A comparative study of AlGaN- and GaN-based lasing structures for near- and deep-UV applications

2000 ◽  
Vol 622 ◽  
Author(s):  
Sergiy Bidnyk ◽  
Jack B. Lam ◽  
Gordon G. Gainer ◽  
Brian D. Little ◽  
Yong-Hwan Kwon ◽  
...  

ABSTRACTWe report a comprehensive study on the optical properties of GaN- and AlGaN-based lasing structures at high-levels of optical excitation (carrier densities of 1017−1020 cm−3) and identify critical issues necessary for the development of near- and deep-UV light emitting devices. We successfully achieved room temperature stimulated emission (SE) with emission wavelengths ranging from 351 nm to 373 nm in a variety of samples. Through an analysis of the temperature-dependent lasing characteristics, combined with absorption and time-resolved photoluminescence measurements, we estimated the carrier density required to achieve the SE threshold in GaN epilayers. We found that in AlGaN epilayers, the onset of SE (∼1019 cm−3) occurs at carrier densities one order of magnitude higher than in thick GaN epilayers, indicating that an electron-hole plasma is the dominant gain mechanism over the entire temperature range studied (10 K to 300 K). A remarkably low lasing threshold was observed in GaN/AlGaN heterostructures over the temperature range of 10 K to 300 K. Our experimental results indicate that GaN/AlGaN heterostructures could be used to efficiently generate laser emission with wavelengths shorter than 373 nm. The implications of this study on the development of UV laser diodes is discussed.

2018 ◽  
Vol 8 (12) ◽  
pp. 2362 ◽  
Author(s):  
Sergey Nikishin

III-Nitride short period superlattices (SPSLs), whose period does not exceed ~2 nm (~8 monolayers), have a few unique properties allowing engineering of light-emitting devices emitting in deep UV range of wavelengths with significant reduction of dislocation density in the active layer. Such SPSLs can be grown using both molecular beam epitaxy and metal organic chemical vapor deposition approaches. Of the two growth methods, the former is discussed in more detail in this review. The electrical and optical properties of such SPSLs, as well as the design and fabrication of deep UV light-emitting devices based on these materials, are described and discussed.


2008 ◽  
Vol 590 ◽  
pp. 141-174 ◽  
Author(s):  
Asif Khan ◽  
Krishnan Balakrishnan

Ultraviolet light emitting diodes with emission wavelengths less than 400 nm have been developed using the AlInGaN material system. Rapid progress in material growth, device fabrication and packaging enabled demonstration of deep-UV light-emitting devices with emission from 400 to 210 nm with varying efficiencies. For high aluminum alloy compositions needed for the shorter wavelength devices, these materials border between having material properties like conventional semiconductors and insulators, adding a degree of complexity to developing efficient light emitting devices. This chapter provides a review of III-nitride based UV light emitting devices including technical developments that allow for emission in the ultraviolet spectrum, and an overview of their applications in optoelectronic systems.


Author(s):  
П.А. Бохан ◽  
К.С. Журавлёв ◽  
Д.Э. Закревский ◽  
Т.В. Малин ◽  
И.В. Осинных ◽  
...  

Time-resolved luminescence and stimulated emission intensities has been experimentally investigated in heavily doped Al0.65Ga0.35N and Al0.74Ga0.26N structures under pulsed optical excitation. These results showed that the time decay of the luminescence and stimulated emission intensities for various wavelengths of the emitted spectrum and optical pumping intensities consisting of at least the fast and the slow components. Fast components with exponential time decay are responsible for the radiative recombination of nonequilibrium electrons on deep acceptors, while slow ones are responsible for the recombination of donor-acceptor pairs


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1220
Author(s):  
Jan Honzíček ◽  
Eliška Matušková ◽  
Štěpán Voneš ◽  
Jaromír Vinklárek

This study describes the catalytic performance of an iron(III) complex bearing a phthalocyaninato-like ligand in two solvent-borne and two high-solid alkyd binders. Standardized mechanical tests revealed strong activity, which appeared in particular cases at concentrations about one order of magnitude lower than in the case of cobalt(II) 2-ethylhexanoate, widespread used in paint-producing industry. The effect of the iron(III) compound on autoxidation process, responsible for alkyd curing, was quantified by kinetic measurements by time-resolved infrared spectroscopy and compared with several primary driers. Effect of the drier concentration on coloration of transparent coatings was determined by UV–Vis spectroscopy.


