Characterization of a Lignite Ash from the METC Gasifier III. Correlations of Leaching Behavior and Mineralogy

1984 ◽  
Vol 43 ◽  
Author(s):  
D. J. Hassett ◽  
G. J. McCarthy ◽  
K. R. Henke ◽  
E. D. Korynta

AbstractLignite gasification ash from the Morgantown Energy Technology Center (METC) gasifier was subiected to two short-term leaching treatments. The cnncentrations of regulated elements in the EPA EP procedure leachate from the bulk METC ash did not exceed the “EP Trigger Limits.” A modification of this procedure that uses a basic synthetic groundwater instead of the acid EP extractant was also performed on the bulk ash and its eleven size fractions. Water equilibria modeling was used to explain the concentrations of major elements in solution. Corcentrations of minor and trace elements in solution after leaching with synthetic groundwater were also below “EP Trigger Limits.”

1988 ◽  
Vol 332 (6) ◽  
pp. 685-688 ◽  
Author(s):  
Jorma Kumpulainen ◽  
Maija Paakki ◽  
Raija Tahvonen

2021 ◽  
Author(s):  
Alessia Borghini ◽  
Silvio Ferrero ◽  
Patrick J. O'Brien ◽  
Bernd Wunder ◽  
Oscar Laurent

<p>Melt inclusions of very unusual nature occur in garnets of eclogites of the Granulitgebirge, Bohemian Massif. This is one of the first direct characterization of a preserved metasomatic melt responsible for the formation of eclogites enclosed in garnet peridotites. The inclusions are micrometric, from glassy to fully crystalized as nanogranitoids and randomly distributed in the garnet core. Nanogranitoids contain kumdykolite/albite, phlogopite, osumilite and kokchetavite with a variable amount of quartz, pyroxene, carbonate and rare white mica. The melt has a granitic composition rather than basaltic or tonalitic/trondhjemitic as would be expected from the partial melting of ultramafic or mafic rocks and it is as well hydrous and peraluminous. The trace elements composition is also unusual for melts in mantle rocks with elements typical of continental crust (Cs, Li, B, Pb and Rb) and subduction zone (Th and U). Similar signatures, i.e. continental crust and subduction, are visible also in the whole rock trace elements in the form of high amounts of LILE and U. The eclogite major elements composition is similar to a Ca- and Fe - rich mafic rock akin more to the crust than to the mantle.</p><p>The peculiar melt composition and the lack of a clear residue of a melting reaction in the eclogites suggest that this melt is external, i.e. metasomatic. It infiltered the peridotites during subduction of the continental crust at mantle depth and aided the transformation of basic layers, already in the peridotite, to eclogite. In addition, similar trace elements patterns to the melt reported here can be found in the so-called durbachite -ultrapotassic melanosyenite present in the high-grade Variscan basement- and in the garnet peridotites and garnet pyroxenites of the T-7 borehole. In both case metasomatism was suggested but the agent was just inferred based on the geochemical signature. All these occurrences suggest that mantle contaminated by melts from deeply subducted continental crust is widespread beneath the Bohemian Massif.</p>


1966 ◽  
Vol 2 (4) ◽  
pp. 265-277 ◽  
Author(s):  
B. C. Akehurst ◽  
A. Sreedharan

SummaryForty-one factorial experiments on rates and forms of the three major elements and rates of some minor and trace elements were carried out over the period 1954–1962 in Iringa, as part of a project to introduce Virginian-type tobacco varieties into the area. There were major responses to nitrogen and phosphate, and a close relationship between their effects, but no responses to other elements. Nitrogen raised yield, particularly in wet seasons, but generally tended to reduce quality, severely above 44 lb N per acre and at lower levels in dry years. Phosphate raised yield and quality, and in some instances crop failures occurred in its absence. Data suggested the optimal N : P2O5 ratio in fertilizer mixtures to be 1 : 15. Despite lack of response to potassium a small amount was recommended, to cover requirements for leaf characteristics which were not measured. The programme amply succeeded in its aim of establishing ‘average’ fertilizer recommendations, which were fundamentally sound, for the whole of the Iringa tobacco growing area. These recommendations are summarized.


1985 ◽  
Vol 57 (11) ◽  
pp. 2106-2109 ◽  
Author(s):  
Claude. Veillon ◽  
Susan A. Lewis ◽  
Kristine Y. Patterson ◽  
Wayne R. Wolf ◽  
James M. Harnly ◽  
...  

Author(s):  
V. Sharma ◽  
R. Acharya ◽  
Hemlata K. Bagla ◽  
P. K. Pujari

Rapid automobile glass forensics by non-destructive analysis of “as-received” samples by external (in-air) PIGE for low Z elements with tantalum as a current normalizer and INAA for minor and trace elements using reactor neutrons.


Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 837
Author(s):  
Franca Caucia ◽  
Maurizio Scacchetti ◽  
Luigi Marinoni ◽  
Mattia Gilio ◽  
Antonio Langone ◽  
...  

In this work a rare and attractive blue diopside present in Sissone valley in the Western Alps was investigated through different methodologies: geological survey; standard gemological methods; X-Ray Powder Diffraction; SEM observations; Raman spectrometry; EMP analyses of major elements; and LA-ICP-MS analyses for minor and trace elements. The host rock of investigated gems is represented by a Mg-calcite bearing marble, belonging to the Suretta nappe and composed of blue diopside, lizardite, phlogopite, forsterite, Ca-Mg-amphibole, and thomsonite; the rock was metamorphosed by the intrusion of Masino-Bregaglia pluton. The diopside is generally found in the core of veins in contact with green–blue tremolite and, more externally, with green–yellowish lizardite. The diopside samples show opaque diaphaneity, are inert to long and short-waves UV radiation, and their specific density varies between 3.24 and 3.30 g/cm3 while medium refraction between 1.680–1.683. The diopside shows a polycrystalline texture with interstitial Mg-calcite which acts as binder. The characteristic blue–turquoise color is mainly determined by traces of V and subordinately of Fe, Mn, Cr and Ti. The contents of V and Ti show a good positive correlation. The minerals associated with diopside in the lenticular veins also show enrichments in V. The blue diopside of the Sissone valley could certainly present a good commercial value, but unfortunately it is difficult to reach the outcrop sites.


2018 ◽  
Vol 33 (8) ◽  
pp. 1345-1353 ◽  
Author(s):  
Cécile Fabre ◽  
Damien Devismes ◽  
Samuel Moncayo ◽  
Frédéric Pelascini ◽  
Florian Trichard ◽  
...  

Evaluation of LIBS-based imaging for the detection of minor and trace elements in minerals with microscopic-scale resolution.


1969 ◽  
Vol 15 (2) ◽  
pp. 235-236 ◽  
Author(s):  
R. G. Eagon

Cell walls of Pseudomonas aeruginosa were digested by a wet-ashing technique and analyzed for 12 different cations. The results indicated that these cell wall-associated inorganic substances can be classed broadly into major, minor, and trace elements. Phosphorus, K+, Mg2+, and Ca2+ were considered major elements since they are present in relatively high concentrations; Na+ and Fe3+ were considered minor elements; and, Zn2+, Pb2+, Co2+, Cu2+, Mn2+, and Sr2+ were considered trace elements.


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