Processing technology for carbonate ore from the Argun deposit

2021 ◽  
pp. 86-91
Author(s):  
V. V. Golovko ◽  
E. Yu. Meshkov ◽  
V. G. Litvinenko

Priargun Mining and Chemical Association has been producing uranium in the Streltsov ore field for more than 50 years. The main ore bodies with high content of uranium have been mined out during this period of time, and the uranium content has dropped in ore which is currently extracted. In connection with this, appraisal of the mineral resources and mineral reserves of Priargun MCA has been accomplished. The Argun ore is composed of a few process types—iron silicate and uranium, silicate–uranium–molybdenum, carbonate and uranium, carbonate and molybdenum, carbonate–uranium–molybdenum and rebellious ore (contains zirconium and brannerite). It is required to undertake technology-based rating and certification of the Argun ore. The autoclave leaching technology is found to be higher economically efficient as against the atmospheric leaching technology due to lower operating expenses. From the preliminary studies, four samples of anion-exchange resins are recommended for further testing: A500Y, BM77-14, D299 and Ambersep 920UXL SO4. These ion-exchangers were used to analyze their influence on sorption–desorption of uranium and molybdenum. All these ion exchangers had preserved their sorption capacity in 10 sorption–desorption cycles. Based on the studies into adsorption of uranium and molybdenum from leached slurry at the Argun deposit, the optimal sorbent for extraction and separation of uranium and molybdenum is Ambersep 920UXL SO4. Producibility of natural uranium to meet ASTM C 967-13 standards is analyzed on a laboratory scale. The produced uranium concentrate contains much less impurities than it is stipulated by International Standard Specification ASTM С 967-13. The action chart of processing of carbonate ore from the Argun and Zherlovoe deposits is developed and economically justified.

1999 ◽  
Vol 40 (9) ◽  
pp. 207-214 ◽  
Author(s):  
J.-P. Croué ◽  
D. Violleau ◽  
C. Bodaire ◽  
B. Legube

The objective of this work was to compare the affinity of well characterized NOM fractions isolated from two surface waters with strong (gel matrix and macroporous matrix) and weak anion exchange resins (AER) using batch experiment conditions. The structural characterization of the fraction of NOM has shown that the higher the hydrophilic character, the lower the C/O atomic ratio, the lower the SUVA, the lower the aromatic carbon content and the lower the molecular weight. In general (not always), strong AER was more efficient to remove DOC than weak AER. For the same water source (Suwannee River), the higher the molecular weight of the NOM fraction, the lower the affinity with AER. Increasing the ionic strength favored the removal of the hydrophobic NOM fraction (“salting out” effect) while increasing the pH apparently reduced the removal of the hydrophilic NOM fraction. Results were discussed in terms of size exclusion, adsorption, anion exchange and also hydrophobic/hydrophilic repulsion.


2020 ◽  
pp. 039139882094773
Author(s):  
Karin Strobl ◽  
Stephan Harm ◽  
Ute Fichtinger ◽  
Claudia Schildböck ◽  
Jens Hartmann

Introduction: Heparin and citrate are commonly used anticoagulants in membrane/adsorption based extracorporeal liver support systems. However, anion exchange resins employed for the removal of negatively charged target molecules including bilirubin may also deplete these anticoagulants due to their negative charge. The aim of this study was to evaluate the adsorption of citrate by anion exchange resins and the impact on extracorporeal Ca2+ concentrations. Methods: Liver support treatments were simulated in vitro. Citrate and Ca2+ concentrations were measured pre and post albumin filter as well as pre and post adsorbents. In addition, batch experiments were performed to quantify citrate adsorption. Results: Pre albumin filter target Ca2+ concentrations were reached well with only minor deviations. Citrate was adsorbed by anion exchange resins, resulting in a higher Ca2+ concentration downstream of the adsorbent cartridges during the first hour of treatment. Conclusions: The anion exchange resin depletes citrate, leading to an increased Ca2+ concentration in the extracorporeal circuit, which may cause an increased risk of clotting during the first hour of treatment. An increase of citrate infusion during the first hour of treatment should therefore be considered to compensate for the adsorption of citrate.


2016 ◽  
Vol 75 (6) ◽  
pp. 1309-1318 ◽  
Author(s):  
Ying Wang ◽  
Zhun Li ◽  
Yansheng Li ◽  
Zhigang Liu

Fouled anion exchange resins were regenerated by electric field intensification of Mg/Al double-metal hydroxides. Regenerative experiments were performed with varying voltages (10–30 V) and dosages of Mg/Al hydroxides (0.045–0.135 mol and 0.015–0.045 mol, respectively) for 1–5 h. Optimal results were obtained under the following regenerative conditions: 20 V, 4 h, and 0.09/0.03 mol of Mg/Al hydroxides. The maximum regenerative capacity of resins was increased to 41.07%. The regenerative mechanism was presented by Fourier-transform infrared spectrum of resins and Mg/Al hydroxides, and the regenerative degree was analyzed with respect to conductivity, pH value, and electric current. Mg/Al hydroxides were also recycled after the regeneration. This method was proven to be cost-effective and environmentally friendly.


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