Total Organic Carbon And Formation Evaluation With Wireline Logs In The Green River Oil Shale

Author(s):  
Michael M. Herron ◽  
Jim Grau ◽  
Susan L. Herron ◽  
Robert L. Kleinberg ◽  
Malka Machlus ◽  
...  

2019 ◽  
Vol 64 (2) ◽  
pp. 230-237
Author(s):  
Renata Rauch ◽  
Rita Foldenyi

It is not only Total Organic Carbon content (TOC) but also the type of Organic Matter (OM) that the sorption of organic pollutants by soils or other natural absorbents is correlated with. Therefore, the characterization of organic components in the adsorbents is very important to elucidate sorption mechanisms.Oil shale samples were collected in Pula, Hungary. The TOC content of the investigated samples was approximately 6.8-40.1 m/m %. The characterization of the organic matter in samples was carried out by using Scanning Electron Microscopy (SEM), elemental analysis, thermal analysis, and GC-MS technics. The results predominantly indicated the presence of a low degree of the branching of aliphatic chain components in the samples. The Humic Substances (HS) content of the samples was only 1-6 m/m %, which could be determined after the treatment of oil shale with hydrogen peroxide.The influence of the amount and type of organic material in oil shale samples was studied on the adsorption of 2,4-dichlorophenol (2,4-DCP) as a model contaminant. For this aim a series of batch equilibration experiments was carried out. The results show that the total organic carbon content of samples is a strong indicator of 2,4-DCP adsorption, while the HS content is an important feature controlling sorption capacity. The study suggests that the special organic matter (kerogen) content of the oil shale plays a major role in its high adsorption capacity and in the nonlinearity of the isotherms. The HS covering the surface could decrease the sorption capacities despite the fact that though the amount of this organic material is quite low.



2016 ◽  
Vol 4 (3) ◽  
pp. T373-T385 ◽  
Author(s):  
Sumit Verma ◽  
Tao Zhao ◽  
Kurt J. Marfurt ◽  
Deepak Devegowda

The Barnett Shale in the Fort Worth Basin is one of the most important resource plays in the USA. The total organic carbon (TOC) and brittleness can help to characterize a resource play to assist in the search for sweet spots. Higher TOC or organic content are generally associated with hydrocarbon storage and with rocks that are ductile in nature. However, brittle rocks are more amenable to fracturing with the fractures faces more resistant to proppant embedment. Productive intervals within a resource play should therefore contain a judicious mix of organics and mineralogy that lends to hydraulic fracturing. Identification of these intervals through core acquisition and laboratory-based petrophysical measurements can be accurate but expensive in comparison with wireline logging. We have estimated TOC from wireline logs using Passey’s method and attained a correlation of 60%. However, errors in the baseline interpretation can lead to inaccurate TOC. Using nonlinear regression with Passey’s TOC, normalized stratigraphic height, and acquired wireline logs, the correlation increased to 80%. This regression can be applied to uncored wells with logs to estimate TOC, and we used it as a ground truth in integrated analysis of seismic and well log data. The brittleness index (BI) is computed based on core Fourier transform infrared mineralogy using Wang and Gale’s formula. The correlation between core BI and estimated BI using elastic logs ([Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text], and [Formula: see text]) combined with wireline logs was 78%. However, this correlation decreases to 66% if the BI is estimated using only wireline logs. Therefore, the later serves as a less reliable proxy. We have correlated production to volumetric estimate of TOC and brittleness by computing distance-weighted averages in 120 horizontal wells. We have obtained a production correlation of 38% on blind wells, which was encouraging, suggesting that the geologic component in completions provides an important contribution to well success.





