scholarly journals Methods for the Assessment of Humic Substances Quality in Forest Soils  

2013 ◽  
Vol 1 (No. 1) ◽  
pp. 3-9
Author(s):  
Mládková Lenka ◽  
Borůvka Marcela Rohošková and Luboš
Keyword(s):  
Humic Acids ◽  
Forest Soils ◽  
Beech Forest ◽  
Soil Extract ◽  
Soil Samples ◽  
Drift Spectroscopy ◽  
Organic Matter Quality ◽  
C And N ◽  
Drift Spectra ◽  
Humus Quality

This paper is focused on soil organic matter quality assessment in acid forest soils. Soil samples were collected in the Jizera Mountains region. Vegetation cover of sampling sites was formed by spruce or beech monocultures. Humus quality was assessed by the ratio of absorbances of pyrophosphate soil extract at the wavelengths of 400 and 600 nm (A400/A600). Humus fractionation was performed on selected soil samples. DRIFT spectra of individual fractions were measured. Higher pH and lower C and N contents were found in beech forest than in spruce forest. A400/A600 well correlates with C and N contents (r = 0.510*** and 0.615***, respectively). C and N content increases as to humus quality decreases. DRIFT spectra of fulvic acids turned out to be unsuitable for describing differences in humus quality. DRIFT spectra of humic acids and humin were hence more suitable. The difference between spruce and beech forest was found in 1514.cm–1 (C=C bounds of benzene rings) and 1550 cm–1 (N-H bounds in monosubstituted amides) bands intensities. Humic acids and humin coming from the O horizons of beech forest are relatively enriched by nitrogen functional groups. Values of humic acids aromaticity index did not differ between beech and spruce forests. DRIFT spectroscopy was shown as a possible method for detailed humus quality studying.

scholarly journals Differences in humic acids structure of various soil types studied by DRIFT spectroscopy

2018 ◽  
Vol 13 (No. 1) ◽  
pp. 29-35 ◽  
Author(s):  
L. Pavlů ◽  
M. Mühlhanselová
Keyword(s):  
Humic Acids ◽  
Agricultural Soils ◽  
Soil Types ◽  
Drift Spectroscopy ◽  
Aromatic Character ◽  
Diffuse Reflectance Infrared Spectroscopy ◽  
Freeze Dried ◽  
Fagus Silvatica ◽  
Diffuse Reflectance Infrared ◽  
Drift Spectra

The method of diffuse reflectance infrared spectroscopy (DRIFT) proved to be useful for studying the soil organic matter structure. The aim of this study was to compare DRIFT spectra of humic acids (HAs) separated from various soils and to identify their specific nature. Samples of agricultural soils (Dystric Cambisol, Haplic Chernozem, Greyic Phaeozem, and Haplic Luvisol) were collected from humic (A) horizons. Soil samples of reclaimed dumpsites (Haplic Technosol (molic) and (calcic)) were taken from the upper part of the soil profile. Samples of forest soils were collected from surface organic (H) horizons of Cambisols in spruce (Picea abies L. Karst.) and beech (Fagus silvatica L.) forests. The selected soil types differ in pH, carbon content, texture, and humus quality. An extraction of HAs was performed using a mixture of 0.5 M NaOH and 0.1 M Na<sub>4</sub>P<sub>2</sub>O<sub>7</sub>. The separated HAs were freeze-dried and analyzed using a DRIFT spectrometer (Thermo Nicolet Nexus) without KBr dilution. There were found differences in relative aromaticity among the agricultural soils HAs. The most aromatic character was observed in HAs from Chernozems and the least in Cambisols. Preservation of the natural structure of Chernozem HAs during the reclamation process was documented on the HAs spectra from Haplic Technosols (molic). By using the DRIFT spectra of HAs of forest H horizons, it is possible to identify the fragments of decomposed material (gymnosperms or angiosperms). HAs isolated from these horizons represent a certain interstage between lignin and the matured soil humic acids.

