Accurate Live Interfacial Tension for Improved Reservoir Engineering Practices

2021 ◽  
Author(s):  
Taha Okasha ◽  
Mohammed Al Hamad ◽  
Bastian Sauerer ◽  
Wael Abdallah

Abstract Current reservoir simulators use interfacial tension (IFT) values derived from dead oil measurements at ambient conditions or predicted from literature correlations. IFT is highly dependent on temperature, pressure and fluid composition. Therefore, knowledge of the IFT value at reservoir conditions is essential for accurate reservoir fluid characterization. This study compares IFT values from dead and live oil measurements and the results of literature predicted values, thereby clearly showing the weakness of existing correlations when trying to predict crude oil IFT. A total of ten live oils was sampled for this study. Using the pendent drop technique, IFT was measured for each oil at different conditions: in the under-saturated region at reservoir pressure and temperature, in the saturated region at reservoir temperature, and for dead oil at ambient conditions. Basic PVT properties such as gas to oil ratio (GOR), gas and liquid composition, density, viscosity and molecular weight were also measured. The bubble point for each oil was identified to define the pressure step in the saturated region for extra IFT measurement. The equilibrium IFT values for the live oils were generally higher than for the corresponding dead oils. For oils where this general trend was not observed, contaminations were found in the crude samples. The use of current literature correlations does not allow to predict correct reservoir IFT. Therefore, this study provides accurate live IFT values for a variety of reservoir fluids and conditions in combination with live oil properties, highly beneficial to reservoir engineers, allowing better oil production planning.

2011 ◽  
Author(s):  
Ali Shariat ◽  
Robert Gordon Moore ◽  
Sudarshan A. Mehta ◽  
Kees Cornelius Van Fraassen ◽  
Kent Edward Newsham ◽  
...  

2008 ◽  
Vol 11 (06) ◽  
pp. 1107-1116 ◽  
Author(s):  
Chengli Dong ◽  
Michael D. O'Keefe ◽  
Hani Elshahawi ◽  
Mohamed Hashem ◽  
Stephen M. Williams ◽  
...  

Summary Downhole fluid analysis (DFA) has emerged as a key technique for characterizing the distribution of reservoir-fluid properties and determining zonal connectivity across the reservoir. Information from profiling the reservoir fluids enables sealing barriers to be proved and compositional grading to be quantified; this information cannot be obtained from conventional wireline logs. The DFA technique has been based largely on optical spectroscopy, which can provide estimates of filtrate contamination, gas/oil ratio (GOR), pH of formation water, and a hydrocarbon composition in four groups: methane (C1), ethane to pentane (C2-5), hexane and heavier hydrocarbons (C6+), and carbon dioxide (CO2). For single-phase assurance, it is possible to detect gas liberation (bubblepoint) or liquid dropout (dewpoint) while pumping reservoir fluid to the wellbore, before filling a sample bottle. In this paper, a new DFA tool is introduced that substantially increases the accuracy of these measurements. The tool uses a grating spectrometer in combination with a filter-array spectrometer. The range of compositional information is extended from four groups to five groups: C1, ethane (C2), propane to pentane (C3-5), C6+, and CO2. These spectrometers, together with improved compositional algorithms, now make possible a quantitative analysis of reservoir fluid with greater accuracy and repeatability. This accuracy enables comparison of fluid properties between wells for the first time, thus extending the application of fluid profiling from a single-well to a multiwall basis. Field-based fluid characterization is now possible. In addition, a new measurement is introduced--in-situ density of reservoir fluid. Measuring this property downhole at reservoir conditions of pressure and temperature provides important advantages over surface measurements. The density sensor is combined in a package that includes the optical spectrometers and measurements of fluid resistivity, pressure, temperature, and fluorescence that all play a vital role in determining the exact nature of the reservoir fluid. Extensive tests at a pressure/volume/temperature (PVT) laboratory are presented to illustrate sensor response in a large number of live-fluid samples. These tests of known fluid compositions were conducted under pressurized and heated conditions to simulate reservoir conditions. In addition, several field examples are presented to illustrate applicability in different environments. Introduction Reservoir-fluid samples collected at the early stage of exploration and development provide vital information for reservoir evaluation and management. Reservoir-fluid properties, such as hydrocarbon composition, GOR, CO2 content, pH, density, viscosity, and PVT behavior are key inputs for surface-facility design and optimization of production strategies. Formation-tester tools have proved to be an effective way to obtain reservoir-fluid samples for PVT analysis. Conventional reservoir-fluid analysis is conducted in a PVT laboratory, and it usually takes a long time (months) before the results become available. Also, miscible contamination of a fluid sample by drilling-mud filtrate reduces the utility of the sample for subsequent fluid analyses. However, the amount of filtrate contamination can be reduced substantially by use of focused-sampling cleanup introduced recently in the next-generation wireline formation testers (O'Keefe et al. 2008). DFA tools provide results in real time and at reservoir conditions. Current DFA techniques use absorption spectroscopy of reservoir fluids in the visible-to-near-infrared (NIR) range. The formation-fluid spectra are obtained in real time, and fluid composition is derived from the spectra on the basis of C1, C2-5, C6+, and CO2; then, GOR of the fluid is estimated from the derived composition (Betancourt et al. 2004; Fujisawa et al. 2002; Dong et al. 2006; Elshahawi et al. 2004; Fujisawa et al. 2008; Mullins et al. 2001; Smits et al. 1995). Additionally, from the differences in absorption spectrum between reservoir fluid and filtrate of oil-based mud (OBM) or water-based mud (WBM), fluid-sample contamination from the drilling fluid is estimated (Mullins et al. 2000; Fadnes et al. 2001). With the DFA technique, reservoir-fluid samples are analyzed before they are taken, and the quality of fluid samples is improved substantially. The sampling process is optimized in terms of where and when to sample and how many samples to take. Reservoir-fluid characterization from fluid-profiling methods often reveals fluid compositional grading in different zones, and it also helps to identify reservoir compartmentalization (Venkataramanan et al. 2008). A next-generation tool has been developed to improve the DFA technique. This DFA tool includes new hardware that provides more-accurate and -detailed spectra, compared to the current DFA tools, and includes new methods of deriving fluid composition and GOR from optical spectroscopy. Furthermore, the new DFA tool includes a vibrating sensor for direct measurement of fluid density and, in certain environments, viscosity. The new DFA tool provides reservoir-fluid characterization that is significantly more accurate and comprehensive compared to the current DFA technology.


Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Masashige Shiga ◽  
Masaatsu Aichi ◽  
Masao Sorai

It is significant to understand the values and trends of the contact angle of CO2/brine/mineral systems to evaluate and model the sealing performance of CO2 Geo-Sequestration (CGS). It has been reported that the contact angles of the CO2/brine/muscovite systems increase as pressure increases from ambient conditions to reservoir conditions. This trend suggests a decrease in seal integrity. In this paper, we studied its mechanisms and the contributing factors by calculating the Frumkin-Derjaguin equation, which is based on the thermodynamics of the interfacial system. Results show that a decrease of pH is a critical factor for the wettability alteration at a lower pressure range (0.1 MPa to 3.0 MPa). In contrast, the increase of CO2 density and the decrease in the interfacial tension of CO2/brine are significant for the wettability change at a higher pressure range (3.0 MPa to 10.0 MPa). Also, sensitivity analysis shows that the contact angle is sensitive to the interfacial tension of CO2/brine and the coefficients of hydration forces.


2021 ◽  
Author(s):  
Terence George Wood ◽  
Scott Campbell ◽  
Nathan Smith

Abstract The requirement for capturing and storing Carbon Dioxide will continue to grow in the next decade and a fundamental part of this is being able to transport the fluid over large geographical distances in numerous terrains and environments. The evolving nature of the fluid supply and the storage characteristics ensure the operation of the pipeline remains a challenge throughout its operational life. This paper will examine the impact of changes in the fluid composition, storage locations, ambient conditions and the various operating modes the pipeline will see throughout the lifecycle, highlight the technical design and operational challenges and finally give guidance on future developments. The thermodynamic behaviour of CO2 with and without impurities will be demonstrated utilising the fluid characterisation software, MultiflashTM. The fluid behaviour and hydraulic performance will be calculated over the expected operational envelope of the pipeline throughout field life, highlighting the benefits and constraints of using the single component module in OLGATM whilst comparing against a compositional approach when dealing with impurities. The paper will demonstrate through two case studies of varying nature including geographical environment, storage location (aquifer vs. abandoned hydrocarbon reservoir) and ambient conditions, the following issues: The impact of the storage type on the pipeline operations and how this will evolve with time; The environmental conditions and the impact these have on selection of process equipment and operational procedures (i.e. shutdown); and The impact the CO2 composition has on the design of the CO2 pipeline, and The paper will conclude with a set of guidelines for undertaking design analysis of CO2 pipelines for variations in fluid composition, storage locations and ambient conditions as well as some key operational strategies. This paper utilises the current state of the art tools and how these evolving tools are making this technically challenging area more mainstream.


2021 ◽  
Vol 196 ◽  
pp. 107673
Author(s):  
Nurudeen Yekeen ◽  
Eswaran Padmanabhan ◽  
Hesham Abdulelah ◽  
Sayed Ameenuddin Irfan ◽  
Oluwagade Adenike Okunade ◽  
...  

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