Highly oriented, textured diamond films on silicon via bias-enhanced nucleation and textured growth

1993 ◽  
Vol 8 (6) ◽  
pp. 1334-1340 ◽  
Author(s):  
B.R. Stoner ◽  
S.R. Sahaida ◽  
J.P. Bade ◽  
P. Southworth ◽  
P.J. Ellis
Keyword(s):  
Silicon Surface ◽  
Diamond Films ◽  
Single Crystal Silicon ◽  
Film Surface ◽  
Potential Effect ◽  
Structural Defects ◽  
Silicon Substrates ◽  
Electrical Characteristics ◽  
Crystal Silicon ◽  
Nucleation Stage

Highly oriented diamond films were grown on single-crystal silicon substrates. Textured films were first nucleated by a two-step process that involved the conversion of the silicon surface to an epitaxial SiC layer, followed by bias-enhanced nucleation. The nucleation stage, which produced a partially oriented diamond film, was immediately followed by a (100) textured growth process, thus resulting in a film surface where approximately 100% of the grains are epitaxially oriented relative to the silicon substrate. The diamond films were characterized by both SEM and Raman spectroscopy. Structural defects in the film are discussed in the context of their potential effect on the electrical characteristics of the resulting film.

scholarly journals Влияние адсорбированных молекул СО на электронное состояние нанопленок иттербия, выращиваемых на кремниевых подложках

2019 ◽  
Vol 89 (7) ◽  
pp. 1086
Author(s):  
М.В. Кузьмин ◽  
М.А. Митцев
Keyword(s):  
Carbon Monoxide ◽  
Single Crystal ◽  
Single Crystal Silicon ◽  
Film Surface ◽  
Electronic Configuration ◽  
Surface Orientation ◽  
Silicon Substrates ◽  
Crystal Silicon ◽  
Adsorption Of Co ◽  
Gas Molecules

Adsorption of carbon monoxide (CO) molecules on ytterbium nanofilms with the thickness of 16 – 200 monolayers (6.1 – 76 nm) has been studied. The films are grown on single-crystal silicon substrates with the (111) surface orientation. It is shown that before the adsorption of CO molecules, ytterbium is divalent with the electronic configuration of [Xe]4f146s2. Upon the adsorption of gas molecules, a layer of trivalent ytterbium (the electronic configuration is [Xe]4f135d16s2), which is adjacent to the film surface, is formed. Evaluations of the thickness of the layer modified by adsorbed CO molecules are performed. Such evaluations have given rise to the values within 9 – 22 monolayers (3.4 – 8.4 nm).

Determination of the Optical & Materials Properties of βFeSi2 Layers Fabricated Using Ion Beam Synthesis

1992 ◽  
Vol 260 ◽  
Author(s):  
T. D. Hunt ◽  
K. J. Reeson ◽  
R. M. Gwilliam ◽  
K. P. Homewood ◽  
R. J. Wilson ◽  
...  
Keyword(s):  
Silicon Surface ◽  
Optical Materials ◽  
Ion Beam ◽  
Dose Range ◽  
Single Crystal Silicon ◽  
Silicon Substrates ◽  
Crystal Silicon ◽  
Materials Properties ◽  
High Temperature Anneal

ABSTRACTIBS of buried α and β iron suicide layers was achieved by the implantation of 2 MeV 56Fe+ ions into (100) single crystal silicon substrates over a dose range of 3 × 1017 to 1 × 1018 cm“-2followed by a high temperature anneal. No photoluminescence was observed from the as-implanted samples which contained a discontinuous layer of βFeSi2 precipitates approximately 1.5 μm below the silicon surface. Upon annealing at 700°C, a 200 nm polycrystalline βFeSi2 layer was formed which gave a PL signal centred at 1.55 μm. After a 900°C anneal, the layer transformed to αFeSix with a resistivity of approximately 280μΩcm.