Impact of sewage sludge application on the humus state of sod-podzolic soil of subcarpathia under energetic willow plantation

2016 ◽  
Vol 3 (2) ◽  
pp. 26-31 ◽  
Author(s):  
V. Lopushniak ◽  
G. Hrytsulyak
Keyword(s):  
Sewage Sludge ◽  
Humic Acids ◽  
Group Composition ◽  
Podzolic Soil ◽  
Humus Content ◽  
Soil Samples ◽  
Humus State ◽  
The Impact ◽  
Sludge Application ◽  
Humus Quality

Aim. To determine the impact of energetic willow fertilization with sewage sludge (SS) and manure on the change in the humus state of sod-podzolic soil of Subcarpathia under energetic willow plantation. Methods. Soil samples were collected on the experimental fi eld of Ivano-Frankivsk College of LNAU. The humus con- tent was determined according to DSTU 4289:2004; that of its labile forms – according to DSTU 4732:2007, the content of organic matter in SS and manure – according to GOST 27980-88. Results. The application of sewage sludge for energetic willow grown in sod-podzolic soil of Subcarpathia led to the increase in the total humus content by 0.5–1.1 % compared to the control (without fertilizers). The use of SS preconditioned the change in the humus quality, including the increase in humic acids in humus by 0.05–0.07 %, which promoted the increase in the share of stable humus up to 68–70 % and the stabilization of the humus state of sod-podzolic soil. Conclusions. The application of sewage sludge impacts the change in the indices of humus quality, in particular, its group composition. The level of humic acids content in humus increases with the increase in the dose of the introduced sewage sludge and manure, based thereon. It ensures the increase in the share of stable humus in soil, which, in its turn, conditions the stabilization of humus state of sod-podzolic soil. However, this dependence weakens with depth.

scholarly journals Properties of humic acids depending on the land use in different parts of Slovakia

2021 ◽  
Author(s):  
Magdalena Banach-Szott ◽  
Bozena Debska ◽  
Erika Tobiasova
Keyword(s):  
Land Use ◽  
Organic Carbon ◽  
Size Distribution ◽  
Humic Acids ◽  
Forest Ecosystem ◽  
Soil Type ◽  
Soil Types ◽  
Organic Matter Quality ◽  
Degree Of Maturity ◽  
Effects Of Land Use

AbstractMany studies report organic carbon stabilization by clay minerals, but the effects of land use and soil type on the properties of humic acids (HAs) are missing. The aim of the paper is to determine the effects of land use and soil types on the characteristics of HAs, which have a considerable influence on organic matter quality. It was hypothesised that the effect of the land use on HAs properties depends on the particular size distribution. The research was performed in three ecosystems: agricultural, forest, and meadow, located in Slovakia. From each of them, the samples of 4 soil types were taken: Chernozem, Luvisol, Planosol, and Cambisol. The soil samples were assayed for the content of total organic carbon (TOC) and the particle size distribution. HAs were extracted with the Schnitzer method and analysed for the elemental composition, spectrometric parameters in the UV-VIS range, and hydrophilic and hydrophobic properties, and the infrared spectra were produced. The research results have shown that the properties of HAs can be modified by the land use and the scope and that the direction of changes depends on the soil type. The HAs of Chernozem and Luvisol in the agri-ecosystem were identified with a higher “degree of maturity”, as reflected by atomic ratios (H/C, O/C, O/H), absorbance coefficients, and the FT-IR spectra, as compared with the HAs of the meadow and forest ecosystem. However, as for the HAs of Cambisol, a higher “degree of maturity” was demonstrated for the meadow ecosystem, as compared with the HAs of the agri- and forest ecosystem. The present research has clearly identified that the content of clay is the factor determining the HAs properties. Soils with a higher content of the clay fraction contain HAs with a higher “degree of maturity”.

scholarly journals The influence of biochar on the content of carbon and the chemical transformations of fallow and grassland humic acids

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Marta Cybulak ◽  
Zofia Sokołowska ◽  
Patrycja Boguta
Keyword(s):  
Humic Acids ◽  
Chemical Properties ◽  
Soil Samples ◽  
Low Molecular Weight ◽  
Organic Carbon Content ◽  
Chemical Transformations ◽  
Limited Information ◽  
Grassland Soils ◽  
Low Degree ◽  
Humification Degree

AbstractThere is limited information regarding the effect of biochar (BioC) on the fertility of fallow and grassland soils, as well as on the properties of their humic acids (HAs). The objective of this study was to evaluate with a 3-year field experiment the influence of BioC on the organic matter (OM) in Haplic Luvisol. BioC (obtained via wood waste pyrolysis at 650 °C) was applied to the soil of subplots under fallow and grassland at doses of 0, 1, 2 and 3 kg m−2. The soil samples were collected eight times. The physicochemical properties were determined for the soil and BioC by analysing the density, pH, surface charge, ash, and organic carbon content. Based on the changes in the structure of the HAs and their quantity in the soils, the chemical properties of the HAs were determined. The maximum BioC dose caused an increase in the content of Corg and HAs. BioC did not influence the humification degree coefficients of the HAs originated from fallow, whereas in the grassland, there were significant changes observed in these coefficient values, indicating that BioC may stimulate and accelerate the humification process of soil HAs. Increasing the BioC doses caused an increase in the soil’s HA content, suggesting an increase in soil sorption capacity. The fluorescence data showed BioC addition to the soil caused an increase in the number of structures characterised by low molecular weight and a low degree of humification.

