Concentration Dependence of the Surface Tension of Three and Four-Component Systems with Peculiarities in the Surface Tension Isotherms of Lateral Binary Melts

2021 ◽  
Vol 1022 ◽  
pp. 194-202
Author(s):  
R.Kh. Dadashev ◽  
R.A. Kutuev
Keyword(s):  
Experimental Data ◽  
Surface Tension ◽  
Concentration Dependence ◽  
Experimental Error ◽  
Binary Systems ◽  
Experimental Studies ◽  
Study Results ◽  
Component Systems ◽  
Minimum Depth ◽  
Surface Tension Isotherms

The experimental study results of the melts concentration dependence of the surface tension of the four-component indium-tin-lead-bismuth system and its constituent binary systems of indium-tin, indium-lead, indium-bismuth, tin-lead, tin-bismuth, lead-bismuth are presented in the paper. It is shown that the concentration dependence of the melts surface tension of the In-Sn-Pb-Bi four-component system can be predicted from the data on ST (surface tension) values of lateral binary systems. Features in the ST isotherms in the form of a minimum are observed only in the indium-tin lateral system from all lateral binaries. A distinctive feature of the detected minimum is that the minimum depth slightly exceeds the experimental error. Therefore, in addition to the fact that the area of average compositions was studied more thoroughly, we carried out the surface tension measurements by two independent methods. The experimental data obtained by both methods coincide within the experimental error and indicate the extremum availability on ST isotherms. Thus, ST experimental studies by two independent methods confirmed the presence of a flat minimum on ST isotherms of the indium-tin binary system increasing the reliability of the obtained data. The obtained outcomes and their comparison with experimental data have shown that the considered models for predicting surface properties based on data due to similar properties of lateral binary systems adequately reflect the experimental dependences. However, the prediction model based on Kohler's method of excess values describes the experimental curves more accurately.

Correlation of Surface and Interfacial Tension of Light Hydrocarbons in the Critical Region

1961 ◽  
Vol 1 (04) ◽  
pp. 259-263 ◽  
Author(s):  
E.W. Hough ◽  
G.L. Stegemeier
Keyword(s):  
Experimental Data ◽  
Surface Tension ◽  
Interfacial Tension ◽  
Critical Pressure ◽  
Binary Systems ◽  
Gas Oil ◽  
Light Hydrocarbons ◽  
Two Phase ◽  
Component Systems ◽  
Two Phases

Abstract Empirical equations for surface tension of propane and normal butane as functions of reduced temperature are obtained from experimental data. Another correlation relating surface tension to enthalpy of vaporization is given for these two compounds. In addition, new parachor numbers are calculated for the normal paraffin hydrocarbons. These numbers are utilized for the calculation of interfacial tension of two-component systems as functions of pressure and temperature, using a modified form of Weinaug-Katz equation. The experimental data for two binary systems are approximated by the correlation. From these results it is found that the inter facial tension in the high-pressure region remains extremely low at large pressure decrements below the critical pressure. Thus, it appears that condensate systems may have flow characteristics almost like single-phase conditions even though the pressure is within the two-phase region. Experimental data have shown that interfacial tension divided by density difference approaches zero as the critical pressure is approached. A calculation of wetting-phase saturations indicates that the saturation gradient at the two-phase contact becomes increasingly abrupt as the critical pressure is approached. Discussion Prediction of the surface and interfacial tension of the light hydrocarbons and of two-component hydrocarbon mixtures at various temperatures and pressures may be made if other physical properties are known. Extensive experimental work on single-component and binary systems is the basis for the correlations outlined in this paper. Interfacial tension is defined as the specific surface-free energy between two phases of unlike fractional composition, while surface tension is defined as the specific surface-free energy between two phases of the same fractional composition. The usual definitions relating interfacial tension to a liquid-liquid interface and surface tension to a gas-liquid interface are not clearly defined when the critical region is included, and there is no sharp distinction between a gas and a liquid phase. Interfacial tension is probably the most important single force that makes one-half to one-third of the total oil actually in place in a reservoir rock unrecoverable by conventional gas-drive or waterflood methods. A rough estimate of this figure for the United States is 100 billion bbl. Interfacial tension presently is used by petroleum engineers in the estimation of saturation gradients at the gas-oil contact and at the oil-water contact. The data in this paper should prove useful for estimates of reserves involving gas-oil contacts. Relative permeability undoubtedly is influenced by interfacial tension, for sufficiently small values. These data should be useful in determining how small the values are. In addition, these data should eventually add to our fundamental knowledge of surfaces. At the critical point, all surface excesses approach zero and the thickness becomes very large. SINGLE-COMPONENT SYSTEMS It has been observed that the following relationships are good approximations to the physical properties of propane and n-butane. For propane, For n-butane, Guggenheim's values for these constants, not specifically for hydrocarbons, are SPEJ P. 259^

scholarly journals Carbides and Nitrides of Zirconium and Hafnium

Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2728 ◽  
Author(s):  
Sergey V. Ushakov ◽  
Alexandra Navrotsky ◽  
Qi-Jun Hong ◽  
Axel van de Walle
Keyword(s):  
Experimental Data ◽  
Phase Equilibria ◽  
Ab Initio ◽  
Solid Solutions ◽  
Binary Systems ◽  
Experimental Studies ◽  
Published Data ◽  
Oxygen Solubility ◽  
Melting Temperatures ◽  
Ab Initio Computations

