scholarly journals Investigation of Inhibitor Polyphosphate Properties for Rotating Steel Disk Electrode in Potassium Nitrate Solution

2016 ◽  
Vol 2 (2) ◽  
pp. 167
Author(s):  
E.A. Dorokhova ◽  
B.D. Burkitbaeva ◽  
I.B. Melsitova ◽  
T.Z. Ahkmetov ◽  
V.I. Kapralova

<p>Inhibition properties of a number of glass-like polyphosphates on 65J steel were investigated using the gravimetry and methods potassium nitrate solution polarization curves in a 0,1M (pH=6,05). The possibilities<br />of optimum experimental conditions were considered as well. Basing on the experimental data the inhibition coefficient and protective effect were found. The inhibiting action of polyphosphates, apparently, is due to the formation of inhomogeneous protecting film on the steel surface.</p>

Soil Research ◽  
1979 ◽  
Vol 17 (2) ◽  
pp. 271 ◽  
Author(s):  
AS Black ◽  
SA Waring

Soil was collected from a number of sites and depths to 300 cm within four great soil groups (krasnozem, red earth, xanthozem, podzolic). Nitrate, chloride and sulfate adsorption were determined at the soil pH. Various soil properties likely to influence the magnitude of adsorption were determined, and their relative importance to adsorption was assessed using stepwise multiple regression. The subsoils of all four soil groups adsorbed nitrate ranging up to 0.47 mmoles/100 g from 0.005 M potassium nitrate solution. The mean adsorption for soil groups decreased in the order krasnozem, xanthozem, red earth and podzolic. Chloride and sulfate adsorption was largely equivalent to that of nitrate. The variations in adsorption between and within great soil groups could be attributed to changes in organic matter, smectite minerals, hydroxy aluminium, surface area and pH.


1999 ◽  
Vol 9 (2) ◽  
pp. 213-216 ◽  
Author(s):  
Thomas S.C. Li ◽  
Douglas A. Wardle

The influence of seed treatments and planting depth on the percentage of seed emergence of Hippophae rhamnoides L. `Indian-Summer', H. tibetana Schlecht., H. neurocarpa Liu & He, H. salicifolia D. Don, and H. rhamnoides subsp. rhamnoides, sinensis, turkestanica, and mongolica were studied. Surface seeding had higher percentages of seed emergence and more rapid completion of emergence compared to a 1- or 2-cm (0.4- or 0.8-inch) seeding depth. Seeds soaked in water or potassium nitrate solution at room temperature emerged in higher percentages. Average plant height of the eight species and subspecies varied significantly at the end of first growing season.


Soil Research ◽  
1976 ◽  
Vol 14 (2) ◽  
pp. 181 ◽  
Author(s):  
AS Black ◽  
SA Waring

Laboratory determinations of nitrate adsorption from a 0.005M potassium nitrate solution indicated that exclusion occurred in soil from 0-20 cm and that adsorption increased through the subsoil from 0.16 m-equiv./100 g at 45-90 cm to 0.45 m-equiv./100 g between 360 and 600 cm. These profile changes appeared to be related to decreases in organic matter and pH and increases in kaolinite content. Correlation studies showed a strong relation (r = 0.87) between nitrate adsorption and relative net charge as measured by �pH (pHKCl pHH2O) and a negative relation (r = -0.67) with pHH2O. Correlations with sesquioxide fractions were variable and mostly negative.


2010 ◽  
Vol 32 (4) ◽  
pp. 151-157 ◽  
Author(s):  
Beatriz Gonçalves Brasileiro ◽  
Denise Cunha F. S. Dias ◽  
Vicente Wagner Dias Casali ◽  
Maria Carmen Bhering ◽  
Paulo Roberto Cecon

The objective of this study was to evaluate the effects of temperature, substrate and pre-germinative treatments on T. triangulare seeds. Four temperatures (constant 20, 25, 30 °C and alternate 20-30 °C) and two types of seeding (on paper and between paper), with light, were evaluated. The pre-germinative treatments evaluated included: immersion in water (24 hours), immersion in 6% hypochlorite solution (1 hour), immersion in 0.2% potassium nitrate solution (24 hours), immersion in 0.05% gibberellin solution (24 hours) and the control (untreated seeds). The highest germination percentage was observed at the alternate temperatures of 20-30 ºC, but with no significant difference between the substrates at this temperature. Soaking seeds in KNO3 gave the highest percentage germination and germination speed index (GSI), which differed from the other treatments except for soaking in water. Pre-soaking of T. triangulare seeds favors germination and may be done only in pure water, resulting in a more rapid and uniform germination.