Post-thinning soil organic matter evolution and soil CO2 effluxes in temperate radiata pine plantations: impacts of moderate thinning regimes on the forest C cycle

2012 ◽  
Vol 42 (11) ◽  
pp. 1953-1964 ◽  
Author(s):  
Irene Fernandez ◽  
Juan Gabriel Álvarez-González ◽  
Beatríz Carrasco ◽  
Ana Daría Ruíz-González ◽  
Ana Cabaneiro
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Radiata Pine ◽  
Soil Samples ◽  
Mitigation Strategies ◽  
Change Scenario ◽  
Soil C ◽  
C Storage ◽  
C Cycle ◽  
C And N

Forest ecosystems can act as C sinks, thus absorbing a high percentage of atmospheric CO2. Appropriate silvicultural regimes can therefore be applied as useful tools in climate change mitigation strategies. The present study analyzed the temporal changes in the effects of thinning on soil organic matter (SOM) dynamics and on soil CO2 emissions in radiata pine ( Pinus radiata D. Don) forests. Soil C effluxes were monitored over a period of 2 years in thinned and unthinned plots. In addition, soil samples from the plots were analyzed by solid-state 13C-NMR to determine the post-thinning SOM composition and fresh soil samples were incubated under laboratory conditions to determine their biodegradability. The results indicate that the potential soil C mineralization largely depends on the proportion of alkyl-C and N-alkyl-C functional groups in the SOM and on the microbial accessibility of the recalcitrant organic pool. Soil CO2 effluxes varied widely between seasons and increased exponentially with soil heating. Thinning led to decreased soil respiration and attenuation of the seasonal fluctuations. These effects were observed for up to 20 months after thinning, although they disappeared thereafter. Thus, moderate thinning caused enduring changes to the SOM composition and appeared to have temporary effects on the C storage capacity of forest soils, which is a critical aspect under the current climatic change scenario.

Thermal analysis (TG-DTA) and drift spectroscopy applied to investigate the evolution of humic acids in forest soil at different vegetation stages

2006 ◽  
Vol 83 (2) ◽  
pp. 393-399 ◽  
Author(s):  
D Montecchio ◽  
O Francioso ◽  
P Carletti ◽  
D Pizzeghello ◽  
S Chersich ◽  
...  
Keyword(s):  
Thermal Analysis ◽  
Forest Soil ◽  
Humic Acids ◽  
Drift Spectroscopy

scholarly journals Drought and rewetting events enhance nitrate leaching and seepage-mediated translocation of microbes from beech forest soils

2020 ◽  
Author(s):  
Markus Krüger ◽  
Karin Potthast ◽  
Beate Michalzik ◽  
Alexander Tischer ◽  
Kirsten Küsel ◽  
...  
Keyword(s):  
Forest Soils ◽  
Nitrate Leaching ◽  
Soil Depth ◽  
Groundwater Resources ◽  
Beech Forest ◽  
Summer Drought ◽  
Ammonia Oxidizing Bacteria ◽  
Litter Layer ◽  
Drought Period ◽  
Potential Nitrification

AbstractNitrification in forest soils is often associated with increased leaching of nitrate to deeper soil layers with potential impacts on groundwater resources, further enhanced under scenarios of anthropogenic atmospheric nitrogen deposition and predicted weather extremes. We aimed to disentangle the relationships between soil nitrification potential, seepage-mediated nitrate leaching and the vertical translocation of nitrifiers in soils of a temperate mixed beech forest in central Germany before, during and after the severe summer drought 2018. Leaching of nitrate assessed below the litter layer and in 4, 16 and 30 cm soil depth showed high temporal and vertical variation with maxima at 16 and 30 cm during and after the drought period. Maximum of soil potential nitrification activity of 4.4 mg N kg-1 d-1 only partially coincided with maximum nitrate leaching of 10.5 kg N ha-2. Both ammonia oxidizing bacteria (AOB) and ammonia oxidizing archaea (AOA) were subject to translocation by seepage, and AOB decreased at least by half and AOA increased by one to three orders of magnitude in their abundance in seepage with increasing soil depth. On the level of the total bacterial population, an increasing trend with depth was also observed for Cand. Patescibacteria while Bacteroidetes were strongly mobilized from the litter layer but poorly transported further down. Despite stable population densities in soil over time, abundances of AOA, AOB and total bacteria in seepage increased by one order of magnitude after the onset of autumn rewetting. Predicted future higher frequency of drought periods in temperate regions may result in more frequent seepage-mediated seasonal flushes of nitrate and bacteria from forest soils. Moreover, the observed translocation patterns point to taxon-specific differences in the susceptibility to mobilization, suggesting that only selected topsoil derived microbial groups are likely to affect subsoil or groundwater microbial communities and their functional potential.

