Formation of ANFO Analogues under Fire Conditions in the Presence of Common Plastics

This article is a continuation of a case study in which we presented the results of research on processes generated under fire conditions by mixing molten ammonium nitrate (AN) with selected polymers. Here, we present an analysis of how certain materials, which may frequently appear in farm buildings and are commonly used in the immediate vicinity of humans, can potentially form explosives. The chosen materials include polyamides (PA) from which the wear-resistant machine elements are made (e.g., high-performance gears, wheels of transport trolleys); polyvinyl chloride (PVC) used, i.e., in construction carpentry, electrical insulation, and hydraulic pipes; polystyrene (PS) used, i.e., in insulation and containers; and poly(methyl methacrylate) (PMMA), i.e., so-called organic glass and plexiglass. The research results showed that these seemingly harmless and safe materials, mixed with AN and heated under fire conditions, may turn into explosives and stimulate stored AN. This creates significant risks of an uncontrolled fire progress.

Improving the robustness of steel frame structures under localised fire conditions

PurposeThe robustness of building structures in a fire has recently drawn wide attention. This study presents the progressive collapse analysis of steel frame building structures under localised fire. The main objective of this study is to propose methods to enhance the structural collapse resistance of such structures in fire.Design/methodology/approachA modelling method was developed and validated against both experimental and analytical studies. Then, a series of robustness analyses were performed to investigate the interaction among the members and the pattern of load distribution within the structures. These analyses show that lateral resistance and load redistribution have a vital role in the robustness of the building. Thus, two approaches have been adopted to enhance the robustness of the focused steel frame during a fire.FindingsIt is found that increased size of floor beams and vertical bracing systems are effective measures in preventing whole structure collapse. The larger beam section is able to prevent catenary action so that the load in the failed columns can safely transfer to the adjacent columns without buckling. On the other hand, the bracing system improves the lateral resistance that can accommodate the lateral force when catenary action occurs in the beam.Originality/valuePrevious studies have focused on the collapse mechanism of steel frame structures. However, the parameters affecting the structural robustness in a fire have not yet been explored. To address this gap, this study adopted numerical modelling to undertake parametric studies to identify effective methods to improve the robustness of such structures under fire conditions.

Splash Erosion on Terraces, Does It Make a Difference If the Terracing Is Done before or after a Fire?

Terraces are a common Mediterranean feature influencing soils, slopes and subsurface hydrology; however, little is known about their impact on erosion processes, especially in humid regions. The purpose of this study was to assess how terracing after a fire affected erosion processes such as splash erosion. For 8 months, the study monitored splash erosion in three terraced plots, one plot under pre-fire conditions and the other two under post-fire conditions. Assessment of the impact of the terracing treatment in such plots was carried out by the installation of two different splash erosion quantitative systems: cups and funnels. An analysis of the splash data obtained in 17 rainfall events and meteorological data collected during each one of those periods was then performed. A significant positive correlation between the amount of rainfall and the splash erosion was observed. The two splash sampling systems show a high degree of concordance; however, the funnel-type model seems to be the most appropriate when it comes to preventing loss of splashed soil samples. The post-fire treatment with terracing leads to a smaller stability of surface soil aggregates, causing higher splash erosion rates. Sampling using the funnel system collects three times the amount of splashed soil than that collected by the cup system, although both systems correlate appropriately with the meteorological parameters.

Integrating Remote and In-Situ Data to Assess the Hydrological Response of a Post-Fire Watershed

Forest fire is a common concern in Mediterranean watersheds. Fire-induced canopy mortality may cause the degradation of chemical–physical properties in the soil and influence hydrological processes within and across watersheds. However, the prediction of the pedological and hydrological effect of forest fires with heterogenous severities across entire watersheds remains a difficult task. A large forest fire occurred in 2017 in northern Italy providing the opportunity to test an integrated approach that exploits remote and in-situ data for assessing the impact of forest fires on the hydrological response of semi-natural watersheds. The approach is based on a combination of remotely-sensed information on burned areas and in-situ measurements of soil infiltration in burned areas. Such collected data were used to adapt a rainfall–runoff model over an experimental watershed to produce a comparative evaluation of flood peak and volume of runoff in pre- and post-fire conditions. The model is based on a semi-distributed approach that exploits the Soil Conservation Service Curve Number (SCS-CN) and lag-time methods for the estimation of hydrological losses and runoff propagation, respectively, across the watershed. The effects of fire on hydrological losses were modeled by adjusting the CN values for different fire severities. Direct infiltration measurements were carried out to better understand the effect of fire on soil infiltration capacity. We simulated the hydrological response of the burned watershed following one of the most severe storm events that had hit the area in the last few years. Fire had serious repercussions in regard to the hydrological response, increasing the flood peak and the runoff volume up to 125% and 75%, respectively. Soil infiltration capacity was seriously compromised by fire as well, reducing unsaturated hydraulic conductivity up to 75% compared with pre-fire conditions. These findings can provide insights into the impact of forest fires on the hydrological response of a whole watershed and improve the assessment of surface runoff alterations suffered by a watershed in post-fire conditions.

