scholarly journals Mushroom’s Evaluation Based on FT-IR Fingerprint and Chemometrics

2021 ◽  
Author(s):  
Ioana Feher ◽  
Cornelia Veronica Floare-Avram ◽  
Florina-Dorina Covaciu ◽  
Olivian Marincas ◽  
Romulus Puscas ◽  
...  
Keyword(s):  
Principal Component ◽  
Therapeutic Effects ◽  
Data Set ◽  
Linear Discriminant ◽  
Long Time ◽  
Fuzzy C Means Clustering ◽  
Ft Ir ◽  
Ir Analysis ◽  
Fcm Analysis ◽  
Sample Set

Edible mushrooms have been recognized as highly nutritional food for a long time, due to their specific flavor, texture and also for therapeutic effects. This study proposes a new simple approach, based on FT-IR analysis, followed by statistical methods, in order to differentiate three wild mushrooms species from Romanian spontaneous flora, namely Armillaria mellea, Boletus edulis and Cantharellus cibarius. The preliminary data treatment consisted of data set reduction with principal component analysis (PCA), which provided scores for the next methods. Linear discriminant analysis (LDA) manage to 100% classify the three species and the cross validation step of the method returned 97.4% of correctly classified samples. Only one A. mellea sample overlapped on B. edulis group. When kNN was used in the same manner as LDA, the overall percent of correctly classified samples from the training step was 86.21%, while for holdout set the percent raised at 94.74%. The lowered values obtained for the training set was due to one C. cibarius sample, two B. edulis and five A. mellea, which were placed to other species. Anyway, for holdout sample set, only one sample from B. edulis was misclassified. The fuzzy c-means clustering (FCM) analysis successfully classified investigated mushroom samples according to their species, meaning that in every partition the predominant specie had the biggest DOMs, while samples belonging to other specie had lower DOMs.

scholarly journals Evaluation of Mushrooms Based on FT-IR Fingerprint and Chemometrics

2021 ◽  
Vol 11 (20) ◽  
pp. 9577
Author(s):  
Ioana Feher ◽  
Cornelia Veronica Floare-Avram ◽  
Florina-Dorina Covaciu ◽  
Olivian Marincas ◽  
Romulus Puscas ◽  
...  
Keyword(s):  
Principal Component ◽  
Therapeutic Effects ◽  
Mushroom Species ◽  
Data Set ◽  
Linear Discriminant ◽  
Long Time ◽  
Fuzzy C Means Clustering ◽  
Ft Ir ◽  
Fcm Analysis ◽  
Sample Set

Edible mushrooms have been recognized as a highly nutritional food for a long time, thanks to their specific flavor and texture, as well as their therapeutic effects. This study proposes a new, simple approach based on FT-IR analysis, followed by statistical methods, in order to differentiate three wild mushroom species from Romanian spontaneous flora, namely, Armillaria mellea, Boletus edulis, and Cantharellus cibarius. The preliminary data treatment consisted of data set reduction with principal component analysis (PCA), which provided scores for the next methods. Linear discriminant analysis (LDA) managed to classify 100% of the three species, and the cross-validation step of the method returned 97.4% of correctly classified samples. Only one A. mellea sample overlapped on the B. edulis group. When kNN was used in the same manner as LDA, the overall percent of correctly classified samples from the training step was 86.21%, while for the holdout set, the percent rose to 94.74%. The lower values obtained for the training set were due to one C. cibarius sample, two B. edulis, and five A. mellea, which were placed to other species. In any case, for the holdout sample set, only one sample from B. edulis was misclassified. The fuzzy c-means clustering (FCM) analysis successfully classified the investigated mushroom samples according to their species, meaning that, in every partition, the predominant species had the biggest DOMs, while samples belonging to other species had lower DOMs.

scholarly journals Application of Spectroscopic UV-Vis and FT-IR Screening Techniques Coupled with Multivariate Statistical Analysis for Red Wine Authentication: Varietal and Vintage Year Discrimination

