scholarly journals Single-variable porous nanomaterial series from polymer structure-directing agents

2021 ◽  
Author(s):  
Morgan Stefik
Keyword(s):  
Functional Materials ◽  
Polymer Structure ◽  
Size Distributions ◽  
Energy Device ◽  
Block Polymer ◽  
Solvent Selectivity ◽  
Solution Type ◽  
Pore Size Distributions ◽  
Structure Directing Agents ◽  
Property Performance

AbstractBlock polymer structure-directing agents (SDA) enable the production of porous nanoscale materials. Most strategies rely upon polymer equilibration where diverse morphologies are realized in porous functional materials. This review details how solvent selectivity determines the polymer SDA behaviors, spanning from bulk-type to solution-type. Equilibrating behavior of either type, however, obscures nanostructure cause-and-effect since the resulting sample series convolve multiple spatial variations. Solution-type SDA behaviors include both dynamic and persistent micelles. Persistent micelle templates (PMT) use high solvent selectivity for kinetic entrapment. PMTs enable independent wall thickness control with demonstrated 2 Å precision alterations. Unimodal PMT pore size distributions have spanned from 11.8 to 109 nm and multimodal pore sizes up to 290 nm. The PMT method is simple to validate with diffraction models and is feasible in any laboratory. Finally, recent energy device publications enabled by PMT are reviewed where tailored nanomaterials provide a unique perspective to unambiguously identify nanostructure–property–performance relationships. Graphical abstract

CHARACTERIZATION OF PORE SIZE DISTRIBUTIONS USING NON-NEWTONIAN FLUIDS

2020 ◽  
Author(s):  
Scott C. Hauswirth ◽  
◽  
Majdi Abou Najm ◽  
Christelle Basset
Keyword(s):  
Pore Size ◽  
Newtonian Fluids ◽  
Size Distributions ◽  
Pore Size Distributions

Preparation of P(GMA-co-EGDMA) Monolithic Columns with Adjustable Porous Properties

2014 ◽  
Vol 936 ◽  
pp. 942-949 ◽  
Author(s):  
Hao Tian Zhang ◽  
Qiu Yu Zhang ◽  
Bao Liang Zhang ◽  
Chun Mei Li
Keyword(s):  
Pore Size ◽  
Monolithic Column ◽  
Organic Polymer ◽  
Monolithic Columns ◽  
Size Distributions ◽  
Notable Effect ◽  
Pore Size Distributions ◽  
Porous Properties ◽  
Glass Tubes ◽  
First Time

Porous properties have notable effect on separating effect of organic polymer-based monolithic column. Different applications of monolithic columns require tailored pore size distributions. On account of that, P(GMA-co-EGDMA) monolithic columns were prepared with novel ternary porogenic agents. Glass tubes was chosen as polymerization mold. Moreover, factors influencing the inner pore morphology, pore size and specific surface area were investigated systematically. The results showed that the increasing of the solubility of porogenic agents and the amount of crosslinker, the decreasing of the amount of porogenic agents and temperature rising all could give rise to the decreasing of pore size. Remarkably, the effect of initiator was studied for the first time. The results showed that amount of initiator had no remarkable influence on porous properties. By controlling effect factors, P(GMA-co-EGDMA) Monolithic Columns with pore size from dozens to thousands of nanometer, which can be applied in separation of molecules with different size.

Coal pore size distributions controlled by the coalification process: An experimental study of coals from the Junggar, Ordos and Qinshui basins in China

Fuel ◽  
2017 ◽  
Vol 206 ◽  
pp. 352-363 ◽  
Author(s):  
Yong Li ◽  
Cheng Zhang ◽  
Dazhen Tang ◽  
Quan Gan ◽  
Xinlei Niu ◽  
...  
Keyword(s):  
Experimental Study ◽  
Pore Size ◽  
Size Distributions ◽  
Pore Size Distributions

A New X-Ray Scattering Method for Determining Pore-Size Distribution in Low-k Thin Films

2001 ◽  
Vol 714 ◽  
Author(s):  
Kazuhiko Omote ◽  
Shigeru Kawamura
Keyword(s):  
Thin Films ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Gas Adsorption ◽  
Size Distributions ◽  
X Ray ◽  
X Ray Scattering ◽  
Pore Size Distributions ◽  
Scattering Technique ◽  
Ray Scattering

ABSTRACTWe have successively developed a new x-ray scattering technique for a non-destructive determination of pore-size distributions in porous low-κ thin films formed on thick substrates. The pore size distribution in a film is derived from x-ray diffuse scattering data, which are measured using offset θ/2θ scans to avoid strong specular reflections from the film surface and its substrate. Γ-distribution mode for the pores in the film is used in the calculation. The average diameter and the dispersion parameter of the Γ-distribution function are varied and refined by computer so that the calculated scattering pattern best matches to the experimental pattern. The technique has been used to analyze porous methyl silsesquioxane (MSQ) films. The pore size distributions determined by the x-ray scattering technique agree with that of the commonly used gas adsorption technique. The x-ray technique has been also used successfully determine small pores less than one nanometer in diameter, which is well below the lowest limit of the gas adsorption technique.

THE VARIATION OF IN SITU MEASURED SOIL WATER PROPERTIES WITHIN SOIL MAP UNITS

1980 ◽  
Vol 60 (3) ◽  
pp. 497-509 ◽  
Author(s):  
G. C. TOPP ◽  
W. D. ZEBCHUK ◽  
J. DUMANSKI
Keyword(s):  
Pore Space ◽  
Size Distributions ◽  
Water Capacity ◽  
Intermediate Group ◽  
Pore Size Distributions ◽  
Soil Units ◽  
Soil Water Properties ◽  
Soil Unit

The in situ saturated hydraulic conductivities of nine soil units were measured and cores of the same soil were taken to the laboratory for determination of desorption water capacity relationships. Hydraulic conductivities for the coarse- and fine-textured soils were equivalent and higher than that for medium-textured soils. However, the coarse- and fine-textured soils showed measurably different desorption curves for each of three soil units tested. Variability of duplicate measurements of hydraulic conductivity at sites were found to be considerably less than that of the soil unit as a whole. The highly variable in situ hydraulic conductivities resulted in separations of two groups of soil with significantly different values. A third intermediate group was not significantly different from the other two. The desorption curves were discussed in relation to differences in pore size distributions, identifying proportions of the pore space attributable to structural pores and to textural pores.

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