Effects of Stress on Step Energies and Surface Roughness

MRS Bulletin ◽  
1996 ◽  
Vol 21 (4) ◽  
pp. 27-30 ◽  
Author(s):  
Christopher Roland

Strain relaxation in lattice-mismatched, heteroepitaxial systems is one of the classic problems in materials physics, which has gained new urgency with the increased applications of strained layers in microelectronic systems. In general both the structure and the integrity of the thin films are strongly influenced by strain. For instance it has long been known that under strain, the growth changes from an initial layer-by-layer growth mode to one with three-dimensional islanding. In the seminal works of van der Merwe, and Matthews and Blakeslee, this change in growth mode is explained in terms of the introduction of strain-relieving misfit dislocations, which appear when the film has reached some critical thickness. Recently it has become clear that this change in growth mode can take place even without the introduction of misfit dislocations. Such dislocation-free coherent islanding, or “roughening,” has been observed experimentally both in Ge/Si and in InGaAs/GaAs systems. Furthermore recent experiments show that in Ge/Si(100) systems, the thin films display a curious asymmetry with respect to the sign of the strain: Films under compression roughen by forming coherent islands while those under tension remain relatively smooth. A possible mechanism behind this strain-induced type of roughening is the subject of this article.

2011 ◽  
Vol 1292 ◽  
Author(s):  
Nobuyuki Iwata ◽  
Mark Huijben ◽  
Guus Rijnders ◽  
Hiroshi Yamamoto ◽  
Dave H. A. Blank

ABSTRACTThe CaFeOX(CFO) and LaFeO3(LFO) thin films as well as superlattices were fabricated on SrTiO3(100) substrates by pulsed laser deposition (PLD) method. The tetragonal LFO film grew with layer-by-layer growth mode until approximately 40 layers. In the case of CFO, initial three layers showed layer-by-layer growth, and afterward the growth mode was transferred to two layers-by-two layers (TLTL) growth mode. The RHEED oscillation was observed until the end of the growth, approximately 50nm. Orthorhombic twin CaFeO2.5 (CFO2.5) structure was obtained. However, it is expected that the initial three CFO layers are CaFeO3 (CFO3) with the valence of Fe4+. The CFO and LFO superlattice showed a step-terraces surface, and the superlattice satellite peaks in a 2θ-θ and reciprocal space mapping (RSM) x-ray diffraction (XRD) measurements, indicating that the clear interfaces were fabricated.


1997 ◽  
Vol 11 (21n22) ◽  
pp. 981-987
Author(s):  
H. Q. Yin ◽  
T. Arakawa ◽  
Y. Kaneda ◽  
T. Yoshikawa ◽  
N. Haneji ◽  
...  

La 2-x Sr x CuO 4 ultra-thin films with thickness 200 Å were fabricated by pulsed laser deposition method in oxygen ( O 2) atmosphere. The morphology of deposited films was investigated by reflection high energy electron diffraction (RHEED), atomic force microscopy (AFM) and scanning electronic microscopy (SEM). The strong oxygen ambient pressure dependence of film morphology was observed. In high oxygen ambient pressure, the film growth is dominated by island growth mode. The results imply that the experimental conditions of oxygen ambient pressure and substrate temperature are critical for the layer-by-layer growth mode.


2014 ◽  
Vol 605 ◽  
pp. 661-664
Author(s):  
Hadria Medouer ◽  
Chahira Benyekken ◽  
Saci Messaadi

Elecrodeposited Ni-P alloy thin films have been the subject of extended investigations, since the pioneering works of Brenner et al, in the late 1940s. It is well known, that the physical and chemical properties of the Ni-P deposit composition are strongly influenced by the preparation conditions. In our experimental procedure, we have used a Parstat 2253 potensiostat equipped with Power-Suite software. All the electrochemical experiments were performed in a three electrode cell in which the volume of the bath was 150ml, in this experimental technique, we can measure one or more of three parameters: the potential (V), current (i), and time (t). The aim of our work consists to study the nucleation and growth process and given morphology and composition of electrodeposited Nix-P100-xthin films on Copper substrates. For this purpose, cyclic voltametry and chnonoamperomaty have been used in order to determine the previous cited properties of thin films Ni-P, [0.10 of NaPH2O2solutions. The chrnoamperogramms can be interpreted by the use of one of three models called: Growth mode (Me layer by layer formation); Franck Van der Merwe, FM model, Growth mode 3D (Me island formation on the top of predeposited), 2D Meads overlayers on substrat and Stranski-Krastanov; (SK model).