1955 ◽  
Vol s3-96 (36) ◽  
pp. 411-421
Author(s):  
WALTER CLIFFORD JONES

Dilute hydrochloric acid, carbonic acid, and potassium nitrate solutions dissolve the spicule calcite revealing a thin, partially contracted sheath. Corrosion by potash solution, however, produces a rigid, brittle ‘sheath’, which consists of the true sheath and an inorganic deposit laid down on its inner surface as the calcite dissolves away. The oscular rays, gastral rays, and curved monaxons corrode much more rapidly than the basal rays and slender monaxons in potash solution, and the corrosion is most noticeable on the surfaces transverse to the optic axis, particularly when dilute potash is used. Potassium nitrate solution and water, however, corrode the surfaces parallel to the optic axis, whereas in hydrochloric and carbonic acid solutions the calcite dissolves uniformly all round the rays. When spicules bearing calcite crystals are corroded, the calcite of the spicules dissolves more rapidly than the crystals, which then remain attached to the sheath and appear to have crystallized upon it, though attempts to crystallize calcite upon isolated sheaths, or sheaths supported by the inorganic deposit, have been unsuccessful. The evidence suggests that when crystals form on the spicule surface they are oriented by crystallizing on the calcite through perforations in the sheath.


1956 ◽  
Vol s3-97 (38) ◽  
pp. 269-285
Author(s):  
WALTER CLIFFORD JONES

Oscular tubes rapidly collapse and disperse in isotonic potassium nitrate solution, the cells dissociating and rounding off, and the mesogloea softening and swelling. Reasons are given for regarding the action as a direct one on the mesogloea and intercellular ‘cement’. Transference of the collapsing tubes to sea-water, or isotonic calcium chloride, results in an immediate stiffening of the mesogloea, and the swollen cells form characteristic processes which are best seen after the cells have been in the nitrate solution for an optimum period depending on the temperature. They are not formed after treatment with M/100 potassium cyanide. The action of other isotonic salt solutions is briefly described. When a comparison is made of the times taken for the tubes to become plastic, the ions respectively used fall into three series which are the same as those found in regard to the dispersiveness of certain hydrophilic organic colloids. The experiments provide evidence that the mesogloea is secreted by the choanocytes or by the amoebocytes close beneath them, and that the secretion stiffens into a firmer gel as it passes into the spicule zone. The degree of firmness also varies apparently according to the health of the tube. The action of distilled water and acidified sea-water are described. After the spicules have dissolved the tube still retains its shape and much of its support can thus derive from the mesogloea. The relative functions of the mesogloea and the spicules are briefly discussed.


Soil Research ◽  
1976 ◽  
Vol 14 (2) ◽  
pp. 189 ◽  
Author(s):  
AS Black ◽  
SA Waring

Nitrate adsorption and movement was studied in soil from depths of 0-15, 40-90 and 160-300 cm. Adsorption was determined at concentrations ranging from 0.5 x 10-3 to 0.5M potassium nitrate and movement by adding 0, 3, 12 and 120 mg nitrogen15 ml of a potassium nitrate solution to packed columns and leaching with deionized water or 0.2M potassium sulphate. In the 0-15 cm soil, nitrate exclusion was evident in both the adsorption and movement studies at low concentrations, but no effect was measured at high concentrations. In the two subsoils, adsorption increased with concentration to 1.9 m-equiv./100 g when equilibrated with 0.5M potassium nitrate. In the subsoils the depth of leaching of nitrate increased with nitrate concentration; the nitrate distribution was skewed; and the rate of nitrate movement was less than that of water. Addition of sulphate to the subsoils resulted in nitrate movement being similar to that of water. The results are discussed in terms of nitrate adsorption. Comparisons with field observations provide further evidence that adsorption is a major process influencing leaching in these soils.


1970 ◽  
Vol 25 (12) ◽  
pp. 1453-1457 ◽  
Author(s):  
Ram Nayan ◽  
Arun K. Dey

Stepwise formation constants of folic acid, N-[p-[[ (2-amino-4-hydroxy-6-pteridyl) methyl] amino] benzyl] glutamic acid, with the carcinogenic metal ions, aluminium (III), chromium (III), beryllium (II), lead (II) and uranium (VI) have been determined at 30 °C, and at various ionic strengths, viz. 0.01 ᴍ, 0.05 ᴍ, 0.10 ᴍ, maintained by potassium nitrate solution. The formation of the chelate is evident from the shift between the (i) ligand and (ii) ligand and metal titration curves. From the values for the stepwise protonation constants and metal-ligand stability constants at various ionic strengths, thermodynamic formation constants were evaluated by extrapolation to zero ionic concentration. Logarithms of the overall thermodynamic stability constants (log Kμ=0) are: 20.40 for H-; 15.15 for Al-; 10.10 for Cr-; 9.35 for Be-; 6.50 for Pb-; 9.00 for U-chelates. Corresponding free energy changes (ΔF0) are -28.47, -21.14, -14.09, -13.05, -9.07, -12.56 K · Cal · mol-1 respectively


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