ON THE KINETICS OF A RELAXING HIGH TEMPERATURE ATMOSPHERIC PRESSURE NITROGEN PLASMA

Author(s):  
A. A. Belevtsev ◽  
V.F. Chinnov ◽  
A.V. Fyodorov ◽  
E. Kh. Isakaev ◽  
O. A. Sinkevich
Author(s):  
Shiro Fujishiro ◽  
Harold L. Gegel

Ordered-alpha titanium alloys having a DO19 type structure have good potential for high temperature (600°C) applications, due to the thermal stability of the ordered phase and the inherent resistance to recrystallization of these alloys. Five different Ti-Al-Ga alloys consisting of equal atomic percents of aluminum and gallium solute additions up to the stoichiometric composition, Ti3(Al, Ga), were used to study the growth kinetics of the ordered phase and the nature of its interface.The alloys were homogenized in the beta region in a vacuum of about 5×10-7 torr, furnace cooled; reheated in air to 50°C below the alpha transus for hot working. The alloys were subsequently acid cleaned, annealed in vacuo, and cold rolled to about. 050 inch prior to additional homogenization


2020 ◽  
Vol 58 (5) ◽  
pp. 671-680
Author(s):  
O. V. Korshunov ◽  
D. I. Kavyrshin ◽  
V. F. Chinnov

1980 ◽  
Vol 45 (10) ◽  
pp. 2728-2741 ◽  
Author(s):  
Pavel Fott ◽  
Petr Schneider

Kinetics have been studied of the reaction system taking place during the reaction of thiophene on the cobalt-molybdenum catalyst in a gradientless circulation flow reactor at 360 °C and atmospheric pressure. Butane has been found present in a small amount in the reaction products even at very low conversion. In view of this, consecutive and parallel-consecutive (triangular) reaction schemes have been proposed. In the former scheme the appearance of butane is accounted for by rate of desorption of butene being comparable with the rate of its hydrogenation. According to the latter scheme part of the butane originates from thiophene via a different route than through hydrogenation of butene. Analysis of the kinetic data has revealed that the reaction of thiophene should be considered to take place on other active sites than that of butene. Kinetic equations derived on this assumption for the consecutive and the triangular reaction schemes correlate experimental data with acceptable accuracy.


2021 ◽  
pp. 095400832098729
Author(s):  
K Sudheendra ◽  
Jennifer Vinodhini ◽  
M Govindaraju ◽  
Shantanu Bhowmik

The study involves the processing of a novel poly [1, 4-phenylene-cis-benzobisoxazole] (PBO) fibre reinforced high-temperature thermoplastic composite with polyaryletherketone (PAEK) as the matrix. The PBO fibre and the PAEK film surface was modified using the method of argon and nitrogen plasma treatment. The investigation primarily focuses on evaluating the tensile properties of the fabricated laminates and correlating it with the effect of plasma treatment, surface characteristics, and its fracture surface. A 5% decrease in tensile strength was observed post argon plasma treatment while a 27% increase in strength was observed post nitrogen plasma treatment. The morphology of the failure surface was investigated by scanning electron microscopy and an interfacial failure was observed. Furthermore, the effect of plasma on the wettability of PBO fibres and PAEK film surface was confirmed by the Dynamic Contact Angle analysis and sessile drop method respectively. FTIR spectral analysis was done to investigate the effect of plasma treatment on the chemical structure on the surface. The results of the wettability study showed that the argon plasma treatment of the fibre surface increased its hydrophobicity while nitrogen plasma treatment resulted in the reduction of contact angle.


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