scholarly journals Effect of pre-treatments and additives on the improvement of cement wood composite: A review

BioResources ◽  
2020 ◽  
Vol 15 (3) ◽  
pp. 7288-7308
Author(s):  
Fatima Z. Brahmia ◽  
Péter György Horváth ◽  
Tibor L. Alpár

Cement wood composites (CWC) are a popular construction material. Lightweight or panel-wise wood-based buildings have a growing market in central Europe. Requirements and regulations on both the global and national level are forcing continuous developments. This paper summarizes the research achievements in improving the hygroscopic and mechanical properties and shortening the manufacturing time of CWC via pre-treatments and additives. In addition, new perspectives on enhancing its fire resistance properties by using fire retardant pre-treatments are discussed. CWC without any pre-treatment is a material within the B-s1, d0 category of fire resistance. Using fire retardants could upgrade it to the category A1 but the fire retardants should not affect the primary properties of CWC. There are a number of potential fire retardants of wood that may be used, such as phosphorus, boron, and magnesium compounds.

BioResources ◽  
2020 ◽  
Vol 15 (4) ◽  
pp. 8235-8248
Author(s):  
Se-Hwi Park ◽  
Min Lee ◽  
Eun-Chang Kang ◽  
Sang-Min Lee ◽  
Kugbo Shim

Fire-retardant performance was imparted to the existing wood-fiber insulation boards (WIB) via internal and external treatment with silica- and phosphorus-based fire-retardants. The combustion and smoke characteristics were investigated using a cone calorimeter. Based on combustion for 600 s, the weight loss and shrinkage of WIBs decreased due to fire-retardant treatment. The time to ignition was delayed to more than 400 s on the WIBs treated internal and external fire- retardant (WIB-IEs), whereas that of WIB with only internal treatment (WIB-I) was 5 s. The overall heat release rate (HRR), HRRpeak, and total heat release (THR) of WIB-IE specimens decreased, and the fire resistance standard Class II was satisfied. The WIB-IE2 showed higher fire resistance performance, with a HRRmean level of 6.7 kW/m2 and a THR of 1.3 MJ/m2. The WIB-I showed extremely low total smoke release (TSR) compared to the external fire-retardant treated specimen. However, the externally treated WIB-IEs had an increased TSR of 165 to 256 m2/m2 due to the increase in incomplete combustion caused by the fire-retardant. After fire-retardant treatment, CO2 generation decreased because the rate of complete combustion decreased, but CO emission increased slightly. Therefore, silica- and phosphorus-based fire-retardants by internal and external treatments were suitable for WIBs.


BioResources ◽  
2014 ◽  
Vol 9 (4) ◽  
pp. 7941-7950
Author(s):  
Siti Noorbaini Sarmin ◽  
Johannes Welling ◽  
Andreas Krause ◽  
Ali Shalbafan

Wood-based composites are widely used in consumer products, either in structural or non-structural applications. One of the basic elements for wood-based composites is the binder itself. Recent years have seen great development and trends in the field of eco-friendly binders in wood-based composite. There have been many concerns on the effects of formaldehyde and volatile organic compounds (VOC) released from wood-based products. Researchers have put lot of effort into developing environmental friendly products with enhanced sustainability. Binder materials with a focus on geopolymers (i.e., alumino-silicates) are discussed in this publication. The development and utilization of geopolymeric binders is relatively new in the field of wood-based composites. Up to the present there has been insufficient information regarding the manufacturing conditions and properties of wood-nonwood composite materials prepared using a geopolymeric binder. This paper considers the background of geopolymer materials and the possibilities of producing inorganic-bonded wood composite using geopolymer.


