Raman Scatteringl And Infrared Absorption in Lithium Intercalated MoS2
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AbstractRaman scattering and IR absorption were studied in Li-intercalated MoS2 at room temperature. After intercalation, new Raman peaks were observed at low-frequency sides of the high-frequency original Raman peaks and around a rigid-layer mode. This fact indicates the formation of superlattice structure along the c-axis. An intercalation mode in which Li atoms vibrate strongly against the host lattice was observed at about 205 cm−1. Two new broad bands grow in the high-frequency region as the concentration of Li increases. The corresponding peaks were observed by IR absorption. They appears to be caused by vibrations of substitutional defects, in which the Li atoms have substituted for Mo atoms in the host lattice.
2007 ◽
Vol 280-283
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pp. 919-924
2014 ◽
Vol 618
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pp. 519-522
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2013 ◽
Vol 357-360
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pp. 1206-1211
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2003 ◽
Vol 03
(01)
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pp. L51-L61
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