scholarly journals Sustainable Bio-methane generation from Petrochemical Wastewater using CSTR

Author(s):  
Md. Nurul Islam Siddique ◽  
Zularisham A. Wahid

The effect of gradual increase in organic loading rate (0LR) and temperature on biomethanation from petrochemical wastewater treatment was investigated using CSTR. The digester performance measured at hydraulic retention time (HRT) of4 to 2d, and start up procedure of the reactor was monitoredfor 60 days via chemical oxygen demand (COD) removal, biogas and methane production. By enhancing the temperature from 30 to 55 “C Thermophilic condition was attained, and pH was adjusted at 7 i 0.5. Supreme COD removal competence was 98i0.5% (r = 0.84) at an 0LR of 7.5 g-COD/Ld and 4d HRT. Biogas and methane yield were logged to an extreme of 0.80 L/g-CODremoved d (r = 0.81), 0.60 L/g-CODremoved d (r = 0.83), and mean methane content of biogas was 65.49%. The full acclimatization was established at 55 C with high COD removal efficiency and biogas production. An 0LR of 7.5 g-COD/L d and HRT of 4 days were apposite forpetrochemical wastewater treatment.

2006 ◽  
Vol 54 (2) ◽  
pp. 261-267 ◽  
Author(s):  
L. Borzacconi ◽  
I. López ◽  
M. Passeggi

An Imhoff tank was reconstructed into a 250 m3 UASB reactor in order to treat a malting plant wastewater. The UASB was inoculated with sludge from an anaerobic lagoon used for slaughterhouse wastewater treatment. After two months of operation the reactor achieved full load with an HRT of 17 h, a COD removal higher than 80% and a biogas production of 300 m3/day (77% average methane content), with an organic loading rate of 3.6 kgCOD/m3.d (0.24 kgCOD/kgVSS.d). A yield coefficient of 0.09 gVSS/gCODrem was found from a mass balance. The fat present in the inoculated sludge (48 mg/gSSV) did not affect the start up performance. Sludge from the inoculum with high content of fat (270 mg/gSSV), was separated by flotation in the first week of operation. The COD removal efficiency was scarcely influenced by the reactor operation temperature (17–25 °C).


The present study explores the feasibility of biogas production from dairy wastewater in the UAF reactor with simultaneous wastewater treatment. The study was carried out at different hydraulic retention times (8h, 12h, 16h, 24h). Two different media such as pebble stone media and aggregate media were used as the packed media. The maximum COD removal efficiency of 91.55 % is achieved at the hydraulic retention time of 24 Hours with an organic loading rate of 1.35 kg/m3 /d for aggregate media, whereas for pebble stone media a maximum COD removal efficiency of 76.32 % is achieved. Before the start of the experiments, the COD/BOD ratio is fixed to 1.4 with initial COD and BOD of 1350 mg/L and 960 mg/L. So, from the results it is concluded that the Upflow Anaerobic Filter (UAF) Reactor can be used as a one of the best treatment methods for the diary wastewater treatment.


1999 ◽  
Vol 40 (8) ◽  
pp. 229-236 ◽  
Author(s):  
F. Fdz-Polanco ◽  
M. D. Hidalgo ◽  
M. Fdz-Polanco ◽  
P. A. García Encina

In the last decade Polyethylene Terephthalate (PET) production is growing. The wastewater of the “Catalana de Polimers” factory in Barcelona (Spain) has two main streams of similar flow rate, esterification (COD=30,000 mg/l) and textile (COD=4000 mg/l). In order to assess the anaerobic treatment viability, discontinuous and continuous experiments were carried out. Discontinuous biodegradability tests indicated that anaerobic biodegradability was 90 and 75% for esterification and textile wastewater. The textile stream revealed some tendency to foam formation and inhibitory effects. Nutrients, micronutrients and alkali limitations and dosage were determined. A continuous lab-scale UASB reactor was able to treat a mixture of 50% (v) esterification/textile wastewater with stable behaviour at organic loading rate larger than 12 g COD/l.d (0.3 g COD/g VSS.d) with COD removal efficiency greater than 90%. The start-up period was very short and the recuperation after overloading accidents was quite fast, in spite of the wash-out of solids. From the laboratory information an industrial treatment plant was designed and built, during the start-up period COD removal efficiencies larger than 90% and organic loading rate of 0.6 kg COD/kg VSS.d (5 kg COD/m3.d) have been reached.