2016 ◽  
Vol 674 ◽  
pp. 277-282 ◽  
Author(s):  
Harri Lipiäinen ◽  
Qian Chen ◽  
Juha Larismaa ◽  
Simo Pekka Hannula

Unsaturated polyester resins (UPRs) are most commonly used coating materials on steel among thermosetting polymers because of their low cost, easy application and good performance properties. However, UPRs show insufficient fire-resistance in respect of relatively high flammability accompanied by smoke production upon burning due to aromatic groups in the structure. Consequently, improving the fire retardancy of UPRs for extending their application becomes pivotal. Fire retardants (FRs) are widely used in polymers because they prolong the time to ignition, slow down the rate of flame spread, and generate less heat and smoke or toxic fume compared with the unmodified polymers. It has been a challenge to develop a cost effective, environmentally friendly fire retardant system which minimizes the negative effect on performance properties of the polymers [1 - 4].


2005 ◽  
pp. 111-124
Author(s):  
Jovan Miljkovic ◽  
Ivana Grmusa ◽  
Milanka Djiporovic ◽  
Zorica Kacarevic-Popovic

Rising demands for fire resistance properties of wood construction and elements matching new standards have been an important part of building codes during the last decade. On the other side, lack of more detailed research on interaction between wood species and selected fire retardant chemicals even with basically one is evident. This is particularly truth with domestic wood species. In this research, beech and poplar veneers were immersed in 25% solutions of monoammonium phosphate (MP) and sodium acetate (SA) and impregnated for different periods of time. To determine the preliminary level of fire retardancy achieved in veneers before manufacturing of finished plywood, thermo gravimetric (TG) and derivative thermo gravimetric (DTG) methods were used. TG and DTG analyses of treated and untreated wood, as well as of fire retardants alone, were performed. The next properties of impregnated and no impregnated veneers and plywood were determined: absorption of imp regnant solution (A), weight percent gain (WPG) of imp regnant, equilibrium moisture content (EMC), pH values, and in the case of plywood, strength and fire resistance. Fire resistance of plywood was tested in accordance with standard test for resistance to the effects of fire and the most efficient fire retardant, monoammonium phosphate, had the same result as TG/DTG analyses, which pointed out the validity of TG methods in predicting fire resistance of future products.


2021 ◽  
Vol 11 (6) ◽  
pp. 2521
Author(s):  
Feng Jiang ◽  
Jianyong Liu ◽  
Wei Yuan ◽  
Jianbo Yan ◽  
Lin Wang ◽  
...  

Improving the fire resistance of the key cables connected to firefighting and safety equipment is of great importance. Based on the engineering practice of an oil storage company, this study proposes a modification scheme that entails spraying fire-retardant coatings on the outer surface of a cable tray to delay the failure times of the cables in the tray. To verify the effect, 12 specimens were processed using five kinds of fire-retardant coatings and two kinds of fire-resistant cotton to coat the cable tray. The specimens were installed in the vertical fire resistance test furnace. For the ISO 834 standard fire condition, a fire resistance test was carried out on the specimens. The data for the surface temperature and the insulation resistance of the cables in trays were collected, and the fireproof effect was analyzed. The results showed that compared with the control group, the failure time of the cable could be delayed by 1.57–14.86 times, and the thicker the fire-retardant coatings were, the better the fireproof effect was. In general, the fire protection effect of the fire-retardant coating was better than that of the fire-resistant cotton.


2021 ◽  
Vol 30 (4) ◽  
pp. 36-47
Author(s):  
O. S. Lebedchenko ◽  
S. V. Puzach ◽  
V. I. Zykov