Molecules ◽  
2019 ◽  
Vol 24 (22) ◽  
pp. 4166 ◽  
Author(s):  
Elisabeta-Irina Geană ◽  
Corina Teodora Ciucure ◽  
Constantin Apetrei ◽  
Victoria Artem
Keyword(s):  
Discriminant Analysis ◽  
Principal Component ◽  
Total Variance ◽  
Red Wines ◽  
Linear Discriminant ◽  
Vis Spectroscopy ◽  
Ft Ir ◽  
Wine Authentication ◽  
Analytical Approaches

One of the most important issues in the wine sector and prevention of adulterations of wines are discrimination of grape varieties, geographical origin of wine, and year of vintage. In this experimental research study, UV-Vis and FT-IR spectroscopic screening analytical approaches together with chemometric pattern recognition techniques were applied and compared in addressing two wine authentication problems: discrimination of (i) varietal and (ii) year of vintage of red wines produced in the same oenological region. UV-Vis and FT-IR spectra of red wines were registered for all the samples and the principal features related to chemical composition of the samples were identified. Furthermore, for the discrimination and classification of red wines a multivariate data analysis was developed. Spectral UV-Vis and FT-IR data were reduced to a small number of principal components (PCs) using principal component analysis (PCA) and then partial least squares discriminant analysis (PLS-DA) and linear discriminant analysis (LDA) were performed in order to develop qualitative classification and regression models. The first three PCs used to build the models explained 89% of the total variance in the case of UV-Vis data and 98% of the total variance for FR-IR data. PLS-DA results show that acceptable linear regression fits were observed for the varietal classification of wines based on FT-IR data. According to the obtained LDA classification rates, it can be affirmed that UV-Vis spectroscopy works better than FT-IR spectroscopy for the discrimination of red wines according to the grape variety, while classification of wines according to year of vintage was better for the LDA based FT-IR data model. A clear discrimination of aged wines (over six years) was observed. The proposed methodologies can be used as accessible tools for the wine identity assurance without the need for costly and laborious chemical analysis, which makes them more accessible to many laboratories.

scholarly journals Rotating Machinery Fault Diagnosis for Imbalanced Data Based on Fast Clustering Algorithm and Support Vector Machine

2017 ◽  
Vol 2017 ◽  
pp. 1-15 ◽  
Author(s):  
Xiaochen Zhang ◽  
Dongxiang Jiang ◽  
Te Han ◽  
Nanfei Wang ◽  
Wenguang Yang ◽  
...  
Keyword(s):  
Support Vector Machine ◽  
Fault Diagnosis ◽  
Clustering Algorithm ◽  
Imbalanced Data ◽  
Principal Component ◽  
Rotating Machinery ◽  
Support Vector ◽  
Data Set ◽  
Diagnosis Model ◽  
Sample Set

To diagnose rotating machinery fault for imbalanced data, a method based on fast clustering algorithm (FCA) and support vector machine (SVM) was proposed. Combined with variational mode decomposition (VMD) and principal component analysis (PCA), sensitive features of the rotating machinery fault were obtained and constituted the imbalanced fault sample set. Next, a fast clustering algorithm was adopted to reduce the number of the majority data from the imbalanced fault sample set. Consequently, the balanced fault sample set consisted of the clustered data and the minority data from the imbalanced fault sample set. After that, SVM was trained with the balanced fault sample set and tested with the imbalanced fault sample set so the fault diagnosis model of the rotating machinery could be obtained. Finally, the gearbox fault data set and the rolling bearing fault data set were adopted to test the fault diagnosis model. The experimental results showed that the fault diagnosis model could effectively diagnose the rotating machinery fault for imbalanced data.

scholarly journals An MPCA/LDA Based Dimensionality Reduction Algorithm for Face Recognition