2021 ◽  
Vol 14 ◽  
pp. 51-57
Author(s):  
M.T. Jafarzadeh ◽  
N. Jamshidi ◽  
L. Talebiazar ◽  
R. Aslaniavali

Organic loading rate (OLR), Hydraulic Retention Time (HRT) and up flow velocity are important parameters significantly affecting microbial ecology and characteristics of anaerobic reactors. In this study, Performance of an anaerobic hybrid reactor (UASB/Filter) at mesophilic condition was evaluated in a 15.4 L reactor receiving petrochemical wastewater. The temperature of influent was adjusted by an inline heat exchanger at around 35 ˚C. The reactor was seeded with flocculent sludge from a UASB plant treating dairy wastewater. The sludge was acclimatized to petrochemical wastewater in twostage operation. After 39 weeks, a COD reduction of 70.3% was obtained at OLR=2.0 kg m-3 d-1 and HRT=18 h. Under steady state conditions, experiments were conducted at OLRs of between 0.5 and 24 kg TCOD m-3 d-1 , hydraulic retention times (HRT) of 4-48 h and up flow velocities 0.021-0.25 m h-1. Removal efficiencies in the range of 42-86% were achieved at feed TCOD concentrations of 1000- 4000 mg L-1 . The biogas production data used for determination of biogas production kinetics. The values of Gmax and GB estimated as 11.173 LL-1d -1 and 85.83 g L-1d -1 , respectively.


2012 ◽  
Vol 9 ◽  
pp. 57-62
Author(s):  
Fiza Sarwar ◽  
Wajeeha Malik ◽  
Muhammad Salman Ahmed ◽  
Harja Shahid

Abstract: This study was designed using actual effluent from the sugary mills in an Up-flow Anaerobic Sludge Blanket (UASB) Reactor to evaluate treatability performance. The reactor was started-up in step-wise loading rates beginning from 0.05kg carbon oxygen demand (COD)/m3-day to 3.50kg-COD/m3-day. The hydraulic retention time (HRT) was slowly decreased from 96 hrs to eight hrs. It was observed that the removal efficiency of COD of more than 73% can be easily achieved at an HRT of more than 16 hours corresponding to an average organic loading rate (OLR) of 3.0kg-COD/m3-day, at neutral pH and constant temperature of 29°C. The average VFAs (volatile fatty acids) and biogas production was observed as 560mg/L and 1.6L/g-CODrem-d, respectively. The average methane composition was estimated as 62%. The results of this study suggest that the treatment of sugar mills effluent with the anaerobic technology seems to be more reliable, effective and economical.DOI: http://dx.doi.org/10.3126/hn.v9i0.7075 Hydro Nepal Vol.9 July 2011 57-62


Energies ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2392 ◽  
Author(s):  
Marcin Dębowski ◽  
Marcin Zieliński ◽  
Marta Kisielewska ◽  
Joanna Kazimierowicz

The aim of this study was the performance evaluation of anaerobic digestion of dairy wastewater in a multi-section horizontal flow reactor (HFAR) equipped with microwave and ultrasonic generators to stimulate biochemical processes. The effects of increasing organic loading rate (OLR) ranging from 1.0 g chemical oxygen demand (COD)/L·d to 4.0 g COD/L·d on treatment performance, biogas production, and percentage of methane yield were determined. The highest organic compounds removals (about 85% as COD and total organic carbon—TOC) were obtained at OLR of 1.0–2.0 g COD/L·d. The highest biogas yield of 0.33 ± 0.03 L/g COD removed and methane content in biogas of 68.1 ± 5.8% were recorded at OLR of 1.0 g COD/L·d, while at OLR of 2.0 g COD/L·d it was 0.31 ± 0.02 L/COD removed and 66.3 ± 5.7%, respectively. Increasing of the OLR led to a reduction in biogas productivity as well as a decrease in methane content in biogas. The best technological effects were recorded in series with an operating mode of ultrasonic generators of 2 min work/28 min break. More intensive sonication reduced the efficiency of anaerobic digestion of dairy wastewater as well as biogas production. A low nutrient removal efficiency was observed in all tested series of the experiment, which ranged from 2.04 ± 0.38 to 4.59 ± 0.68% for phosphorus and from 9.67 ± 3.36 to 20.36 ± 0.32% for nitrogen. The effects obtained in the study (referring to the efficiency of wastewater treatment, biogas production, as well as to the results of economic analysis) proved that the HFAR can be competitive to existing industrial technologies for food wastewater treatment.


