Monitoring of Process of Ion Transport in Nonstoichiometric Fluorides with the LaF3 Structure

1994 ◽  
Vol 369 ◽  
Author(s):  
Nikolay I. Sorokin ◽  
Boris P. Sobolev
Keyword(s):  
Ion Transport ◽  
Rare Earths ◽  
Chemical Sensors ◽  
Solid Electrolytes ◽  
Electrical Response ◽  
Important Class ◽  
Transport Parameters ◽  
Ionic Conductors ◽  
Structure Form ◽  
Type Crystal

AbstractFluoride compounds with the tysonite (LaF3- type) crystal structure form an important class of materials which find diverse technological applications as fast ionic conductors. The results of investigations of the ionic conductivity process within tysonite structured R1-xMxF3-x single crystals (R=rare earths and M=alkali-rare earths) are presented using various techniques of electrical response spectroscopy. Influence of isomorphic substitutions of iso- and heterovalent cations on ion transport parameters was studied. By monitoring the composition of nonstoichiometric R1-xMxF3-x. crystals we can vary fluorine-ion conductivity within the range 10−7 - 10−4 S/cm at 293 K and 10−4 - 10−2 S/cm at 500 K. The studied nonstoichiometric crystals with the LaF3-structure are promising solid electrolytes which can be used in chemical sensors and fluorine generators.

How Certain Are the Reported Ionic Conductivities of Thiophosphate-Based Solid Electrolytes? an Interlaboratory Study

2020 ◽  
Author(s):  
Saneyuki Ohno ◽  
Tim Bernges ◽  
Johannes Buchheim ◽  
Marc Duchardt ◽  
Anna-Katharina Hatz ◽  
...  
Keyword(s):  
Standard Deviation ◽  
Ionic Conductivity ◽  
Relative Standard Deviation ◽  
Solid Electrolytes ◽  
Ionic Conductivities ◽  
Ionic Conductors ◽  
Energy Storage Devices ◽  
Activation Barriers ◽  
Storage Devices ◽  
Relative Standard

<p>Owing to highly conductive solid ionic conductors, all-solid-state batteries attract significant attention as promising next-generation energy storage devices. A lot of research is invested in the search and optimization of solid electrolytes with higher ionic conductivity. However, a systematic study of an <i>interlaboratory reproducibility</i> of measured ionic conductivities and activation energies is missing, making the comparison of absolute values in literature challenging. In this study, we perform an uncertainty evaluation via a Round Robin approach using different Li-argyrodites exhibiting orders of magnitude different ionic conductivities as reference materials. Identical samples are distributed to different research laboratories and the conductivities and activation barriers are measured by impedance spectroscopy. The results show large ranges of up to 4.5 mScm<sup>-1</sup> in the measured total ionic conductivity (1.3 – 5.8 mScm<sup>-1</sup> for the highest conducting sample, relative standard deviation 35 – 50% across all samples) and up to 128 meV for the activation barriers (198 – 326 meV, relative standard deviation 5 – 15%, across all samples), presenting the necessity of a more rigorous methodology including further collaborations within the community and multiplicate measurements.</p>

scholarly journals Structural, Electrical and Electrochemical Properties of Glycerolized Biopolymers Based on Chitosan (CS): Methylcellulose (MC) for Energy Storage Application

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1183
Author(s):  
Shujahadeen B. Aziz ◽  
Ahmad S. F. M. Asnawi ◽  
Mohd Fakhrul Zamani Kadir ◽  
Saad M. Alshehri ◽  
Tansir Ahamad ◽  
...  
Keyword(s):  
Energy Storage ◽  
Ion Transport ◽  
Ammonium Thiocyanate ◽  
Transference Number ◽  
Ionic Mobility ◽  
Transport Parameters ◽  
Ionic Transference Number ◽  
Energy Storage Application ◽  
Electrochemical Double Layer ◽  
Ion Conducting