2021 ◽  
Vol 118 (23) ◽  
pp. 231102
Author(s):  
Youn Joon Sung ◽  
Dong-Woo Kim ◽  
Geun Young Yeom ◽  
Kyu Sang Kim

2007 ◽  
Vol 46 (No. 23) ◽  
pp. L537-L539 ◽  
Author(s):  
Vinod Adivarahan ◽  
Qhalid Fareed ◽  
Surendra Srivastava ◽  
Thomas Katona ◽  
Mikhail Gaevski ◽  
...  

2005 ◽  
Vol 87 (9) ◽  
pp. 093108 ◽  
Author(s):  
W. M. Kwok ◽  
A. B. Djurišić ◽  
Y. H. Leung ◽  
W. K. Chan ◽  
D. L. Phillips

2014 ◽  
Vol 70 (a1) ◽  
pp. C776-C776 ◽  
Author(s):  
Elzbieta Trzop ◽  
Bertrand Fournier ◽  
Katarzyna Jarzembska ◽  
Jesse Sokolow ◽  
Radoslaw Kaminski ◽  
...  

Thanks to their potential applications as light-emitting devices, chemical sensors and dye-sensitized solar cells, heteroleptic copper (I) complexes have been extensively studied. Cu(DPPE)(DMP)·PF6(dppe= 1,2-bis(diphenylphosphino)ethane; dmp = 2,9-dimethyl-1,10-phenanthroline) crystallizes in the monoclinic system, P21/c, with two independent molecules in the asymmetric unit. Previous studies on this system [1,2] show strong temperature-dependent emission. The complex was studied at 90K under 355nm laser excitation. At this temperature, the luminescence decay for Cu(DPPE)(DMP)·PF6is biexponential with lifetimes of ~3μs and ~28μs. Two time-resolved X-ray diffraction techniques were applied for studies: (1) a Laue technique at BioCARS ID-14 beamline at the Advanced Photon Source, and (2) monochromatic diffraction at a newly constructed in-house pump-probe monochromatic facility at the University at Buffalo. Structural changes determined with the two methods are in qualitative agreement; discrepancies in position of the Cu and P atoms were observed. The molecular distortions were smaller than those determined at 16K in the earlier synchrotron study by Vorontsov et al. [2]. Photodeformation maps (see Figure below), in which the increase in temperature on photoexcitation has been eliminated, clearly illustrate the photoinduced atomic shifts for both data sets. Results will be compared with those obtained for other studied heteroleptic copper (I) complexes, for instance Cu[(1,10-phenanthroline-N,N′) bis(triphenylphosphine)]·BF4[3]. The in-house pump-probe facility is discussed by Radoslaw Kaminski at this meeting. Research funded by the National Science Foundation (CHE1213223). BioCARS Sector 14 at APS is supported by NIH (RR007707). The Advanced Photon Source is funded by the Office of Basic Energy Sciences, U.S. Department of Energy, (W-31-109-ENG-38). KNJ is supported by the Polish Ministry of Science and Higher Education through the "Mobility Plus" program.


2009 ◽  
Vol 42 (3) ◽  
pp. 392-400 ◽  
Author(s):  
I. B. Ramsteiner ◽  
A. Schöps ◽  
H. Reichert ◽  
H. Dosch ◽  
V. Honkimäki ◽  
...  

Diffuse X-ray scattering has been an important tool for understanding the atomic structure of binary systems for more than 50 years. The majority of studies have used laboratory-based sources providing 8 keV photons or synchrotron radiation with similar energies. Diffuse scattering is weak, with the scattering volume determined by the X-ray absorption length. In the case of 8 keV photons, this is not significantly different from the typical extinction length for Bragg scattering. If, however, one goes to energies of the order of 100 keV the scattering volume for the diffuse scattering increases up to three orders of magnitude while the extinction length increases by only one order of magnitude. This leads to a gain of two orders of magnitude in the relative intensity of the diffuse scattering compared with the Bragg peaks. This gain, combined with the possibility of recording the intensity from an entire plane in reciprocal space using a two-dimensional X-ray detector, permits time-resolved diffuse scattering studies in many systems. On the other hand, diffraction features that are usually neglected, such as multiple scattering, come into play. Four types of multiple scattering phenomena are discussed, and the manner in which they appear in high-energy diffraction experiments is considered.


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