Fire performance of earthquake-damaged reinforced concrete columns: an experimental study

PurposeEarthquake tremors not only increase the chances of fire ignition but also hinder the fire-fighting efforts due to the damage to the lifelines of a city. Most of the international codes have independent recommendations for structural safety against earthquake and fire. However, the possibility of a multi-hazard event, such as fire following an earthquake is seldom addressed.Design/methodology/approachThis paper presents an experimental study of Reinforced Concrete (RC) columns in post-earthquake fire (PEF) conditions. An experimental approach is proposed that allows the testing of a column instead of a full structural frame. This approach allows us to control the loading and boundary conditions individually and facilitates the testing under a variety of these conditions. Also, it allows the structure to be tested until failure. The role of parameters, such as earthquake intensity, axial load ratio and the ductile detailing of the column on the earthquake damage and subsequently the fire performance of the structure, is studied in this research. Six RC column specimens are tested under a sequence of quasi-static earthquake loading, followed by combined fire and axial compression loading conditions.FindingsThe experiment results indicate that ductile detailed columns subjected to 4% or less lateral drift did not lose significant load-carrying capacity in fire conditions. A lateral drift of 6% caused significant damage to the columns and reduced the load-carrying capacity in fire conditions. The level of the axial load acting on the column at the time of earthquake loading was found to have a very significant effect on the extent of damage and reduction in column load capacity in fire conditions. The columns that were not detailed for a ductile behavior observed a more significant reduction in axial load carrying capacity in fire conditions.Research limitations/implicationsThis study is limited to columns of 230 mm size due to the limitations of the test setup. The applicability of these findings to larger column sections needs to be verified by developing a numerical analysis methodology and simulating other post-earthquake-fire tests available in the literature.Originality/valueThe experimental procedure proposed in this paper offers an alternative to the testing of a complete structural frame system for PEF behavior. In addition to the ease of conducting the tests, the procedure also allows much better control over the heating, structural loading and boundary conditions.

The application efficiency of intumescent coatings for power cables of safety systems of nuclear power plants under fire conditions

Introduction. The reliable operation of safety systems, that allows for the failure of no more than one safety system component, entails the safe shutdown and cool-down of an NPP reactor in the event of fire. However, the co-authors have not assessed the loss of performance by an insulating material, treated by intumescent compositions and used in the power cables of the above safety systems exposed to the simultaneous effect of various modes of fire and current loads.Goals and objectives. The purpose of the article is the theoretical assessment of the application efficiency of intumescent fire-retardant coatings in power cables used in the safety systems of nuclear power plants having water-cooled and water-moderated reactors under fire conditions. To achieve this goal, the temperature of the outer surface of the insulation and the intumescent fire-retardant coating was analyzed depending on the mode of fire. Theoretical foundations. A non-stationary one-dimensional heat transfer equation is solved to identify the temperature distribution inside the multilayered insulation and the fire-protection layer of a conductive core.Results and their discussion. The co-authors have identified dependences between the temperature of the outer surface of the insulation and the fire retarding composition of the three-core cable VVGng (A)-LS 3x2.5-0.66, on the one hand, and the temperature of the indoor gas environment for three standard modes of fire and one real fire mode. It is found that before the initiation of the process of destruction of the insulation material, the intumescence of the fire-retardant coating occurs only in case of a hydrocarbon fire. Under real fire conditions, the maximal insulation melting time before the initiation of intumescence of the fire-retardant coating at the minimal temperature of intumescence is 4.75 minutes, while the maximal time period from the initiation of destruction of the insulation material to the moment of the insulation melting is 6.0 minutes.Conclusions. An experimental or theoretical substantiation of parameters of intumescent fire retardants, performed using standard modes of fire, has proven the potential loss of operational properties by insulating materials of power cables, used in the safety systems of nuclear power plants, in case of a real fire. Therefore, it is necessary to establish a scientific rationale for the efficient use of fire retardants in the above cables with regard for the conditions of a real fire.