Photoelectron Spectroscopy Measurements of the Valence Band Structures of C60 Thin Films on Single Crystal Silicon and Polycrystalline Copper

2002 ◽  
Vol 734 ◽  
Author(s):  
B. Ha ◽  
J. H. Rhee ◽  
Y. Li ◽  
D. Singh ◽  
S. C. Sharma

ABSTRACTWe have used photoelectron spectroscopy to study possible modifications in the electronic valence band structures of thin films of C60 due to their deposition on single crystal silicon and polycrystalline copper. The C60 thin films were deposited by thermal evaporation under high vacuum and further characterized by using Raman spectroscopy. We observe significant differences in the valence band structures of C60 thin films deposited on these substrates and attribute them to interactions at the interface.

1981 ◽  
Vol 25 ◽  
pp. 365-371
Author(s):  
Glen A. Stone

This paper presents a new method to measure the thickness of very thin films on a substrate material using energy dispersive x-ray diffractometry. The method can be used for many film-substrate combinations. The specific application to be presented is the measurement of phosphosilicate glass films on single crystal silicon wafers.


2020 ◽  
Vol 8 (2) ◽  
Author(s):  
Weijia Guo ◽  
Senthil Kumar Anantharajan ◽  
Xinquan Zhang ◽  
Hui Deng

Abstract In this study, atmospheric-pressure (AP) plasma generated using He/O2/CF4 mixture as feed gas was used to etch the single-crystal silicon (100) wafer and the characteristics of the etched surface were investigated. The wafer morphology and surface elemental composition were analyzed using scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS), respectively. The XPS results reveal that the fluorine element will be deposited on the wafer surface during the etching process when oxygen was not introduced as the feed gas. By detecting the energy and intensity of emitted particles, optical emission spectroscopy (OES) is used to identify the radicals in plasma. The fluorocarbon radicals generated during CF4 plasma ionization can form carbon fluoride polymer, which is considered as one factor to suppress the etching process. The roughness was measured to be changed with the increase in the etching time. The surface appears to be rougher at first when the plasma etching occurred on the subsurface damaged (SSD) layer, and the subsurface cracks would show on the surface after a short-time etching. After the damaged layer was fully removed, etching resulted in the formation of square-opening etching pits. During extended etching, the individual etching pits grew up and coalesced with one another; this coalescence provided an improved surface roughness. This study explains the AP plasma etching mechanism, and the formation of anisotropic surface etching pits at a microscale level for promoting the micromachining process.


2002 ◽  
Vol 734 ◽  
Author(s):  
R. Govinthasamy ◽  
J. H. Rhee ◽  
S. C Sharma

ABSTRACTHighly conducting thin films of C60 were deposited by thermal evaporation in high vacuum on single crystal silicon substrates. The microstructure of the films was characterized by using Atomic Force Microscopy, and laser Raman spectroscopy. The films were polymerized by uv irradiation. The dc electrical resistivities of the as-deposited and uv-polymerized films were measured as functions of temperature between 295 and 17K by the four-probe technique. We present results on the effects of uv-irradiation on the surface microstructure and the temperature dependence of the electrical resistivity of these films.


2007 ◽  
Vol 140 (2) ◽  
pp. 257-265 ◽  
Author(s):  
Hsien-Kuang Liu ◽  
B.J. Lee ◽  
Pang-Ping Liu

2011 ◽  
Vol 56 (11) ◽  
pp. 1670-1674 ◽  
Author(s):  
M. V. Gomoyunova ◽  
G. S. Grebenyuk ◽  
I. I. Pronin

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