scholarly journals Establishment of regularities of influence on the specific heat capacity and thermal diffusivity of polymer nanocomposites of a complex of defining parameters

Author(s):  
Nataliia Fialko ◽  
Roman Dinzhos ◽  
Julii Sherenkovskii ◽  
Nataliia Meranova ◽  
Sergii Aloshko ◽  
...  

This paper reports a series of experimental studies to establish regularities of the integrated effect exerted on the specific heat capacity of polymer nanocomposites by such factors as the temperature regime of their production, the value of the mass fraction of the filler, and the temperature of the composite material. The studies were conducted for nanocomposites based on polypropylene filled with carbon nanotubes. When obtaining composites, the method of mixing the components in the melt of the polymer was used. During the studies, the temperature of nanocomposites varied from 295 to 455 K, the mass fraction of the filler ‒ from 0.3 to 10 %. The basic parameter of the technological mode for obtaining composite materials, the value of overheating the polymer melt relative to its melting point, varied in the range of 10...75 K. It is shown that the temperature dependence of the specific heat capacity of the considered composites is sensitive to changes in the overheating of the polymer melt only in the region maximum values of the specific heat capacity. Concentration dependences of the specific heat capacity of the considered nanocomposites at different values of their temperature and the level of overheating of the polymer melt have been built. The studies have been carried out to identify the effects of the influence of the above parameters on the coefficient of thermal diffusivity of nanocomposites. It has been established, in particular, that an increase in the level of overheating the polymer could lead to a very significant increase in the coefficient of thermal diffusivity, which is all the more significant the higher the proportion of filler and the lower the temperature of the composite material. It is shown that the level of overheating the polymer melt relative to its melting point is a parameter that can be used as the basis for the creation of polymer composite materials with specified thermophysical properties.

2010 ◽  
Vol 14 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Sunday Etuk ◽  
Louis Akpabio ◽  
Ita Akpan

Thermal conductivity values at the temperature of 301-303K have been measured for Zea mays straw board as well as Zea mays heartwood (cork) board. Comparative study of the thermal conductivity values of the boards reveal that Zea mays heartwood board has a lower thermal conductivity value to that of the straw board. The study also shows that the straw board is denser than the heartwood board. Specific heat capacity value is less in value for the heartwood board than the straw board. These parameters also affect the thermal diffusivity as well as thermal absorptivity values for the two types of boards. The result favours the two boards as thermal insulators for thermal envelop but with heartwood board as a preferred insulation material than the straw board.


Author(s):  
Siti Shahirah Suhaili ◽  
Md Azree Othuman Mydin ◽  
Hanizam Awang

The addition of mesocarp fibre as a bio-composite material in foamed concrete can be well used in building components to provide energy efficiency in the buildings if the fibre could also offer excellent thermal properties to the foamed concrete. It has practical significance as making it a suitable material for building that can reduce heat gain through the envelope into the building thus improved the internal thermal comfort. Hence, the aim of the present study is to investigate the influence of different volume fractions of mesocarp fibre on thermal properties of foamed concrete. The mesocarp fibre was prepared with 10, 20, 30, 40, 50 and 60% by volume fraction and then incorporated into the 600, 1200 and 1800 kg/m3 density of foamed concrete with constant cement-sand ratio of 1:1.5 and water-cement ratio of 0.45. Hot disk thermal constant analyser was used to attain the thermal conductivity, thermal diffusivity and specific heat capacity of foamed concrete of various volume fractions and densities. From the experimental results, it had shown that addition of mesocarp fibre of 10-40% by volume fraction resulting in low thermal conductivity and specific heat capacity and high the thermal diffusivity of foamed concrete with 600 and 1800 kg/m3 density compared to the control mix while the optimum amount of mesocarp fibre only limit up to 30% by volume fraction for 1200 kg/m3 density compared to control mix. The results demonstrated a very high correlation between thermal conductivity, thermal diffusivity and specific heat capacity which R2 value more than 90%.


2019 ◽  
Vol 796 ◽  
pp. 74-79
Author(s):  
Mohd Faizal Tukimon ◽  
Wan Nur Azrina Wan Muhammad ◽  
M. Nor Anuar Mohamad ◽  
Nurhayati Rosly ◽  
Norasikin Mat Isa

Quaternary molten salt nitrate have been used very practically as medium for energy storage or heat transfer fluid in terms of energy recovery system. Quaternary molten salt nitrate is a mixture that can transfer heat to generate energy such as electricity. Mixed alkaline molten nitrate salt can act as a heat transfer fluid due to their advantageous in terms of heat recovery system due to high specific heat capacity, low vapour pressure, low cost and wide range of temperature in its application. This studies shows about determining the new composition of quaternary molten nitrate salts from different primary salts that can possibly give a high specific heat capacity with low melting point. The mixture of quaternary molten nitrate salts was then heated inside the box furnace at 150°C for four hours and rose up the temperature to 400°C for eight hours. Through heating process, the quaternary molten nitrate alkaline was completely homogenized. The temperature was then dropped to room temperature before removing the mixture from the furnace. The specific heat capacities of each sample were determined by using Differential Scanning Calorimeter, DSC. From the result of DSC testing, Sample 6 gives the highest point of specific heat capacity and low melting point which is 0.4648 J/g°C and 97.71°C respectively. In the nut shell, Sample 6 was chosen as a good mixture with good thermal properties that has a low melting point which is below 100°C but high specific heat capacity that may be a helpful in the application energy recovery system.


2019 ◽  
Vol 955 ◽  
pp. 25-30
Author(s):  
Lucie Marackova ◽  
Veronika Melcova ◽  
Josef Samek ◽  
Oldrich Zmeskal

This paper is focused on the determination of thermal parameters (thermal conductivity, thermal diffusivity, and specific heat capacity) of electrical insulating paper from various producers. The transient step-wise method was used to determine all thermal parameters simultaneously. Evaluation was carried out using the differential method. Thermal conductivity was determined from the steady-state temperature response on thickness (corresponding to the number of paper layers), while thermal diffusivity and specific heat capacity was obtained from the dependence of derivative maximum and the corresponding temperature on thickness. Four electro insulating papers differing by composition and thickness: materials NKN (Nomex-Kapton-Nomex), DMD (Dacron-Mylar-Dacron), TFT (TufQUIN TFT 50) and TVAR (ThermaVolt AR) were studied. As a result, the highest value of thermal conductivity (0.17 W/m/K) was determined for the DMD. Remaining three materials possessed thermal conductivity about 0.12 W/m/K. However, differences in specific heat capacity and thermal diffusivity were found to be significantly higher. The lowest specific heat capacity was found for the DMD sample (1200 J/kg/K), while the highest specific heat capacity was found for TVAR sample (4000 J/kg/K).


2021 ◽  
Vol 881 ◽  
pp. 87-94
Author(s):  
Jin Hua Chen

Reducing the melting point, in creasing the thermal stability limit, and enhancing the specific heat capacity of molten salt are the research hotspots in the field of medium and high temperature energy storage in recent years. From the perspectives of the melting point, thermal stability limit, and specific heat capacity of nitrates, we summarize the melting point, thermal stability limit, and specific heat capacity enhancement of molten salts with different compositions and ratios. The melting points of molten salt with different compositions and ratios are compared. Furthermore, the enhancing effect of various nanomaterials on molten salt is elucidated. The application of nitrate molten salt is also summarized to provide a reference for the research and application of novel molten salts. Keywords: Nitrate Molten Salt; Melting Point; Thermal Stability Limit; Specific Heat Capacity; Application


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