Among transition metal carbides and nitrides, zirconium, and hafnium compounds are the most stable and have the highest melting temperatures. Here we review published data on phases and phase equilibria in Hf-Zr-C-N-O system, from experiment and ab initio computations with focus on rocksalt Zr and Hf carbides and nitrides, their solid solutions and oxygen solubility limits. The systematic experimental studies on phase equilibria and thermodynamics were performed mainly 40–60 years ago, mostly for binary systems of Zr and Hf with C and N. Since then, synthesis of several oxynitrides was reported in the fluorite-derivative type of structures, of orthorhombic and cubic higher nitrides Zr3N4 and Hf3N4. An ever-increasing stream of data is provided by ab initio computations, and one of the testable predictions is that the rocksalt HfC0.75N0.22 phase would have the highest known melting temperature. Experimental data on melting temperatures of hafnium carbonitrides are absent, but minimum in heat capacity and maximum in hardness were reported for Hf(C,N) solid solutions. New methods, such as electrical pulse heating and laser melting, can fill the gaps in experimental data and validate ab initio predictions.

Concentration dependence of the surface tension for binary systems

2007 ◽  
Vol 71 (2) ◽  
pp. 257-259 ◽  
Author(s):  
R. Kh. Dadashev ◽  
Kh. B. Khokonov ◽  
Dj. Z. Elimkhanov ◽  
Z. I. Bichueva
Keyword(s):  
Surface Tension ◽  
Concentration Dependence ◽  
Binary Systems

scholarly journals Modifications of the SURDAT database of the physicochemical properties of metals and alloys

2012 ◽  
Vol 48 (3) ◽  
pp. 427-431 ◽  
Author(s):  
W. Gasior ◽  
A. Debski
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Electrical Properties ◽  
Experimental Studies ◽  
Viscosity Data ◽  
Pressure Method ◽  
Mechanical And Electrical Properties ◽  
Study Results ◽  
Wetting Time ◽  
Wetting Force

Experimental studies of the surface tension and the density were carried out by means of the maximum bubble pressure method and the dilatometric technique and next, they were compiled with the results of over 12 years of research of the liquid pure components, binary and multicomponent alloys, with the aim to create the SURDAT database of the Pb-free soldering materials. In the last years, a modification of SURDAT has been conducted. The new version, beside the earlier data of the physical properties, also contains such data as: the viscosity data, selected data of the mechanical and electrical properties, the DTA data and the meniscographic study results (contact angle, wetting time, wetting force and interfacial tension). Additionally, the data base of the heat properties, worked out at NIST (National Institute of Standard and Technology from Boulder in Colorado) has been implemented.

TEMPERATURE DEPENDENCE BEHAVIOR OF ELECTRICAL RESISTIVITY IN NOBLE METALS AT LOW TEMPERATURES

2014 ◽  
Vol 5 (3) ◽  
pp. 982-992 ◽  
Author(s):  
M AL-Jalali
Keyword(s):  
Experimental Data ◽  
Electrical Resistivity ◽  
Temperature Dependence ◽  
Concentration Dependence ◽  
Low Temperatures ◽  
Noble Metals ◽  
Phonon Scattering ◽  
Theoretical Models ◽  
Residual Resistivity ◽  
Electron Phonon Scattering

Resistivity temperature – dependence and residual resistivity concentration-dependence in pure noble metals(Cu, Ag, Au) have been studied at low temperatures. Dominations of electron – dislocation and impurity, electron-electron, and electron-phonon scattering were analyzed, contribution of these mechanisms to resistivity were discussed, taking into consideration existing theoretical models and available experimental data, where some new results and ideas were investigated.

Diagnostics of metal samples using the results of experimental and theoretical study of positively charged microparticles formed upon sample destruction

2018 ◽  
Vol 84 (10) ◽  
pp. 23-28
Author(s):  
D. A. Golentsov ◽  
A. G. Gulin ◽  
Vladimir A. Likhter ◽  
K. E. Ulybyshev
Keyword(s):  
Experimental Data ◽  
Early Stage ◽  
Experimental Studies ◽  
Material Model ◽  
Total Charge ◽  
Cross Sectional ◽  
Practical Applications ◽  
Mechanical And Electrical Properties ◽  
Order Of Magnitude ◽  
Using Data