2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Markus Heryanto Langsa

<p>Penelitian ini bertujuan untuk menentukan senyawa organik khususnya organic karbon terlarut (DOC) dari dua spesies daun tumbuhan (<em>wandoo eucalyptus </em>and <em>pinus radiate, conifer</em>) yang larut dalam air selama periode 5 bulan leaching eksperimen. Kecepatan melarutnya senyawa organic ditentukan secara kuantitatif dan kualitatif menggunakan kombinasi dari beberapa teknik diantaranya Total Organic Carbon (TOC) analyser, Ultraviolet-Visible (UV-VIS) spektrokopi dan pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS).</p><p>Hasil analisis DOC dan UV menunjukkan peningkatan yang tajam dari kelarutan senyawa organic di awal periode pengamatan yang selanjutnya berkurang seiring dengan waktu secara eksponensial. Jumlah relatif senyawa organic yang terlarut tergantung pada luas permukaan, aktifitas mikrobiologi dan jenis sampel tumbuhan (segar atau kering) yang digunakan. Fluktuasi profil DOC dan UV<sub>254</sub> disebabkan oleh aktifitas mikrobiologi. Diperoleh bahwa daun kering lebih mudah terdegradasi menghasilkan senyawa organic dalam air dibandingkan dengan daun segar. Hasil pyrolysis secara umum menunjukkan bahwa senyawa hidrokarbon aromatic dan fenol (dan turunannya) lebih banyak ditemukan pada residue sampel setelah proses leaching kemungkinan karena adanya senyawa lignin atau aktifitas humifikasi mikrobiologi membuktikan bahwa senyawa-senyawa tersebut merupakan komponen penting dalam proses karakterisasi DOC.</p>



2016 ◽  
Vol 53 (1) ◽  
pp. 5-28 ◽  
Author(s):  
Grace Ford ◽  
David Pyles ◽  
Marieke Dechesne

A continuous window into the fluvial-lacustrine basin-fill succession of the Uinta Basin is exposed along a 48-mile (77-kilometer) transect up the modern Green River from Three Fords to Sand Wash in Desolation Canyon, Utah. In ascending order the stratigraphic units are: 1) Flagstaff Limestone, 2) lower Wasatch member of the Wasatch Formation, 3) middle Wasatch member of the Wasatch Formation, 4) upper Wasatch member of the Wasatch Formation, 5) Uteland Butte member of the lower Green River Formation, 6) lower Green River Formation, 7) Renegade Tongue of the lower Green River Formation, 8) middle Green River Formation, and 9) the Mahogany oil shale zone marking the boundary between the middle and upper Green River Formations. This article uses regional field mapping, geologic maps, photographs, and descriptions of the stratigraphic unit including: 1) bounding surfaces, 2) key upward stratigraphic characteristics within the unit, and 3) longitudinal changes along the river transect. This information is used to create a north-south cross section through the basin-fill succession and a detailed geologic map of Desolation Canyon. The cross section documents stratigraphic relationships previously unreported and contrasts with earlier interpretations in two ways: 1) abrupt upward shifts in the stratigraphy documented herein, contrast with the gradual interfingering relationships proposed by Ryder et al., (1976) and Fouch et al., (1994), 2) we document fluvial deposits of the lower and middle Wasatch to be distinct and more widespread than previously recognized. In addition, we document that the Uteland Butte member of the lower Green River Formation was deposited in a lacustrine environment in Desolation Canyon. Two large-scale (member-scale) upward patterns are noted: Waltherian, and non-Waltherian. The upward successions in Waltherian progressions record progradation or retrogradation of a linked fluvial-lacustrine system across the area; whereas the upward successions in non-Waltherian progressions record large-scale changes in the depositional system that are not related to progradation or retrogradation of the ancient lacustrine shoreline. Four Waltherian progressions are noted: 1) the Flagstaff Limestone to lower Wasatch Formation member records the upward transition from lacustrine to fluvial—or shallowing-upward succession; 2) the upper Wasatch to Uteland Butte records the upward transition from fluvial to lacustrine—or a deepening upward succession; 3) the Uteland Butte to Renegade Tongue records the upward transition from lacustrine to fluvial—a shallowing-upward succession; and 4) the Renegade Tongue to Mahogany oil shale interval records the upward transition from fluvial to lacustrine—a deepening upward succession. The two non-Waltherian progressions in the study area are: 1) the lower to middle Wasatch, which records the abrupt shift from low to high net-sand content fluvial system, and 2) the middle to upper Wasatch, which records the abrupt shift from high to intermediate net-sand content fluvial system.



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