scholarly journals Trophic conditions of forest soils of the Pieniny National Park, southern Poland

2017 ◽  
Vol 68 (4) ◽  
pp. 205-211 ◽  
Author(s):  
Tomasz Wanic ◽  
Jan Bodziarczyk ◽  
Michał Gąsiorek ◽  
Paweł Hawryło ◽  
Agnieszka Józefowska ◽  
...  
Keyword(s):  
Plant Communities ◽  
Forest Soils ◽  
National Park ◽  
Beech Forest ◽  
Primary Objective ◽  
Forest Monitoring ◽  
Mountainous Areas ◽  
Trophic Conditions ◽  
Clay Particles ◽  
Trophic Index

Abstract The primary objective of this study was to characterise the edaphic conditions of forest areas in the Pieniny National Park (PNP), and to describe the dependencies between properties of forest soils and types of forest plant communities. The “Soil Trophic Index” (SIGg) for mountainous areas was applied. The evaluation of the trophism for 74 forest monitoring employed the soil trophic index for mountainous areas SIGg or SIGgo. Plant communities in the forest monitoring areas were classified according to the Braun-Blanquet’s phytosociological method. Soils of PNP present in the forest monitoring areas were mostly classified as eutrophic brown soils (72.9%), rendzinas (10.8%), brown rendzinas (5.41%), and rubble initial soils (5.41%). Pararendzinas, dystrophic brown soils, and gley soils were less common (total below 5.5%). In the forest monitoring areas of PNP, eutrophic soils predominate over mesotrophic soils. High SIGg index of the soils is caused by high values of acidity and nitrogen content. The Carpathian beech forest Dentario glandulosae-Fagetum and thermophilic beech forest Carici albae-Fagetum associations are characterised by high naturalness and compatibility of theoretical habitats. The soils of the Carpathian fir forest Dentario glandulosae-Fagetum abietetosum subcommunity is characterised by a higher share of silt and clay particles and lower acidity as compared to the Carpathian beech forest Dentario glandulosae-Fagetum typicum subcommunity. The soils of the forest monitoring areas in PNP stand out in terms of their fertility against forest soils in other mountainous areas in Poland.

scholarly journals Properties of Humic Acids in Meadow Soils Irrigated With the Slope-And Flooding System

2021 ◽  
Author(s):  
Magdalena Banach-Szott ◽  
Andrzej Dziamski
Keyword(s):  
Particle Size ◽  
Organic Matter ◽  
Organic Carbon ◽  
Humic Acids ◽  
Soil Samples ◽  
Hydrophobic Properties ◽  
Irrigation Ditch ◽  
Ft Ir ◽  
Degree Of Maturity

Abstract The aim of the research has been to determine the effect of many-year irrigation of unique grasslands on the properties of humic acids defining the quality of organic matter. The research was performed based on the soil (Albic Brunic Arenosol, the A, AE and Bsv horizons) sampled from Europe’s unique complex of permanent grasslands irrigated continuously for 150 years, applying the slope-and-flooding system; the Czerskie Meadows. The soil samples were assayed for the content of total organic carbon (TOC) and the particle size distribution. HAs were extracted with the Schnitzer method and analysed for the elemental composition, spectrometric parameters in the UV-VIS range, hydrophilic and hydrophobic properties and the infrared spectra were produced. The research results have shown that the HAs properties depended on the depth and the distance from the irrigation ditch. The HAs of the A horizon of the soils were identified with a lower “degree of maturity”, as reflected by the values of atomic ratios (H/C, O/C, O/H), absorbance coefficients, and the FT-IR spectra, as compared with the HAs of the Bsv horizon. The HAs molecules of the soils sampled furthest from the irrigation ditch were identified with a higher degree of humification, as compared with the HAs of the soils sampled within the closest distance. The results have demonstrated that many-year grassland irrigation affected the structure and the properties of humic acids.

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