Destruction of bodies is accompanied by formation of both large and microscopic fragments. Numerous experiments on the rupture of different samples show that those fragments carry a positive electric charge. his phenomenon is of interest from the viewpoint of its potential application to contactless diagnostics of the early stage of destruction of the elements in various technical devices. However, the lack of understanding the nature of this phenomenon restricts the possibility of its practical applications. Experimental studies were carried out using an apparatus that allowed direct measurements of the total charge of the microparticles formed upon sample rupture and determination of their size and quantity. The results of rupture tests of duralumin and electrical steel showed that the size of microparticles is several tens of microns, the particle charge per particle is on the order of 10–14 C, and their amount can be estimated as the ratio of the cross-sectional area of the sample at the point of discontinuity to the square of the microparticle size. A model of charge formation on the microparticles is developed proceeding from the experimental data and current concept of the electron gas in metals. The model makes it possible to determine the charge of the microparticle using data on the particle size and mechanical and electrical properties of the material. Model estimates of the total charge of particles show order-of-magnitude agreement with the experimental data.

scholarly journals Revisiting Kelvin equation and Peng–Robinson equation of state for accurate modeling of hydrocarbon phase behavior in nano capillaries

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ilyas Al-Kindi ◽  
Tayfun Babadagli
Keyword(s):  
Experimental Data ◽  
Surface Tension ◽  
Equation Of State ◽  
Phase Behavior ◽  
Pore Radius ◽  
Microfluidic Chips ◽  
Tight Sandstone ◽  
Kelvin Equation ◽  
Rock Samples ◽  
Robinson Equation

AbstractThe thermodynamics of fluids in confined (capillary) media is different from the bulk conditions due to the effects of the surface tension, wettability, and pore radius as described by the classical Kelvin equation. This study provides experimental data showing the deviation of propane vapour pressures in capillary media from the bulk conditions. Comparisons were also made with the vapour pressures calculated by the Peng–Robinson equation-of-state (PR-EOS). While the propane vapour pressures measured using synthetic capillary medium models (Hele–Shaw cells and microfluidic chips) were comparable with those measured at bulk conditions, the measured vapour pressures in the rock samples (sandstone, limestone, tight sandstone, and shale) were 15% (on average) less than those modelled by PR-EOS.

Treated Textile Electrostatic Properties Study

2020 ◽  
Vol 992 ◽  
pp. 439-444
Author(s):  
I.V. Cherunova ◽  
S.S. Tashpulatov ◽  
S.V. Kurenova
Keyword(s):  
Experimental Studies ◽  
Material Structure ◽  
Ministry Of Education ◽  
Research Results ◽  
Textile Materials ◽  
Electrostatic Properties ◽  
Film Forming ◽  
Study Results ◽  
Water Proofing ◽  
Textile Fabric

In the article research results are presented, which aim to provide treated textile electrostatic properties study. In the article research results are presented, which aim to provide find out abilities of an anti-electrostatic treatment and binding agents for it in treatment of special textile materials and their dependance from modes of operating textile washing. Results of determine a composition and abilities of a functional impregnation; develop a method to study values of electrostatic field for tribocharging conditions of textile materialsare; experimental studies of electrostatic values of materials with functional treatment depending on operating washing modes also presented here. Study results allowed to establish efficiency of the proposed combination of anti-electrostatic active composition based on 5 % solution of dialkyldimethylammonium chloride with a binding agent with the effect to preserve the treatment in the material structure and content of which is 4 % in application of textile fabric with widely used fiber content (cotton 53 %, polyester + oil and water-proofing finish). Acrylic dispersion is stable film-forming component suitable in preserving anti-electrostatic treatment on the surface of a textile material. The research was made in Don State Technical University within the framework of State Assignment of the Ministry of education and science of Russia under the project 11.9194.2017/BCh.

An investigation of effects of level density models and gamma ray strength functions on cross-section calculations for the production of 90Y, 153Sm, 169Er, 177Lu and 186Re therapeutic radioisotopes via (n,γ) reactions

2019 ◽  
Vol 108 (1) ◽  
pp. 11-17
Author(s):  
Mert Şekerci ◽  
Hasan Özdoğan ◽  
Abdullah Kaplan
Keyword(s):  
Experimental Data ◽  
Cross Section ◽  
Production Cross Section ◽  
Gamma Ray ◽  
Production Cross ◽  
Level Density ◽  
Experimental Studies ◽  
Level Density Models ◽  
Strength Functions ◽  
Cancer Diseases

Abstract One of the methods used to treat different cancer diseases is the employment of therapeutic radioisotopes. Therefore, many clinical, theoretical and experimental studies are being carried out on those radioisotopes. In this study, the effects of level density models and gamma ray strength functions on the theoretical production cross-section calculations for the therapeutic radioisotopes 90Y, 153Sm, 169Er, 177Lu and 186Re in the (n,γ) route have been investigated. TALYS 1.9 code has been used by employing different level density models and gamma ray strength functions. The theoretically obtained data were compared with the experimental data taken from the literature. The results are presented graphically for better interpretation.

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