cyclohexane, and Methanol–Cyclohexane–Acetone

1972 ◽  
Vol 50 (8) ◽  
pp. 1109-1114 ◽  
Author(s):  
A. N. Campbell ◽  
S. C. Anand
Keyword(s):  
Surface Tension ◽  
Ternary System ◽  
Binary Systems ◽  
Dielectric Constants ◽  
Molecular Surface ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Constant Change ◽  
Molar Polarization ◽  
Horizontal Portion

The density, dielectric constant, change of volume on mixing, refractive index, surface tension, and viscosity of the methanol–cyclohexane system have been investigated experimentally at temperatures ranging from 25° to 50°. The same properties of the binary systems acetone–methanol and acetone–cyclohexane, as well as of the ternary system methanol–cyclohexane–acetone were determined experimentally at 25°. The critical region of the partially miscible system methanol–cyclohexane has been investigated by determining the above physical properties at temperatures above and below the critical solution temperature. A similar investigation of the ternary system has been made, isothermally at 25°, by investigating solutions lying in the neighborhood of the plait point.The surface tension or a derived function of it, viz. the molecular surface energy, does not show a horizontal portion of the isotherm in the methanol–cyclohexane system, but the ternary system does show such a constant surface tension, probably fortuitously, all along the tangential line. The viscosity exhibits anomaly.All the systems show azeotropic behavior. The methanol–cyclohexane and acetone–cyclohexane systems show marked deviations in molar polarization from linearity and this agrees with the thermodynamic data, which indicate larger than unity values for the activity coefficients of the components' behavior (1). The viscosity isotherms of all these systems give no indication of the formation of any stable compound.

Physico-chemical properties of the ternary system urea-ammonium nitrate-water. Surface tension

1985 ◽  
Vol 50 (8) ◽  
pp. 1629-1635 ◽  
Author(s):  
Marie Šišková ◽  
Jiřina Hejtmánková ◽  
Lidmila Bartovská
Keyword(s):  
Surface Tension ◽  
Ternary System ◽  
Ammonium Nitrate ◽  
Binary Systems ◽  
Chemical Properties ◽  
Ternary Systems ◽  
Surface Tensions ◽  
Physico Chemical ◽  
Urea Ammonium Nitrate ◽  
Experimental Values

Surface tension of two binary systems ammonium nitrate-water and urea-water and of the ternary system ammonium nitrate-urea-water was measured as a function of concentration at 20 and 40 °C. The experimental values were compared with those calculated from the relations which were proposed for calculating surface tensions of ternary systems from measured surface tensions of both binary systems.

Estimation of Various Properties of CaO–“FeO”–SiO2 System at 1,673 K by Mass Triangle Model

2017 ◽  
Vol 36 (6) ◽  
pp. 581-585
Author(s):  
Yaxian Wang ◽  
Lijun Wang ◽  
Kuo-chih Chou
Keyword(s):  
Experimental Data ◽  
Surface Tension ◽  
Physicochemical Properties ◽  
Calculated Data ◽  
Sulfide Capacity ◽  
Metallurgical Process ◽  
New Model ◽  
Sio2 System ◽  
Limited Solubility ◽  
Contour Lines

AbstractIn consideration of great need for the physicochemical properties of slag systems in metallurgical process estimation, this work examined the possibility of predicting multi-properties by one model. The mass triangle model was applied to evaluate the density, viscosity, surface tension and sulfide capacity of CaO–“FeO”–SiO2 system at 1,673 K. Good agreements were achieved between calculated data and experimental data in the various properties. Meanwhile, the calculated contour lines successfully predicted the properties of slag within the limited solubility area. The new model thus is competitive and flexible when an integrated knowledge of a certain system is necessary.

PHASE EQUILIBRIUM IN THE AS2TE3-TM2TE3 SYSTEM.

2020 ◽  
Vol 5 (8(77)) ◽  
pp. 65-68
Author(s):  
Teymur Mammad Ilyasly ◽  
Rahman Hasanaga Fatullazade ◽  
Zakir Islam Ismailov ◽  
Nigar Nadir Jafarova
Keyword(s):  
Thermal Analysis ◽  
Solid Solution ◽  
Differential Thermal Analysis ◽  
Phase Equilibrium ◽  
Physicochemical Properties ◽  
Thermal Effects ◽  
Isothermal Annealing ◽  
Intermediate Phase ◽  
Physicochemical Analysis ◽  
Two Phases

The synthesis of alloys of the system was carried out stepwise in rotary furnaces. The synthesis mode was selected based on the physicochemical properties of the elementary components. For homogenization, the alloys were subjected to isothermal annealing at 750 and 1275 K, depending on the Tm2Te3 concentration, for 250 h after homogenization of the alloys, they were subjected to physicochemical analysis. The results of differential thermal analysis showed that reversible thermal effects are observed in the alloys of the system. In alloys in a 1: 1 ratio, a new intermediate phase is formed with a composition corresponding to the TmAsTe3 compound. The homogeneity area is observed in the concentration range 52.5-47.5. It was found that in the concentration range 98.5-52.5 Tm2Te3 there are two phases - a mixture of β and of the solid solution, and in the concentration range of 47.51 mol% Tm2Te3 phases and α are in equilibrium. ) 66 The eutectic has coordinates of 11.5 mol Tm2Te3 at a temperature of 575 K.

[P21] Experimental investigation of phase equilibrium in Al-Ti-Zr ternary system

Calphad ◽  
2015 ◽  
Vol 51 ◽  
pp. 378-379
Author(s):  
F. Yang ◽  
H.S. Liu ◽  
G.M. Cai ◽  
Z.P. Jin
Keyword(s):  
Experimental Investigation ◽  
Phase Equilibrium ◽  
Ternary System

Concentration Dependence of the Surface Tension of Three and Four-Component Systems with Peculiarities in the Surface Tension Isotherms of Lateral Binary Melts

2021 ◽  
Vol 1022 ◽  
pp. 194-202
Author(s):  
R.Kh. Dadashev ◽  
R.A. Kutuev
Keyword(s):  
Experimental Data ◽  
Surface Tension ◽  
Concentration Dependence ◽  
Experimental Error ◽  
Binary Systems ◽  
Experimental Studies ◽  
Study Results ◽  
Component Systems ◽  
Minimum Depth ◽  
Surface Tension Isotherms

The experimental study results of the melts concentration dependence of the surface tension of the four-component indium-tin-lead-bismuth system and its constituent binary systems of indium-tin, indium-lead, indium-bismuth, tin-lead, tin-bismuth, lead-bismuth are presented in the paper. It is shown that the concentration dependence of the melts surface tension of the In-Sn-Pb-Bi four-component system can be predicted from the data on ST (surface tension) values of lateral binary systems. Features in the ST isotherms in the form of a minimum are observed only in the indium-tin lateral system from all lateral binaries. A distinctive feature of the detected minimum is that the minimum depth slightly exceeds the experimental error. Therefore, in addition to the fact that the area of average compositions was studied more thoroughly, we carried out the surface tension measurements by two independent methods. The experimental data obtained by both methods coincide within the experimental error and indicate the extremum availability on ST isotherms. Thus, ST experimental studies by two independent methods confirmed the presence of a flat minimum on ST isotherms of the indium-tin binary system increasing the reliability of the obtained data. The obtained outcomes and their comparison with experimental data have shown that the considered models for predicting surface properties based on data due to similar properties of lateral binary systems adequately reflect the experimental dependences. However, the prediction model based on Kohler's method of excess values describes the experimental curves more accurately.

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