1992 ◽  
Vol 26 (9-11) ◽  
pp. 2381-2384 ◽  
Author(s):  
C. Polprasert ◽  
S. Kessomboon ◽  
W. Kanjanaprapin

Small-scale and pilot-scale experiments were conducted on pig wastewater treatment in water hyacinth (Eichhornia crassipesl ponds. The main objectives were to evaluate the treatment performance of the water hyacinth ponds and to determine suitable operating conditions. From the experimental results obtained, the optimum organic loading rate was found to be 200 kg COD/(ha.d), while the hydraulic retention times were proposed to be 10-20 days. The % COD removal in the small-scale water hyacinth ponds were 74-93, while for the pilot-scale ponds the % COD removal were 52-72 because of fluctuations in the influent wastewater characteristics and occasional insect attacks on the water hyacinth leaves and stems. Similar results were obtained for N removal. Although the water hyacinth ponds were found to be feasible for pig wastewater treatment, at least one polishing pond in series should be provided to polish the water hyacinth pond effluents before discharging into the environment.


2020 ◽  
Author(s):  
Sohail Khan ◽  
Fuzhi Lu ◽  
Qiong Jiang ◽  
Chengjian Jiang ◽  
Muhammad Kashif ◽  
...  

Abstract Background Molasses is a highly dense and refined byproduct produced in the sugarcane industry, and it contains high amounts of degradable compounds. These compounds can potentially be converted into renewable products biologically. However, the involved biological process is negatively influenced by the high chemical oxygen demand (COD) of molasses and its high ion concentration, although this problem is commonly addressed by dilutions. Results The co-digestion of molasses with rice alcohol waste water (RAW) was compared with its mono-digestion at an increasing organic loading rate (OLR). Both processes were assessed by detecting the COD removal rate, the methane contents of biogas, and the structure and composition of microbial communities at different stages. Results showed that the co-digestion is stable up to a maximum OLR of 16 g COD L− 1d− 1. By contrast, after the acclimatization phase, the mono-digestion process was upset twice, which occurred at a maximum OLR of 9 and 10 g COD L− 1d− 1. The co-digestion procgess demonstrated consistency in terms of COD removal rates (86.36% ± 0.99–90.72% ± 0.63%) and methane contents (58.10% ± 1.12–64.47% ± 0.59%) compared with the mono-digestion process. Microbial community analysis showed that the relative abundance of bacterial and archaeal communities differs between the processes at different stages. However, in both processes, Propionibacteriaceae was the most abundant family in the bacterial communities, whereas Methanosaetaceae was abundant in the archaeal communities. Conclusion Rice alcohol wastewater could be a good co-substrate for anaerobic digestion of molasses. Integrate molasses into progressive biogas production at high OLR.


Author(s):  
Javkhlan Ariunbaatar ◽  
Robert Bair ◽  
Onur Ozcan ◽  
Harish Ravishankar ◽  
Giovanni Esposito ◽  
...  

Anaerobic digestion of food waste (FW) is typically limited to large reactors due to high hydraulic retention times (HRTs). Technologies such as anaerobic membrane reactors (AnMBRs) can perform anaerobic digestion at lower HRTs while maintaining high chemical oxygen demand (COD) removal efficiencies. This study evaluated the effect of HRT and organic loading rate (OLR) on the stability and performance of a side-stream AnMBR in treating diluted fresh food waste (FW). The reactor was fed with synthetic FW at an influent concentration of 8.24 (± 0.12) g COD/L. The OLR was increased by reducing the HRT from 20 to 1 d. The AnMBR obtained an overall removal efficiency of >97 and >98% of the influent COD and total suspended solids (TSS), respectively, throughout the course of operation. The biological process was able to convert 76% of the influent COD into biogas with 70% methane content, while the cake layer formed on the membrane gave an additional COD removal of 7%. Total ammoniacal nitrogen (TAN) and total nitrogen (TN) concentrations were found to be higher in the bioreactor than in the influent, and average overall removal efficiencies of 17.3 (± 5) and 61.5 (± 3)% of TAN and TN, respectively, were observed with respect to the bioreactor concentrations after 2 weeks. Total phosphorus (TP) had an average removal efficiency of 40.39 (± 5)% with respect to the influent. Membrane fouling was observed when the HRT was decreased from 7 to 5 d and was alleviated through backwashing. This study suggests that the side-stream AnMBR can be used to successfully reduce the typical HRT of wet anaerobic food waste (solids content 7%) digesters from 20 days to 1 day, while maintaining a high COD removal efficiency and biogas production.


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