2014 ◽  
Vol 2014 ◽  
pp. 1-12 ◽  
Author(s):  
Jun Huang ◽  
Kehua Su ◽  
Jamal El-Den ◽  
Tao Hu ◽  
Junlong Li
Keyword(s):  
Face Recognition ◽  
Nearest Neighbor ◽  
Recognition Accuracy ◽  
Principal Component ◽  
Feature Space ◽  
Recognition Algorithm ◽  
Linear Discriminant ◽  
Face Images ◽  
Sample Set ◽  
Multilinear Principal Component Analysis

We proposed a face recognition algorithm based on both the multilinear principal component analysis (MPCA) and linear discriminant analysis (LDA). Compared with current traditional existing face recognition methods, our approach treats face images as multidimensional tensor in order to find the optimal tensor subspace for accomplishing dimension reduction. The LDA is used to project samples to a new discriminant feature space, while theKnearest neighbor (KNN) is adopted for sample set classification. The results of our study and the developed algorithm are validated with face databases ORL, FERET, and YALE and compared with PCA, MPCA, and PCA + LDA methods, which demonstrates an improvement in face recognition accuracy.

SHORT PROKARYOTIC DNA FRAGMENT BINNING USING A HIERARCHICAL CLASSIFIER BASED ON LINEAR DISCRIMINANT ANALYSIS AND PRINCIPAL COMPONENT ANALYSIS

2010 ◽  
Vol 08 (06) ◽  
pp. 995-1011 ◽  
Author(s):  
HAO ZHENG ◽  
HONGWEI WU
Keyword(s):  
Principal Component Analysis ◽  
Discriminant Analysis ◽  
Linear Discriminant Analysis ◽  
Simulated Data ◽  
Principal Component ◽  
Component Analysis ◽  
Dna Fragments ◽  
Data Set ◽  
Linear Discriminant ◽  
Hierarchical Classifier

Metagenomics is an emerging field in which the power of genomic analysis is applied to an entire microbial community, bypassing the need to isolate and culture individual microbial species. Assembling of metagenomic DNA fragments is very much like the overlap-layout-consensus procedure for assembling isolated genomes, but is augmented by an additional binning step to differentiate scaffolds, contigs and unassembled reads into various taxonomic groups. In this paper, we employed n-mer oligonucleotide frequencies as the features and developed a hierarchical classifier (PCAHIER) for binning short (≤ 1,000 bps) metagenomic fragments. The principal component analysis was used to reduce the high dimensionality of the feature space. The hierarchical classifier consists of four layers of local classifiers that are implemented based on the linear discriminant analysis. These local classifiers are responsible for binning prokaryotic DNA fragments into superkingdoms, of the same superkingdom into phyla, of the same phylum into genera, and of the same genus into species, respectively. We evaluated the performance of the PCAHIER by using our own simulated data sets as well as the widely used simHC synthetic metagenome data set from the IMG/M system. The effectiveness of the PCAHIER was demonstrated through comparisons against a non-hierarchical classifier, and two existing binning algorithms (TETRA and Phylopythia).

scholarly journals Fatty Acids-Based Quality Index to Differentiate Worldwide Commercial Pistachio Cultivars

2018 ◽  
Author(s):  
Mahnaz Esteki ◽  
Parvin Ahmadi ◽  
Yvan Vander Heyden ◽  
Jesus Simal-Gandara
Keyword(s):  
Fatty Acid ◽  
Quality Index ◽  
Predictive Power ◽  
Principal Component ◽  
Chromatographic Fingerprint ◽  
Data Set ◽  
Linear Discriminant ◽  
Fatty Acid Data ◽  
Percent Accuracy ◽  
Almost All

