scholarly journals Improve Performance of Soy Flour Based-Adhesive with a Lignin Based Resin

Author(s):  
Xiaochun Zhang ◽  
Yuding Zhu ◽  
Youming Yu ◽  
Jiangang Song

The aim of this study was to using a lignin based resin (LB) to improve the performance of the soy flour based adhesive. Soy flour (SF), polyamidoamine-epichlorohydrin (PAE), LB was used to develop a plywood adhesive. The solid content and viscosity of the adhesive, functional groups, thermo-stability, and crystallinity of the cured adhesive were characterized and the performance of the resultant adhesive was evaluated by fabricating three-ply plywood. Results showed using LB and PAE mixture to modify SF adhesive improves dry and wet bond strength by 66.3 and 184.2%. PAE contributed more for the wet bond strength improvement and the LB contributed more for the dry bond strength. The improvement was attributed to: 1) LB/PAE reacted with the functions of the soy protein and form a cross-linking network; 2) Polycondensation reaction between LB molecules further improved crosslinking density of the adhesive and formed a interpenetration structure with crosslinked protein; 3)The easy penetration of LB on wood surface and formed more interlock with wood. The denser structure created by LB and PAE mixture improved the thermal stability and decreased the crystallinity of cured adhesive. The usage of the LB and PAE mixture increased solid content by 35.5%, meanwhile, makes its viscosity acceptable for the industrial application.

Holzforschung ◽  
2012 ◽  
Vol 66 (7) ◽  
pp. 857-862 ◽  
Author(s):  
Guangbo He ◽  
Martin Feng ◽  
Chunping Dai

Abstract Soy-based resins have recently attracted great attention as adhesives in the wood composite industry. This article is focusing on hydrolysis and modification of soy protein concentrates to formulate soy-based resins for wood composites. The soy-based resins have been evaluated in terms of bondability on wood substrates and bonding performance in plywood products. The performance of plywood was found to meet the relevant CSA standard (Canadian Standard Association) requirements under both of dry and wet conditions, if the soy-based resins were obtained from low hydrolyzed soy flour. Hydrolysis is an effective and efficient tool for reducing the viscosity of soy resins. However, hydrolysis also reduces the bond strength of soy-based resins as hydrolysis cleaves the macromolecules of soy proteins into smaller molecules. Modified soy-based resins have a certain potential for production of interior- and exterior-used plywood.


2011 ◽  
Vol 25 ◽  
pp. 471-474 ◽  
Author(s):  
Nathan E. Glavitz ◽  
LaVern A. Starman ◽  
Ronald A. Coutu ◽  
Richard L. Johnston

2018 ◽  
Vol 34 (2) ◽  
pp. 288-295 ◽  
Author(s):  
Annalisa Mazzoni ◽  
Valeria Angeloni ◽  
Allegra Comba ◽  
Tatjana Maravic ◽  
Milena Cadenaro ◽  
...  
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Author(s):  
ROSANE DA SILVA RODRIGUES ◽  
ÂNGELA MARIA GOZZO ◽  
ROBERTO HERMÍNIO MORETTI

Estudou-se o comportamento reológico de extratos elaborados com grãos, farinha integral e isolado protéico de soja. Extratos com 3% de proteína foram obtidos de grãos de soja (em equipamento conhecido como “vaca mecânica”), de farinha integral e de isolado protéico (por dissolução em água) e pasteurizados a 74±2°C por 15 seg. Os parâmetros reológicos estudados foram o coeficiente de consistência, o índice de comportamento do fluxo e a viscosidade aparente. Foram determinados, também, sólidos totais, proteínas, lipídios, cinzas, fibra bruta, carboidratos e índice de sedimentação (AOAC, 1995). Verificou-se que a viscosidade aparente, a 4 e 25°C, do extrato obtido de grãos de soja (fluido nãonewtoniano com comportamento pseudoplástico) foi maior que a do extrato da farinha (fluido não-newtoniano com comportamento pseudoplástico a 4°C e dilatante a 25°C) e do isolado (fluido newtoniano). O maior índice de sedimentação constatado no extrato de farinha integral e o baixo teor de sólidos solúveis no isolado protéico foram determinantes, entre outros fatores, no comportamento reológico verificado. AbstractRHEOLOGICAL BEHAVIOR OF SOYMILK, WHOLE SOY FLOUR AND SOY ISOLATED PROTEIN The rheological properties of extracts elaborated with soybeans, whole soy flour and isolated protein were studied. Extracts with 3% of protein were obtained from soybeans (in a equipment called “mechanic cow”), whole soy flour and isolated soy protein (by dissolution in water) and pasteurized at 74±2°C for 15 seg. The rheological parameters studied were the flow behavior index, consistency coefficient and apparent viscosity. Total solid, proteins, lipids, ashes, brute fiber, carbohydrates and sedimentation index (AOAC, 1995) was also determined. The apparent viscosity, at 4 and 25°C, of the extract obtained from soybeans (non-newtonian fluid with pseudoplastic behavior), was greater than the one of whole soy flour extract (nonnewtonian fluid with pseudoplastic behavior at 4°C and dilatant at 25°C) and of the isolated soy protein extract (Newtonian fluid). The highest sedimentation index verified in the whole soy flour extract and the low content of soluble solids in the extract of isolated soy protein defined, among others factors, the rheological behavior verified.


2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Jong Sung Won ◽  
Ji Eun Lee ◽  
Da Young Jin ◽  
Seung Goo Lee

The effective utilization of original natural fibers as indispensable components in natural resins for developing novel, low-cost, eco-friendly biocomposites is one of the most rapidly emerging fields of research in fiber-reinforced composite. The objective of this study is to investigate the interfacial adhesion properties, water absorption, biodegradation properties, and mechanical properties of the kenaf/soy protein isolate- (SPI-) PVA composite. Experimental results showed that 20 wt% poly (vinyl alcohol) (PVA) and 8 wt% glutaraldehyde (GA) created optimum conditions for the consolidation of the composite. The increase of interfacial shear strength enhanced the composites flexural and tensile strength of the kenaf/SPI-PVA composite. The kenaf/SPI-PVA mechanical properties of the composite also increased with the content of cross-linking agent. Results of the biodegradation test indicated that the degradation time of the composite could be controlled by the cross-linking agent. The degradation rate of the kenaf/SPI-PVA composite with the cross-linking agent was lower than that of the composite without the cross-linking agent.


2012 ◽  
Vol 51 (46) ◽  
pp. 15109-15121 ◽  
Author(s):  
S. Sinha-Ray ◽  
S. Khansari ◽  
A. L. Yarin ◽  
B. Pourdeyhimi

2009 ◽  
Vol 91B (1) ◽  
pp. 419-424 ◽  
Author(s):  
Aiman Al-Ammar ◽  
James L. Drummond ◽  
Ana Karina Bedran-Russo

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