2021 ◽  
Author(s):  
Marius Grundmann ◽  
Tillmann Stralka ◽  
Michael Lorenz ◽  
Susanne Selle ◽  
Christian Patzig ◽  
...  

The growth of (AlxGa1-x)2O3 alloy thin films in corundum phase on r-plane (01.2) Al2O3 substrates is investigated. The growth mode changes from step flow for pseudomorphic layers to three-dimensional growth...


2004 ◽  
Vol 11 (06) ◽  
pp. 563-568
Author(s):  
A. AZIZI ◽  
J. ARABSKI ◽  
A. DINIA

Ag thin films deposited on Ru (0001) surface by molecular beam epitaxy, at temperatures of 20°C and 450°C, have been investigated using reflection high-energy electron diffraction (RHEED), atomic force microscopy (AFM) and X-ray diffraction (XRD) techniques. For both growth temperatures, the in situ RHEED patterns of the Ag films exhibited an in-plane six-fold symmetry, indicating that the Ag deposit is in epitaxy with the Ru buffer surface. At RT, the RHEED technique indicated a three-dimensional growth (3D), while a layer-by-layer growth (2D) takes place at HT. The AFM images showed a granular structure of the surface of the deposited Ag layers with a large variation of the roughness with the growth temperature. XRD analysis gave indication of a strongly textured thin film along the growth direction. The lattice mismatch between the Ag and Ru is at the origin of a stress at the interface and defects structure in the film.


1993 ◽  
Vol 312 ◽  
Author(s):  
T. Kawai ◽  
H. Yonezu ◽  
Y. Ogasawara ◽  
D. Saito ◽  
K. Pak

AbstractThe segregation and interdiffusion of In atoms in the GaAs/InAs/GaAs heterostructures were investigated by secondary ion mass spectroscopy. When the 1 ML thick InAs layer was grown in a layer-by-layer growth mode with no dislocations, the segregation of In atoms became marked with the increase of the growth temperature. However, the segregation was observed even at relatively low growth temperature of 400°C in molecular beam epitaxy. It was found that the segregation was markedly enhanced by dislocations near the heterointerface when the thick InAs layers were grown in a three-dimensional island growth mode. The interdiffusion of In atoms toward the growth direction occurred after thermal annealing, which could be assisted by vacancies propagating from the film surface into epilayer. It became apparent that the interdiffusion was effectively suppressed by a thin AlAs layer inserted in the GaAs cap layer.


1997 ◽  
Vol 474 ◽  
Author(s):  
F. C. Voogt ◽  
T. Hibma ◽  
P.J.M. Smulders ◽  
L. Iesen ◽  
T. Fujii

ABSTRACTWe have made a study of the use of NO2 as the source of oxygen in the MBE-growth of iron oxides thin films. It is found that NO2 is a much more efficient oxidising agent than molecular O2. As indicated by Mössbauer spectroscopy, performed on 57Fe probe layers, NO2 is not only capable of forming stoichiometric magnetite Fe3O41 but also all non-stoichiometric Fe3-δO4 phases. Even the metastable maghemite phase γ-Fe2O3 (Fe3-δO4 with δ=1/3) can be formed. All iron oxides grow layer-by-layer-like, as indicated by strong RHEED intensity oscillations. When small doses of NO2 are used, new wustite Fe3-xO and Fe3O4 phases are formed. In contrast to the Fe3-δO4 films, these phases have nitrogen incorporated into the crystal lattice. Similar compounds are obtained when NO is used as the source of oxygen. The use of N2O does not lead to the formation of iron oxides. It does, however, alter the growth mode of Fe on MgO(100). Whereas Fe deposited under UHV conditions forms 3D islands, the N2O acts as a surfactant and induces 2D layer-by-layer growth.


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