Characterization of Structural Quality of Bonded Silicon-On-Insulator Wafers by Spectroscopic Ellipsometry and Raman Spectroscopy

2004 ◽  
Vol 809 ◽  
Author(s):  
N. V. Nguyen ◽  
J. E. Maslar ◽  
Jin-Yong Kim ◽  
Jin-Ping Han ◽  
Jin-Won Park ◽  
...  

ABSTRACTThe crystalline quality of bonded Silicon-On-Insulator (SOI) wafers were examined by spectroscopic ellipsometry and Raman spectroscopy. Both techniques detect slight structural defects in the SOI layer. If a pure crystalline silicon dielectric function is assumed for the SOI layer, the spectroscopic ellipsometry data fitting yields an unacceptably large discrepancy between the experimental and modeled data. The best fits for all the samples result in a dielectric function of the SOI layer that consists of a physical mixture of crystalline silicon and about 4 % to 7 % of amorphous silicon. Using such a mixture indicates that there are still some defects in the SOI layer when compared with the high-quality bulk crystalline silicon. This observation is further supported by Raman spectroscopy measurements. The Raman spectra of all SOI samples exhibit a feature at about 495 cm−1 that is not observed in the crystalline silicon spectrum. Features similar to the 495 cm−1 feature have been reported in the literature and attributed to dislocations or faults in the silicon lattice.

2004 ◽  
Vol 85 (14) ◽  
pp. 2765-2767 ◽  
Author(s):  
N. V. Nguyen ◽  
J. E. Maslar ◽  
Jin-Yong Kim ◽  
Jin-Ping Han ◽  
Jin-Won Park ◽  
...  

2015 ◽  
Vol 60 (3) ◽  
pp. 2047-2052 ◽  
Author(s):  
A.D. Dobrzańska-Danikiewicz ◽  
W. Wolany ◽  
D. Cichocki ◽  
D. Łukowiec

Abstract The combination of TEM research and Raman spectroscopy to characterization of MWNTs-Re nanocomposites gives a new notion about the structure and quality of materials obtained. TEM studies indicate that the functionalization method significantly influences the morphology of obtained MWCNTs-Re nanocomposites. Due to the specific spectrum recorded for the MWCNTs they can be distinguished from other forms of carbon, furthermore comparative analysis of the results at different stages of the manufacturing process confirms the covalent modification of the MWCNTs structure. The D-band intensity compared to the G-band intensity provides valuable information about the quality of the sample, in particular indicates the existence of contamination and/or the presence of structural defects. Preliminary results suggest that the high-temperature manufacturing process of MWCNTs-Re nanocomposite improves the quality of the carbon material intended for the experiment.


1998 ◽  
Vol 526 ◽  
Author(s):  
G. E. Jellison ◽  
D. B. Geohegan ◽  
D. H. Lowndes ◽  
A. A. Puretzky ◽  
V. I. Merkulov

AbstractSpectroscopic ellipsometry is used to characterize amorphous diamond, also known as tetrahedral amorphous carbon, (ta-C) films grown by pulsed laser ablation. The ellipsometry data is collected with the two-modulator generalized ellipsometer, which measures all three parameters required to characterize isotropic samples, as well as additional parameters used to characterize strain-induced birefringence of the focusing optics. Lenses are used to focus the light spot to an ellipse 0.7 × 2.0 mm2, allowing us to perform several ellipsometric measurements across the profile of ta-C films grown on 7.5 cm diameter Si wafers. The spectroscopic ellipsometry data are fit using a model of the ta-C dielectric function based on the Tauc band edge and the Lorentz expression of the dielectric function for an ensemble of atoms. These fits are used to determine the thicknesses of the rough surface layer, the ta-C film, and the interface layer, as well as the energy gap of the film. Comparisons are made with fits to an earlier formulation due to Forouhi and Bloomer [Phys. Rev. B 34, 7018 (1986).]. In addition to being Kramers-Kronig consistent, the Tauc-Lorentz formulation fits the ta-C data better.


2020 ◽  
Vol 96 (3s) ◽  
pp. 154-159
Author(s):  
Н.Н. Егоров ◽  
С.А. Голубков ◽  
С.Д. Федотов ◽  
В.Н. Стаценко ◽  
А.А. Романов ◽  
...  

