Dependence of Modulus and Hardness on the Annealing Conditions of Pt57.5Cu14.7Ni5.3P22.5 Bulk Metallic Glass

MRS Advances ◽  
2019 ◽  
Vol 4 (2) ◽  
pp. 73-79 ◽  
Author(s):  
Zheng Chen ◽  
Amit Datye ◽  
P. Aidan Brooks ◽  
Madison Sprole ◽  
Jittisa Ketkaew ◽  
...  

ABSTRACTThe mechanical properties of metallic glasses are often tuned by annealing, which influences these properties by adjusting the relaxation and/or crystallization status of the glasses. Here, we studied the hardness and modulus of Pt57.5Cu14.7Ni5.3P22.5 bulk metallic glass annealed at different temperatures by nanoindentation, where the annealing gives the material different fictive temperatures and fractions of crystallization. It is found that both reducing the fictive temperature of a fully amorphous sample and increasing the degree of crystallization in a partially crystallized sample increase hardness and modulus. Combining the two approaches, elevated hardness and modulus values are found for composite materials containing both crystalline and amorphous phases when they are compared to chemically identical alloys featuring similar percentages of crystalline and amorphous phases that have been prepared by annealing at higher temperatures. Our findings indicate that the mechanical properties of the platinum-based alloys can be customized by processing them with targeted heat treatments.

2010 ◽  
Vol 654-656 ◽  
pp. 1050-1053
Author(s):  
Min Ha Lee ◽  
Joong Hwan Jun ◽  
Jürgen Eckert

Mechanical treatments such as deep rolling are known to affect the strength and toughness of metallic glass due to the residual stress. It is well known that compressive residual stress states usually enhance the mechanical properties in conventional metallic materials. We present investigations on the change of fracture behavior related with mechanical properties of “brittle” bulk metallic glass by cold rolling at room temperature. Improvement of the intrinsic plasticity is observed not only after constrained cyclic compression but also after cold rolling. Moreover, neither nanocrystallization nor phase separation occurs during deformation. By these findings we provide a unique fundamental basis by considering the introduction of structural inhomogeneity and ductility improvement in metallic glasses. The experimental evidence clearly supports that such an inhomogeneous glassy can be produced by residual stress in well known “brittle” bulk metallic glasses, and does not depend on a specific pinpointed chemical composition.


2007 ◽  
Vol 561-565 ◽  
pp. 1345-1348 ◽  
Author(s):  
J. Kobata ◽  
Yorinobu Takigawa ◽  
Sung Wook Chung ◽  
Hiroshi Tsuda ◽  
Tokuteru Uesugi ◽  
...  

Microstructure and mechanical properties in friction stir processed (FSPed) Zr-based bulk metallic glass were investigated. The microstructure in the friction zone (FZ) exhibits an amorphous “band-like” structure with a small number of nanoscale crystalline particles. On the other hand, the microstructure in the FZ near the finish point of the process exhibits a large number of nanocrystalline particles in size of less than 20nm and amorphous phase. The difference of the microstructure in each FSP region is explained from the difference of the heat input by FSP. The hardness in each FSPed region shows higher value compared with that of other Zr-based balk metallic glasses with almost the same volume fraction of crystalline phase.


2011 ◽  
Vol 66-68 ◽  
pp. 741-746
Author(s):  
Jia Hua Zou ◽  
Zhi Chen Zhang ◽  
Shu Quan Sun

In the present study, the Zr-Cu-Ni-Al based bulk metallic glasses with different Ti addition was successfully prepared by suction casting . It was found that the glass forming ability was improved with increasing of Ti content from 3 at.% to 7 at.%. However, with increasing of Ti content, the room-temperature plasticity decreased from 4.33% to 0.66 %.


2016 ◽  
Vol 5 (1) ◽  
Author(s):  
Shuaidan Lu ◽  
Shuchen Sun ◽  
Xiaoxiao Huang ◽  
Xiaoping Zhu ◽  
Ganfeng Tu ◽  
...  

AbstractZr-based bulk metallic glass possesses the highest potential as a structural material among metallic glasses. However, the production conditions have a great effect on its glass-forming ability (GFA) and mechanical characteristics. In this paper, an attempt was made to find the effect of a hereditary structure on the GFA and mechanical properties of a solid Zr


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2815
Author(s):  
Yu Hang Yang ◽  
Jun Yi ◽  
Na Yang ◽  
Wen Liang ◽  
Hao Ran Huang ◽  
...  

Bulk metallic glasses have application potential in engineering structures due to their exceptional strength and fracture toughness. Their fatigue resistance is very important for the application as well. We report the tension-tension fatigue damage behavior of a Zr61Ti2Cu25Al12 bulk metallic glass, which has the highest fracture toughness among BMGs. The Zr61Ti2Cu25Al12 glass exhibits a tension-tension fatigue endurance limit of 195 MPa, which is higher than that of high-toughness steels. The fracture morphology of the specimens depends on the applied stress amplitude. We found flocks of shear bands, which were perpendicular to the loading direction, on the surface of the fatigue test specimens with stress amplitude higher than the fatigue limit of the glass. The fatigue cracking of the glass initiated from a shear band in a shear band flock. Our work demonstrated that the Zr61Ti2Cu25Al12 glass is a competitive structural material and shed light on improving the fatigue resistance of bulk metallic glasses.


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