TEM characterization of Au/Polysilicon interactions

1990 ◽  
Vol 48 (4) ◽  
pp. 650-651
Author(s):  
N. David Theodore ◽  
Leslie H. Allen ◽  
C. Barry Carter ◽  
James W. Mayer
Keyword(s):  
Solid Phase ◽  
Single Crystal Silicon ◽  
Chemical Vapor ◽  
Electrical Contacts ◽  
Silicon Substrates ◽  
Crystal Silicon ◽  
Transmission Electron ◽  
Polysilicon Films ◽  
The Stability

Metal/polysilicon investigations contribute to an understanding of issues relevant to the stability of electrical contacts in semiconductor devices. These investigations also contribute to an understanding of Si lateral solid-phase epitactic growth. Metals such as Au, Al and Ag form eutectics with Si. reactions in these metal/polysilicon systems lead to the formation of large-grain silicon. Of these systems, the Al/polysilicon system has been most extensively studied. In this study, the behavior upon thermal annealing of Au/polysilicon bilayers is investigated using cross-section transmission electron microscopy (XTEM). The unique feature of this system is that silicon grain-growth occurs at particularly low temperatures ∽300°C).Gold/polysilicon bilayers were fabricated on thermally oxidized single-crystal silicon substrates. Lowpressure chemical vapor deposition (LPCVD) at 620°C was used to obtain 100 to 400 nm polysilicon films. The surface of the polysilicon was cleaned with a buffered hydrofluoric acid solution. Gold was then thermally evaporated onto the samples.

A Current Conduction Mechanism in Laser Recrystallized Silicon Metal-Oxide-Semiconductor Transistors

1983 ◽  
Vol 23 ◽  
Author(s):  
Han-Sheng Lee
Keyword(s):  
Conduction Mechanism ◽  
Single Crystal Silicon ◽  
Silicon Films ◽  
Oxide Semiconductor ◽  
Silicon Substrates ◽  
Mos Transistors ◽  
Crystal Silicon ◽  
Ion Laser ◽  
Argon Ion ◽  
A Current

ABSTRACTN-channel MOS transistors were fabricated on silicon films that had been recrystallized by an argon ion laser at different power levels. These transistors showed electrical characteristics similar, but somewhat inferior to those devices fabricated on single crystal silicon substrates. These differences are attributed to the presence of trapping states at the grain boundaries of the crystallites in the recrystallized silicon. A coulombic scattering model is presented to explain these differences. In the case of films annealed at low laser power, an additional factor of nonuniform trap state distribution is invoked to explain device characteristics. This model provides an adequate explanation for the observed transport properties of transistors fabricated from recrystallized silicon films.

Formation of ultrathin iron silicide layers on the single-crystal silicon surface

2006 ◽  
Vol 48 (10) ◽  
pp. 2016-2020 ◽  
Author(s):  
M. V. Gomoyunova ◽  
D. E. Malygin ◽  
I. I. Pronin
Keyword(s):  
Single Crystal ◽  
Silicon Surface ◽  
Iron Silicide ◽  
Single Crystal Silicon ◽  
Crystal Silicon

Laser Writing of High Purity Gold Lines

1989 ◽  
Vol 158 ◽  
Author(s):  
M. Jubber ◽  
J.I.B. Wilson ◽  
J.L. Davidson ◽  
P. John ◽  
P.G. Roberts
Keyword(s):  
Rectangular Cross Section ◽  
Single Crystal Silicon ◽  
Gold Surface ◽  
Decomposition Temperature ◽  
Silicon Substrates ◽  
Beam Diameter ◽  
Scanning Calorimetry ◽  
Crystal Silicon ◽  
Ion Laser ◽  
Stage Process

ABSTRACTGold tracks have been deposited on thermally oxidised and single crystal silicon, gold and nichrome coated silicon wafers by pyrolytic decomposition of gaseous alkyl (triethyl phosphine) gold(I) complexes using focussed 514 nm radiation from an argon ion laser. The precursors, RAu(I)Et3P, R = CH3, C2H5 are low melting point crystalline solids with relatively high vapour pressures (∼5 mtorr). They are representative of a class of compounds being evaluated for laser deposition of gold. Differential scanning calorimetry, DSC, shows that the thermal decomposition of MeAu(I)Et3P in the solid state is a two-stage process. The decomposition temperature is 63 ± 1°C. Tracks were deposited at laser scan speeds up to 35 μm s−1 with a beam diameter (1/e2) at the focus of ∼12 μm. SIMS, EDX and laser ionisation microprobe analysis, LIMA, were used to determine the chemical composition of the tracks. The purity of >98% is consistent with the measured resistivities (4.2 μΩ cm) at room temperature compared to bulk gold (∼2 μΩ cm). These resistivities were achieved without post deposition annealing. Stylus profilimetry and SEM data showed the lines produced from MeAu(I)Et3P have a virtually rectangular cross-section. Together with the absence of the ubiquitous λ-ripples, this feature suggests that deposition is more rapid on the gold surface than on the SiO2 substrate. Laser power thresholds are lower for silicon substrates coated with thin (5 - 10°A) films of gold or nichrome.

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