The fatty-acid profiles of five main commercial pistachio cultivars, including Ahmad-Aghaei, Akbari, Chrok, Kalle-Ghouchi and Ohadi, were determined by gas chromatography: palmitic (C16:0), palmitoleic (C16:1), stearic (C18:0), oleic (C18:1), linoleic (C18:2), linolenic (C18:3) arachidic (C20:0) and gondoic (C20:1) acid. Based on the oleic to linoleic acid (O/L) ratio, a quality index was determined for these five cultivars: Ohadi (2.40) < Ahmad-Aghaei (2.60) < Kale-Ghouchi (2.94) < Chrok (3.05) < Akbari (3.66). Principal component analysis (PCA) of the fatty-acid data yielded three significant PCs, which together account for 80.0% of the total variance in the data set. A linear discriminant analysis (LDA) model evaluated with cross validation correctly classified almost all samples: the average percent accuracy for the prediction set was 98.0%. The high predictive power for the prediction set shows the ability to indicate the cultivar of an unknown sample based on its fatty-acid chromatographic fingerprint.

scholarly journals Chemometric approach to quality characterization of milk-based kombucha beverages

Mljekarstvo ◽  
2021 ◽  
Vol 71 (2) ◽  
pp. 83-94
Author(s):  
Jasmina Vitas ◽  
Keyword(s):  
Fatty Acids ◽  
Milk Fat ◽  
Unsaturated Fatty Acids ◽  
Principal Component ◽  
Unknown Origin ◽  
Hierarchical Cluster ◽  
Monounsaturated Fatty Acids ◽  
Data Set ◽  
Linear Discriminant

Milk-based kombucha beverages were obtained conducting kombucha lead fermentation of milk. In order to discriminate the analysed samples and to detect similarities or dissimilarities among them in the space of experimentally determined variables, hierarchical cluster analysis (HCA) and principal component analysis (PCA) were applied. Linear discriminant analysis (LDA) was conducted on the raw data set in order to find a rule for allocating a new sample of unknown origin to the correct group of samples. In the space of the variables analysed by HCA, the dominant discriminating factor for the studied samples of kombucha beverages is the milk fat (MF) content, followed by total unsaturated fatty acids content (TUFA), monounsaturated fatty acids content (MUFA) and polyunsaturated fatty acids content (PUFA). The samples with 0.8 and 1.6% milk fat belong to the same cluster in the space of the analysed variables due to similarities in their AADPPH. It was determined by LDA that there was the biggest difference in quality between the groups of products with winter savoury and stinging nettle, while the highest similarity is between groups of products with wild thyme and peppermint regarding their pH values and antioxidant activity expressed as AADPPH.

scholarly journals Assessment of Under Five Child Mortality in Tanzania Mainland Based on Principal Component Analysis

2019 ◽  
pp. 1-13
Author(s):  
Privatus Christopher
Keyword(s):  
Principal Component Analysis ◽  
Child Mortality ◽  
Vitamin A Deficiency ◽  
Principal Component ◽  
Original Data ◽  
Component Analysis ◽  
Data Set ◽  
Under Five ◽  
Long Time ◽  
Main Components

Deaths of children younger than 5 years has been a global problem for long time. This study is focused on evaluating diseases that caused under five child mortality in Tanzania in 2013. Diseases that causes child mortality were collected from 25 regions and analysed for 42 disease variables. The data obtained were standardized and subjected to principal component analysis (PCA) to define the diseases responsible for the variability in child mortality. PCA produced seven significant main components that explain 73:40% of total variance of the original data set. The results reveal that Thyroid Diseases, Snake and Insect Bites, Vitamin A Deficiency /Xerophthalmia, Eye Infections, Schistosomiasis (SS), Intestinal Worms, Ear Infections, Haematological Diseases, Diabetes Mellitus, Ill Defined Symptoms no Diagnosis, Poisoning, Anaemia, HIV/AIDS, Burns, Rheumatic Fever, Bronchial Asthma, Peri-natal conditions and Urinary tract infection are most significant diseases in assessing under five child mortality in Tanzania mainland. This study suggest that PCA technique is useful tool for identification of important diseases that causes death of children less than five years.

scholarly journals Characterization of Indonesia wild honey and its potential for authentication and origin distinction