Высокая плотность структурных дефектов является основной проблемой при изготовлении электроники на гетероструктурах «кремний на сапфире» (КНС). Современный метод получения ультратонких структур КНС с помощью твердофазной эпитаксиальной рекристаллизации позволяет значительно снизить дефектность в гетероэпитаксиальном слое КНС. В данной работе ультратонкие (100 нм) слои КНС были получены путем рекристаллизации и утонения субмикронных (300 нм) слоев кремния на сапфире, обладающих различным структурным качеством. Плотность структурных дефектов в слоях КНС оценивалась с помощью рентгеноструктурного анализа и просвечивающей электронной микроскопии. Кривые качания от дифракционного отражения Si(400), полученные в ω-геометрии, продемонстрировали максимальную ширину на полувысоте пика не более 0,19-0,20° для ультратонких слоев КНС толщиной 100 нм. Формирование структурно совершенного субмикронного слоя КНС 300 нм на этапе газофазной эпитаксии обеспечивает существенное уменьшение плотности дислокаций в ультратонком кремнии на сапфире до значений ~1 • 104 см-1. Тестовые n-канальные МОП-транзисторы на ультратонких структурах КНС характеризовались подвижностью носителей в канале 725 см2 Вс-1. The high density of structural defects is the main problem on the way to the production of electronics on silicon-on-sapphire (SOS) heteroepitaxial wafers. The modern method of obtaining ultrathin SOS wafers is solid-phase epitaxial recrystallization which can significantly reduce the density of defects in the SOS heteroepitaxial layers. In the current work, ultrathin (100 nm) SOS layers were obtained by recrystallization and thinning of submicron (300 nm) SOS layers, which have various structural quality. The density of structural defects in the layers was estimated by using XRD and TEM. Full width at half maximum of rocking curves (ω-geometry) was no more than 0.19-0.20° for 100 nm ultra-thin SOS layers. The structural quality of 300 nm submicron SOS layers, which were obtained by CVD, depends on dislocation density in 100 nm ultrathin layers. The dislocation density in ultrathin SOS layers was reduced by ~1 • 104 cm-1 due to the utilization of the submicron SOS with good crystal quality. Test n-channel MOS transistors based on ultra-thin SOS wafers were characterized by electron mobility in the channel 725 cm2 V-1 s-1.


1988 ◽  
Vol 144 ◽  
Author(s):  
K. C. Garrison ◽  
C. J. Palmstrøm ◽  
R. A. Bartynski

ABSTRACTWe have demonstrated growth of high quality single crystal CoGa films on Ga1−xAlxAs. These films were fabricated in-situ by codeposition of Co and Ga on MBE grown Ga1−xAlxAs(100) surfaces. The elemental composition of the films was determined using Rutherford Backscattering (RBS) and in-situ Auger analysis. The structural quality of the films' surfaces was studied using RHEED (during deposition) and LEED (post deposition). RBS channeling was used to determine the bulk crystalline quality of these films.For ∼500 Å CoGa films grown at ∼450°C substrate temperature, channeling data showed good quality epitaxial single crystals [χmin ∼7%] with minimal dechanneling at the interface.


2001 ◽  
Vol 693 ◽  
Author(s):  
N.V. Edwards ◽  
O.P.A. Lindquist ◽  
L.D. Madsen ◽  
S. Zollner ◽  
K. Järrehdahl ◽  
...  

AbstractAs a first step toward enabling the in-line metrology of III-V nitride heterostructure and materials, we present the optical constants of the two common substrate materials over an unprecendented spectral range. Vacuum Ultraviolet spectroscopic ellipsometry (VUVSE) was used to obtain the optical constants for Al2O3 and the ordinary and extra-ordinary component of the dielectric function for both 4H- and 6H-SiC. The results are discussed in the context of anisotropy, polytypism, bandstructure, optical transitions, and preparation/characterization of abrupt surfaces, where appropriate.


1987 ◽  
Vol 62 (8) ◽  
pp. 3458-3461 ◽  
Author(s):  
F. Ferrieu ◽  
D. P. Vu ◽  
C. D’Anterroches ◽  
J. C. Oberlin ◽  
S. Maillet ◽  
...  

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