In this work, a pair of biopolymer materials has been used to prepare high ion-conducting electrolytes for energy storage application (ESA). The chitosan:methylcellulose (CS:MC) blend was selected as a host for the ammonium thiocyanate NH4SCN dopant salt. Three different concentrations of glycerol was successfully incorporated as a plasticizer into the CS–MC–NH4SCN electrolyte system. The structural, electrical, and ion transport properties were investigated. The highest conductivity of 2.29 × 10−4 S cm−1 is recorded for the electrolyte incorporated 42 wt.% of plasticizer. The complexation and interaction of polymer electrolyte components are studied using the FTIR spectra. The deconvolution (DVN) of FTIR peaks as a sensitive method was used to calculate ion transport parameters. The percentage of free ions is found to influence the transport parameters of number density (n), ionic mobility (µ), and diffusion coefficient (D). All electrolytes in this work obey the non-Debye behavior. The highest conductivity electrolyte exhibits the dominancy of ions, where the ionic transference number, tion value of (0.976) is near to infinity with a voltage of breakdown of 2.11 V. The fabricated electrochemical double-layer capacitor (EDLC) achieves the highest specific capacitance, Cs of 98.08 F/g at 10 mV/s by using the cyclic voltammetry (CV) technique.

Surface Modification of Solid Electrolytes for Advanced Chemical Sensors.

1988 ◽  
Vol 135 ◽  
Author(s):  
Werner Weppner
Keyword(s):  
Surface Modification ◽  
Solid State ◽  
Ionic Conductivity ◽  
Process Control ◽  
Environmental Protection ◽  
Chemical Sensors ◽  
Solid Electrolytes ◽  
Elevated Temperatures ◽  
High Ionic Conductivity ◽  
Ion Conductors

Solid State ion conductors are sucessfully employed in chemical sensors for gases such as oxygen for process control and environmental protection. The application requires elevated temperatures for sufficiently high ionic conductivity and is restricted to a few gases for which suitable solid electrolytes are available.

scholarly journals Crosslinked perfluoropolyether solid electrolytes for lithium ion transport

2017 ◽  
Vol 310 ◽  
pp. 71-80 ◽  
Author(s):  
Didier Devaux ◽  
Irune Villaluenga ◽  
Mahesh Bhatt ◽  
Deep Shah ◽  
X. Chelsea Chen ◽  
...  
Keyword(s):  
Ion Transport ◽  
Solid Electrolytes ◽  
Lithium Ion

scholarly journals Quantifying the impact of disorder on Li-ion and Na-ion transport in perovskite titanate solid electrolytes for solid-state batteries

2020 ◽  
Vol 8 (37) ◽  
pp. 19603-19611
Author(s):  
Adam R. Symington ◽  
John Purton ◽  
Joel Statham ◽  
Marco Molinari ◽  
M. Saiful Islam ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Solid Electrolytes ◽  
Research Interest ◽  
Considerable Research ◽  
Solid State Batteries ◽  
Li Ion ◽  
All Solid State Batteries ◽  
And Performance ◽  
The Impact

Solid electrolytes for all-solid-state batteries are generating considerable research interest as a means to improving their safety, stability and performance.

scholarly journals Nano Resistive Memory (Re-RAM) Devices and their Applications

2019 ◽  
Vol 58 (1) ◽  
pp. 248-270 ◽  
Author(s):  
Chandra Sekhar Dash ◽  
S. R. S. Prabaharan
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Random Access ◽  
Resistive Random Access Memory ◽  
Ionic Conductors ◽  
Artificial Synapse ◽  
Depth Analysis ◽  
Art Research ◽  
Memory Applications ◽  
State Ionic

Abstract Use of solid state ionic conductors the so-called Solid Electrolytes has brought new impetus to the field of solid state memories namely resistive random access memory (Re-RAM). In this review article, to begin we present the detailed understanding on the basics of solid electrolytes. Later, the same has been reviewed focusing on its application in novel solid state memory applications. Few examples of solid electrolytes are considered and their impact on the state-of-art research in this domain is discussed in detail. An in-depth analysis on the fundamentals of Resistive switching mechanism involved in various classes of Memristive devices viz., Electrochemical Metallization Memories (ECM) and Valence change Memories (VCM). A few important applications of Memristors such as Neuristor and artificial synapse in neuromorphic computing are reviewed as well. Finally, the most anticipated energy efficient battery-like cells as artificial synapse in brain-inspired computing is also covered.

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