Food Research ◽  
2020 ◽  
Vol 4 (5) ◽  
pp. 1670-1680
Author(s):  
Y. Riswahyuli ◽  
A. Rohman ◽  
F.M.C.S. Setyabudi ◽  
S. Raharjo
Keyword(s):  
Ph Value ◽  
Sugar Content ◽  
Antioxidant Properties ◽  
Principal Component ◽  
Food Product ◽  
Natural Food ◽  
Data Set ◽  
Linear Discriminant ◽  
Geographical Regions ◽  
Antioxidant Parameters

Honey is a natural food derived from flowers nectar that has many health benefits. This reason made honey become one of category food product that has a risk to be adulterated because of economically motivation. This study was conducted for characterization and authentication of Indonesia wild honey (IWH) collected from seven geographical regions (Sumatra, Bangka Belitung, Java, Kalimantan, Sulawesi, West Nusa Tenggara, and East Nusa Tenggara) and harvested during 2016–2018 based on physicochemical parameters, sugar content, minerals, and antioxidant components. The study showed that the result differs widely among the type of honey. IWH has a moisture content between 16.52- 33.41%, a pH value between 3.00 to 4.65 and color characteristic ranged from pale yellow to dark brown. All samples contain the highest amount in potassium, but several minerals found in the specific region. Evaluation of authenticity from sugar content data set by principal component analysis (PCA) and Linear Discriminant Analysis (LDA) revealed that the authentic and adulterated honey samples could be differentiated with a 95.5% accuracy. The honey samples were classified on their botanical and geographical origin using the antioxidant properties, and results of PCA and LDA demonstrated that the antioxidant parameters can provide adequate information to allow classification of the various types of IWH samples collected from different geographical regions with accuracy 80-100% for Bangka Belitung, Sulawesi, Kalimantan, West Nusa Tenggara, East Nusa Tenggara and Java island

scholarly journals An Improved Comparison of Chemometric Analyses for the Identification of Acids and Bases With Colorimetric Sensor Arrays

2018 ◽  
Vol 10 (2) ◽  
pp. 36 ◽  
Author(s):  
Michael James Kangas ◽  
Christina L Wilson ◽  
Raychelle M Burks ◽  
Jordyn Atwater ◽  
Rachel M Lukowicz ◽  
...  
Keyword(s):  
Image Analysis ◽  
Discriminant Analysis ◽  
Linear Discriminant Analysis ◽  
Sensor Arrays ◽  
Principal Component ◽  
Colorimetric Sensor ◽  
Support Vector ◽  
Chemometric Methods ◽  
Data Set ◽  
Linear Discriminant

Colorimetric sensor arrays incorporating red, green, and blue (RGB) image analysis use value changes from multiple sensors for the identification and quantification of various analytes. RGB data can be easily obtained using image analysis software such as ImageJ. Subsequent chemometric analysis is becoming a key component of colorimetric array RGB data analysis, though literature contains mainly principal component analysis (PCA) and hierarchical cluster analysis (HCA). Seeking to expand the chemometric methods toolkit for array analysis, we explored the performance of nine chemometric methods were compared for the task of classifying 631 solutions (0.1 to 3 M) of acetic acid, malonic acid, lysine, and ammonia using an eight sensor colorimetric array. PCA and LDA (linear discriminant analysis) were effective for visualizing the dataset. For classification, linear discriminant analysis (LDA), (k nearest neighbors) KNN, (soft independent modelling by class analogy) SIMCA, recursive partitioning and regression trees (RPART), and hit quality index (HQI) were very effective with each method classifying compounds with over 90% correct assignments. Support vector machines (SVM) and partial least squares – discriminant analysis (PLS-DA) struggled with ~85 and 39% correct assignments, respectively. Additional mathematical treatments of the data set, such as incrementally increasing the exponents, did not improve the performance of LDA and KNN. The literature precedence indicates that the most common methods for analyzing colorimetric arrays are PCA, LDA, HCA, and KNN. To our knowledge, this is the first report of comparing and contrasting several more diverse chemometric methods to analyze the same colorimetric array data.

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