Introduction. The reliable operation of safety systems, that allows for the failure of no more than one safety system component, entails the safe shutdown and cool-down of an NPP reactor in the event of fire. However, the co-authors have not assessed the loss of performance by an insulating material, treated by intumescent compositions and used in the power cables of the above safety systems exposed to the simultaneous effect of various modes of fire and current loads.Goals and objectives. The purpose of the article is the theoretical assessment of the application efficiency of intumescent fire-retardant coatings in power cables used in the safety systems of nuclear power plants having water-cooled and water-moderated reactors under fire conditions. To achieve this goal, the temperature of the outer surface of the insulation and the intumescent fire-retardant coating was analyzed depending on the mode of fire. Theoretical foundations. A non-stationary one-dimensional heat transfer equation is solved to identify the temperature distribution inside the multilayered insulation and the fire-protection layer of a conductive core.Results and their discussion. The co-authors have identified dependences between the temperature of the outer surface of the insulation and the fire retarding composition of the three-core cable VVGng (A)-LS 3x2.5-0.66, on the one hand, and the temperature of the indoor gas environment for three standard modes of fire and one real fire mode. It is found that before the initiation of the process of destruction of the insulation material, the intumescence of the fire-retardant coating occurs only in case of a hydrocarbon fire. Under real fire conditions, the maximal insulation melting time before the initiation of intumescence of the fire-retardant coating at the minimal temperature of intumescence is 4.75 minutes, while the maximal time period from the initiation of destruction of the insulation material to the moment of the insulation melting is 6.0 minutes.Conclusions. An experimental or theoretical substantiation of parameters of intumescent fire retardants, performed using standard modes of fire, has proven the potential loss of operational properties by insulating materials of power cables, used in the safety systems of nuclear power plants, in case of a real fire. Therefore, it is necessary to establish a scientific rationale for the efficient use of fire retardants in the above cables with regard for the conditions of a real fire.


2020 ◽  
Vol 2020 (2) ◽  
pp. 64-69
Author(s):  
I Khaidarov ◽  
◽  
R Ismailov

This article presents studies of fire resistance in the treatment of expanded vermiculite, which depends on the size of the dispersed particles and the orientation of the granules, their moisture and temperature. It has been studied that one of the interesting and important in practice properties of vermiculite is its ability to swell and turn into a lightweight effective material for imparting fire resistance. The properties and compositions of vermiculite from the Tebinbulak deposit are studied, from which a flame-retardant suspension is prepared for processing textile materials based on vermiculite dissolved in orthophosphoric acid and alkali in an aqueous medium. When modifying materials with developed flame-retardant suspensions, it is possible to obtain fire-resistant textile materials that meet the requirements of GOST for fire resistance, smoke generation and other physical and mechanical properties.


2007 ◽  
Vol 336-338 ◽  
pp. 1753-1755
Author(s):  
Ya Dong Yao ◽  
Guang Fu Yin ◽  
Xiao Wei Cheng ◽  
Xiang Li Gou

Silicate fireproof coatings for tunnels (FCT) have many eminent properties. But low adhesion strength and poor water/fire-resistance of this kind of materials largely limit its applications. Here we reported a new kind of FCT based on high alumina cement as principle adhesive, redispersible powder as assisting adhesive, ammonium polyphosphate as fire-retardant material, vermiculite as adiabatic padding, and magnesium hydroxide as assisting reagents. The influence of various experimental conditions on fire resistance, adhesion strength and water resistance were carefully studied. Results showed that dispersible emulsoid powder was a key component affecting adhesion strength and water resistance of FCT, whereas fire-retardant material posed significant effects on the fire resistance.


Author(s):  
Yury Shebeko ◽  
Aleksey Shebeko ◽  
Andrey Zuban

Проанализирована взаимосвязь разброса значений пределов огнестойкости стальных конструкций со вспучивающимися огнезащитными покрытиями и соответствующего этому разбросу интервала толщины огнезащитного покрытия. Предложена методика, на основании которой может быть осуществлен выбор необходимой толщины огнезащитного покрытия в зависимости от заданных значений дисперсии предела огнестойкости и приведенной толщины конструкции при заданной доверительной вероятности.An analysis of a relationship between fire resistance limits scatter for steel structures coated with intumescent fire retardant coating and an appropriate interval of thicknesses of the coating was carried out. A methodology for the determination of this relationship was proposed. This methodology was tested on a practical example. A steel structure with a reduced thickness of 6 mm was considered. A typical dependence of the required thickness of the structure was taken into account. A ratio of a mean square deviation of the fire resistance limit to this limit was accepted to be equal 0.1. Using these values an appropriated interval of the thicknesses of the intumescent fire retardant coating was determined. This interval can be calculated for any given confidence level. Boundaries of this interval can be not symmetric in relation to the value of the normative thickness of the fire retardant coating. The proposed methodology can be used for the determination of the required thicknesses of the intumescent fire retardant coatings on steel structures for the given r value, reduced thickness of the structure and the confidence level.


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